Mercury diiodide
- Formula: HgI2
- Molecular weight: 454.40
- IUPAC Standard InChIKey: YFDLHELOZYVNJE-UHFFFAOYSA-L
- CAS Registry Number: 7774-29-0
- Chemical structure:
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Phase change data
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
Enthalpy of vaporization
ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
64.0 | 574. | UV | Su, Zhu, et al., 2002 | Based on data from 537. to 610. K. |
Enthalpy of fusion
ΔfusH (kJ/mol) | Temperature (K) | Method | Reference |
---|---|---|---|
20.3 | 537. | Sub-Vap | Su, Zhu, et al., 2002 |
Gas phase ion energetics data
Go To: Top, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data evaluated as indicated in comments:
L - Sharon G. Lias
Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
IE (evaluated) | 9.509 ± 0.002 | eV | N/A | N/A | L |
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
9.5088 ± 0.0022 | PI | Linn, Tzeng, et al., 1983 | LBLHLM |
9.5 | PE | Lee and Potts, 1981 | LLK |
9.50 | PE | Eland, 1970 | RDSH |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
HgI+ | 10.88 ± 0.05 | I | PI | Linn, Tzeng, et al., 1983 | LBLHLM |
HgI+ | 10.88 ± 0.05 | I | EI | Linn, Tzeng, et al., 1983 | LBLHLM |
HgI+ | 11.3 ± 0.4 | I | EI | Kiser, Dillard, et al., 1969 | RDSH |
I+ | 13.12 ± 0.04 | HgI | EI | Linn, Tzeng, et al., 1983 | LBLHLM |
I+ | 13.12 ± 0.04 | HgI | PI | Linn, Tzeng, et al., 1983 | LBLHLM |
I+ | 15.5 ± 0.4 | ? | EI | Kiser, Dillard, et al., 1969 | RDSH |
I2+ | 10.73 ± 0.04 | Hg | EI | Linn, Tzeng, et al., 1983 | LBLHLM |
I2+ | 10.73 ± 0.04 | Hg | PI | Linn, Tzeng, et al., 1983 | LBLHLM |
References
Go To: Top, Phase change data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Su, Zhu, et al., 2002
Su, Ching-Hua; Zhu, Shen; Ramachandran, N.; Burger, A.,
Beer law constants and vapor pressures of HgI2 over HgI2(s,l),
Journal of Crystal Growth, 2002, 235, 1-4, 313-319, https://doi.org/10.1016/S0022-0248(01)01806-1
. [all data]
Linn, Tzeng, et al., 1983
Linn, S.H.; Tzeng, W.-B.; Brom, J.M., Jr.; Ng, C.Y.,
Molecular beam photoionization study of HgBr2 and HgI2,
J. Chem. Phys., 1983, 78, 50. [all data]
Lee and Potts, 1981
Lee, E.P.F.; Potts, A.W.,
Fine structure in the He(I)/He(II) photoelectron spectra of the metal valence (d) shells of the group IIB dihalides,
J. Electron Spectrosc. Relat. Phenom., 1981, 22, 247. [all data]
Eland, 1970
Eland, J.H.D.,
Photoelectron spectra and chemical bonding of mercury(II) compounds,
Intern. J. Mass Spectrom. Ion Phys., 1970, 4, 37. [all data]
Kiser, Dillard, et al., 1969
Kiser, R.W.; Dillard, J.G.; Dugger, D.L.,
Mass spectrometry of inorganic halides,
Advan. Chem. Ser., 1969, 72, 153. [all data]
Notes
Go To: Top, Phase change data, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy IE (evaluated) Recommended ionization energy ΔfusH Enthalpy of fusion ΔvapH Enthalpy of vaporization - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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