Si4 anion
- Formula: Si4-
- Molecular weight: 112.3425
- CAS Registry Number: 106389-61-1
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | 112.3 ± 5.4 | kcal/mol | R-EA | Nakajima, Taguwa, et al., 1995 | Vertical Detachment Energy: 2.15±0.04 eV. |
Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
By formula: (Si4- • 4294967295Si) + Si = Si4-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 98.2 ± 6.9 | kcal/mol | N/A | Nakajima, Taguwa, et al., 1995 | gas phase; Vertical Detachment Energy: 2.15±0.04 eV. |
Ion clustering data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
By formula: (Si4- • 4294967295Si) + Si = Si4-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 98.2 ± 6.9 | kcal/mol | N/A | Nakajima, Taguwa, et al., 1995 | gas phase; Vertical Detachment Energy: 2.15±0.04 eV. |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Nakajima, Taguwa, et al., 1995
Nakajima, A.; Taguwa, T.; Nakao, K.; Gomei, M.; Kishi, R.; Iwata, S.; Kaya, K.,
Photoelectron Spectroscopy of silicon-carbon cluster Anions (SinCm-),
J. Chem. Phys., 1995, 103, 6, 2050, https://doi.org/10.1063/1.469731
. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, References
- Symbols used in this document:
ΔfH°gas Enthalpy of formation of gas at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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