GA8 methyl ester TMS ether

• Formula: C₂₉H₅₀O₇Si₃
• Molecular weight: 594.9596
• IUPAC Standard InChI: InChI=1S/C29H50O7Si3/c1-18-15-27-17-28(18,36-39(10,11)12)14-13-20(27)29-16-19(34-37(4,5)6)23(35-38(7,8)9)26(2,25(31)33-29)22(29)21(27)24(30)32-3/h19-23H,1,13-17H2,2-12H3/t19-,20?,21?,22?,23-,26-,27-,28-,29+/m1/s1 Copy

  
• IUPAC Standard InChIKey: URXALWQXBINWJP-MASLEOCOSA-N Copy
• Chemical structure:
  This structure is also available as a 2d Mol file
• Stereoisomers:
  • [13C]GA8 methyl ester TMS ether
  • GA8-catabolite, MeTMS
  • GA56, MeTMSi
• Other names: GA8, MeTMSi; GA8, Me-TMS; Gibberellin GA8, methyl ester trimethylsilyl ether; Gibberelline GA8, methyl ester TMS ether; GA8, methyl ester TMS
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• Information on this page:
  • Van Den Dool and Kratz RI, non-polar column, custom temperature program
  • References
  • Notes
• Other data available:
  • Gas Chromatography
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Van Den Dool and Kratz RI, non-polar column, custom temperature program

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

References

Go To: Top, Van Den Dool and Kratz RI, non-polar column, custom temperature program, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Frisse, Pimenta, et al., 2003
Frisse, A.; Pimenta, M.J.; Lange, T., Expression studies of gibberellin oxidases in developing pumpkin seeds, Plant Physiol., 2003, 131, 3, 1220-1227, retrieved from http://www.plantphysiol.org, https://doi.org/10.1104/pp.015206 . [all data]

Blake, Taylor, et al., 2002
Blake, P.S.; Taylor, J.M.; Finch-Savage, W.E., Identification of abscisic acid, indole-3-acetic acid, jasmonic acid, indole-3-acetonitrile, methyl jasmonate and gibberellins in developing, dormant and startified seeds of ash (Fraxinus excelsior), Plant Growth Regul., 2002, 37, 2, 119-125, https://doi.org/10.1023/A:1020504610172 . [all data]

Pearce, Hutt, et al., 2002
Pearce, D.W.; Hutt, O.E.; Rood, S.B.; Mander, L.N., Gibberellins in shoots and developing capsules of Populus species, Phytochemistry, 2002, 59, 6, 679-687, https://doi.org/10.1016/S0031-9422(02)00009-2 . [all data]

Blake, Browning G., et al., 2000
Blake, P.S.; Browning G.; Benjamin, L.J.; Mander, L.N., Gibberellins in seedlings and flowering trees of Prunus avium L., Phytochemistry, 2000, 53, 4, 519-528, https://doi.org/10.1016/S0031-9422(99)00597-X . [all data]

Taylor, Blake, et al., 2000
Taylor, D.R.; Blake, P.S.; Crisp, C.M., Identification of gibberellins in leaf tissues of day-neutral strawberry (Fragaria × ananassa Duch.) cultivars, Plant Growth Regul., 2000, 30, 1, 5-7, https://doi.org/10.1023/A:1006275024517 . [all data]

Roberts, Blake, et al., 1999
Roberts, A.V.; Blake, P.S.; Lewis, R.; Taylor, J.M.; Dunstan, D.I., The effect of gibberellins on flowering in roses, J. Plant Growth Regul., 1999, 18, 3, 113-119, https://doi.org/10.1007/PL00007058 . [all data]

Hisamatsu, Koshioka, et al., 1998
Hisamatsu, T.; Koshioka, M.; Kubota, S.; Nishijima, T.; Yamane, H.; King, R.W.; Mander, L.N., Isolation and identification of GA₁₁₂ (12β-hydroxy-GA₁₂) in Matthiola incana, Phytochemistry, 1998, 47, 1, 3-6, https://doi.org/10.1016/S0031-9422(97)00543-8 . [all data]

Webb, Appleford, et al., 1998
Webb, S.E.; Appleford, N.E.J.; Gaskin, P.; Lenton, J.R., Gibberellins in internodes and ears of wheat containing different dwarfing alleles, Phytochemistry, 1998, 47, 5, 671-677, https://doi.org/10.1016/S0031-9422(97)00684-5 . [all data]

