Mercury diiodide


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
64.0574.UVSu, Zhu, et al., 2002Based on data from 537. to 610. K.

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Method Reference
20.3537.Sub-VapSu, Zhu, et al., 2002

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
L - Sharon G. Lias

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Quantity Value Units Method Reference Comment
IE (evaluated)9.509 ± 0.002eVN/AN/AL

Ionization energy determinations

IE (eV) Method Reference Comment
9.5088 ± 0.0022PILinn, Tzeng, et al., 1983LBLHLM
9.5PELee and Potts, 1981LLK
9.50PEEland, 1970RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
HgI+10.88 ± 0.05IPILinn, Tzeng, et al., 1983LBLHLM
HgI+10.88 ± 0.05IEILinn, Tzeng, et al., 1983LBLHLM
HgI+11.3 ± 0.4IEIKiser, Dillard, et al., 1969RDSH
I+13.12 ± 0.04HgIEILinn, Tzeng, et al., 1983LBLHLM
I+13.12 ± 0.04HgIPILinn, Tzeng, et al., 1983LBLHLM
I+15.5 ± 0.4?EIKiser, Dillard, et al., 1969RDSH
I2+10.73 ± 0.04HgEILinn, Tzeng, et al., 1983LBLHLM
I2+10.73 ± 0.04HgPILinn, Tzeng, et al., 1983LBLHLM

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Su, Zhu, et al., 2002
Su, Ching-Hua; Zhu, Shen; Ramachandran, N.; Burger, A., Beer law constants and vapor pressures of HgI2 over HgI2(s,l), Journal of Crystal Growth, 2002, 235, 1-4, 313-319, https://doi.org/10.1016/S0022-0248(01)01806-1 . [all data]

Linn, Tzeng, et al., 1983
Linn, S.H.; Tzeng, W.-B.; Brom, J.M., Jr.; Ng, C.Y., Molecular beam photoionization study of HgBr2 and HgI2, J. Chem. Phys., 1983, 78, 50. [all data]

Lee and Potts, 1981
Lee, E.P.F.; Potts, A.W., Fine structure in the He(I)/He(II) photoelectron spectra of the metal valence (d) shells of the group IIB dihalides, J. Electron Spectrosc. Relat. Phenom., 1981, 22, 247. [all data]

Eland, 1970
Eland, J.H.D., Photoelectron spectra and chemical bonding of mercury(II) compounds, Intern. J. Mass Spectrom. Ion Phys., 1970, 4, 37. [all data]

Kiser, Dillard, et al., 1969
Kiser, R.W.; Dillard, J.G.; Dugger, D.L., Mass spectrometry of inorganic halides, Advan. Chem. Ser., 1969, 72, 153. [all data]


Notes

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