1,3-Dioxane, 4,4-dimethyl-

• Formula: C₆H₁₂O₂
• Molecular weight: 116.1583
• IUPAC Standard InChI: InChI=1S/C6H12O2/c1-6(2)3-4-7-5-8-6/h3-5H2,1-2H3 Copy

  
• IUPAC Standard InChIKey: GDKSTFXHMBGCPG-UHFFFAOYSA-N Copy
• CAS Registry Number: 766-15-4
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Other names: m-Dioxane, 4,4-dimethyl-; 4,4-Dimethyl-m-dioxane; 4,4-Dimethyl-1,3-dioxane; 4,4-Dimethyldioxane-1,3
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• Information on this page:
  • Phase change data
  • Gas phase ion energetics data
  • Mass spectrum (electron ionization)
  • References
  • Notes
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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos

Enthalpy of vaporization

Antoine Equation Parameters

log₁₀(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard

Ionization energy determinations

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

References

Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lesteva and Timofeev, 1972
Lesteva, T.M.; Timofeev, G.A., Phase equilibria in methanol + 4,4-dimethyl-1,3-dioxane and trimethyl carbinol + 4,4-dimethyl-1,3-dioxane systems, Zh. Prikl. Khim. (Leningrad), 1972, 45, 695-697. [all data]

Farberov and Speranskaya, 1958
Farberov, M.I.; Speranskaya, V.A., Synthesis of β-Chloro Substituted Alcohols and Their Transformations, Zh. Obshch. Khim., 1958, 28, 2151. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Kachalova and Nemtsov, 1968
Kachalova, R.V.; Nemtsov, M.S., Zh. Prikl. Khim. (Leningrad), 1968, 41, 10, 2315. [all data]

Lesteva, Morozova, et al., 1969
Lesteva, T.M.; Morozova, A.I.; Morozova, V.I.; Ogorodnikov, S.K.; Tyvina, T.N., Zh. Prikl. Khim. (S.-Peterburg), 1969, 42, 3, 553. [all data]

Lesteva, Morozova, et al., 1969, 2
Lesteva, T.M.; Morozova, A.I.; Morozova, V.I.; Ogorodnikov, S.K.; Tyrina, T.N., Equilibrium of Liquid-Steam and Liquid-Liquid in System 4,4-Dimethyldioxane-1,3-Methyldihydropyrine-Water, Zh. Prikl. Khim. (Leningrad), 1969, 42, 553-558. [all data]

Asfandiarov and Zykov, 1983
Asfandiarov, N.L.; Zykov, B.G., Photoelectron spectra of methyl-substituted 1,3-Dioxanes, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1983, 10, 2069, In original 2293. [all data]

Notes

Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), References

• Symbols used in this document:
  

  Tboil	Boiling point
  ΔvapH	Enthalpy of vaporization

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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