Grünzweig, Rabinowitch, et al., 1997
Grünzweig, J.M.; Rabinowitch, H.D.; Katan, J.; Wodner, M.; Ben-Tal, Y., Endogenous gibberellins in foliage of tomato (Lycopersicon esculentum), Phytochemistry, 1997, 46, 5, 811-815, https://doi.org/10.1016/S0031-9422(97)00383-X . [all data]

Kappers, Jordi, et al., 1997
Kappers, I.F.; Jordi, W.; Maas, F.M.; van der Plas, L.H.W., Gibberellins in leaves of Alstroemeria hybrida: identification and quantification in relation to leaf age, J. Plant Growth Regul., 1997, 16, 4, 219-225, https://doi.org/10.1007/PL00007000 . [all data]

Spray, Kobayashi, et al., 1996
Spray, C.R.; Kobayashi, M.; Suzuki, Y.; Phinney, B.O.; Gaskin, P.; MacMillan, J., The dwarf-1 (dl) mutant of Zea mays blocks three steps in the gibberellin-biosynthetic pathway, Proc. Nat. Acad. Sci. U.S.A., 1996, 93, 19, 10515-10518, https://doi.org/10.1073/pnas.93.19.10515 . [all data]

Ridoutt, Pharis, et al., 1995
Ridoutt, B.G.; Pharis, R.P.; Sands, R., Identification and quantification of cambial region hormones of Eucalyptus globulus, Plant Cell Physiol., 1995, 36, 6, 1143-1147. [all data]

Santes, Hedden, et al., 1995
Santes, C.M.; Hedden, P.; Gaskin, P.; Garcia-Martinez, J.L., Gibberellins and related compounds in young fruits of pea and their relationship to fruit-set, Phytochemistry, 1995, 40, 5, 1347-1355, https://doi.org/10.1016/0031-9422(95)00489-T . [all data]

Kobayashi, Gaskin, et al., 1994
Kobayashi, M.; Gaskin, P.; Spray, C.R.; Phinney, B.O.; MacMillan, J., The metabolism of gibberellin A₂₀ to gibberellin A₁ by tall and dwarf mutants of Oryza sativa and Arabidopsis thaliana, Plant Physiol., 1994, 106, 1367-1372. [all data]

Pearce, Koshioka, et al., 1994
Pearce, D.W.; Koshioka, M.; Pharis, R.P., Chromatography of gibberellins, J. Chromatogr. A, 1994, 658, 1, 91-122, https://doi.org/10.1016/0021-9673(94)85210-3 . [all data]

Taylor, Blake, et al., 1994
Taylor, D.R.; Blake, P.S.; Browning, G., Identification of gibberellins in leaf tissues of strawberry (Fragaria × ananassa Duch.) grown under different photoperiods, Plant Growth Regul., 1994, 15, 3, 235-240, https://doi.org/10.1007/BF00029896 . [all data]

Waycott, Smith, et al., 1991
Waycott, W.; Smith, V.A.; Gaskin, P.; MacMillan, J.; Taiz, L., The endogenous gibberellins of dwarf mutants of lettuce, Plant Physiol., 1991, 95, 4, 1169-1173, https://doi.org/10.1104/pp.95.4.1169 . [all data]

Poling and Maier, 1988
Poling, S.M.; Maier, V.P., Identification of endogenous gibberellins in navel orange shoots, Plant Physiol., 1988, 88, 3, 639-642, https://doi.org/10.1104/pp.88.3.639 . [all data]

Heupel R.C., Phinney B.O., et al., 1985
Heupel R.C.; Phinney B.O.; Spray C.R.; Gaskin P.; MacMillan J.; Hedden P.; Graebe J.E., Native gibberellins and the metabolism of [14C] gibberellin A53 and of [17-C-13,17-3H)] gibberellin A-20 in tassels of Zea-mays, Phytochemistry, 1985, 24, 1, 47-53, https://doi.org/10.1016/S0031-9422(00)80805-5 . [all data]

Gaskin, Gilmour, et al., 1984
Gaskin, P.; Gilmour, S.J.; Lenton, J.R.; MacMillan, J.; Sponsel, V.M., Endogenous gibberellins and kauranoids identified from developing and germinating barley grain, J. Plant Growth Regul., 1984, 2, 1-4, 229-242, https://doi.org/10.1007/BF02042252 . [all data]

Notes

Go To: Top, Van Den Dool and Kratz RI, non-polar column, custom temperature program, References

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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