Decanoic acid, ethyl ester

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas-612. ± 2.kJ/molCmWiberg and Waldron, 1991Heat of hydrolysis

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfliquid-679.6 ± 1.1kJ/molCmWiberg and Waldron, 1991Heat of hydrolysis
Quantity Value Units Method Reference Comment
Δcliquid-7448. ± 1.kJ/molCcbFreedman, Bagby, et al., 1989Corresponding Δfliquid = -704.6 kJ/mol (simple calculation by NIST; no Washburn corrections)

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Tboil518.2KN/AAldrich Chemical Company Inc., 1990BS
Tboil514.7KN/AVogel, 1948Uncertainty assigned by TRC = 1. K; TRC
Tboil518.05KN/ADeffet, 1931Uncertainty assigned by TRC = 1. K; TRC
Quantity Value Units Method Reference Comment
Δvap70.5kJ/molN/AZaitsau, Paulechka, et al., 2009AC
Δvap67. ± 1.kJ/molVWiberg and Waldron, 1991Heat of hydrolysis; ALS
Δvap67.6kJ/molN/AWiberg and Waldron, 1991DRB
Δvap67.4 ± 1.3kJ/molMMWiberg and Waldron, 1991Based on data from 404. to 440. K.; AC

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
69.9 ± 0.7305.CZaitsau, Paulechka, et al., 2009AC
58.4 ± 0.1422.MMWiberg and Waldron, 1991Based on data from 404. to 440. K.; AC
59.6374.AStephenson and Malanowski, 1987Based on data from 359. to 515. K.; AC

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Method Reference Comment
32.29253.6ACZaitsau, Paulechka, et al., 2009Based on data from 5. to 370. K.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wiberg and Waldron, 1991
Wiberg, K.B.; Waldron, R.F., Lactones. 2. Enthalpies of hydrolysis, reduction, and formation of the C4-C13 monocyclic lactones. strain energies and conformations, J. Am. Chem. Soc., 1991, 113, 7697-7705. [all data]

Freedman, Bagby, et al., 1989
Freedman, B.; Bagby, M.O.; Khoury, H., Correlation of heats of combustion with empirical formulas for fatty alcohols, J. Am. Oil Chem. Soc., 1989, 66, 595-596. [all data]

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Vogel, 1948
Vogel, A.I., J. Chem. Soc., 1948, 1948, 624-44. [all data]

Deffet, 1931
Deffet, L., The Freezing Points of Organic Compounds XIII. Compounds With Seven Eight, Nine or Ten Carbon Atoms, Bull. Soc. Chim. Belg., 1931, 40, 385-402. [all data]

Zaitsau, Paulechka, et al., 2009
Zaitsau, Dzmitry H.; Paulechka, Yauheni U.; Blokhin, Andrey V.; Yermalayeu, Andrei V.; Kabo, Andrei G.; Ivanets, Maryna R., Thermodynamics of Ethyl Decanoate, J. Chem. Eng. Data, 2009, 54, 11, 3026-3033, https://doi.org/10.1021/je900093h . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]


Notes

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