GA34 methyl ester TMS ether
- Formula: C26H42O6Si2
- Molecular weight: 506.7791
- IUPAC Standard InChI: InChI=1S/C26H42O6Si2/c1-15-12-25-13-16(15)10-11-18(25)26-14-17(31-33(4,5)6)21(32-34(7,8)9)24(2,23(28)30-26)20(26)19(25)22(27)29-3/h16-21H,1,10-14H2,2-9H3/t16-,17+,18?,19-,20?,21+,24+,25+,26-/m0/s1
- IUPAC Standard InChIKey: MABXSEMQIJETIP-PMDKZKSBSA-N
- Chemical structure:
This structure is also available as a 2d Mol file - Stereoisomers:
- Other names: GA34, MeTMSi; GA34, Me-TMS; Gibberellin GA34, methyl ester trimethylsilyl ether; GA34, methyl ester TMS
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Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | SE-30 | 2671. | Odén, Wang, et al., 1995 | 25. m/0.25 mm/0.25 μm; Program: 80C(1min) => (20C/min) => 200C => (4C/min) => 250C |
| Capillary | Ultra-2 | 2620. | Talon, Koornneef, et al., 1990 | 25. m/0.32 mm/0.52 μm; Program: 50C => 40C/min => 220C => 6C/min => 280C |
| Capillary | BP-1 | 2687. | Hedden, Croker, et al., 1989 | 25. m/0.32 mm/0.33 μm, He; Program: 50C(1min) => 20C/min => 240C => 4C/min => 295C |
| Capillary | BP-1 | 2688. | Hedden, Croker, et al., 1989 | 25. m/0.32 mm/0.33 μm, He; Program: 50C(1min) => 20C/min => 240C => 4C/min => 295C |
Van Den Dool and Kratz RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | BPX-5 | 2669. | Frisse, Pimenta, et al., 2003 | 30. m/0.25 mm/0.25 μm, He; Program: 60C => 45C/min => 220C => 4C/min => 300C |
| Capillary | HP-1 | 2672. | Pearce, Hutt, et al., 2002 | Column length: 12. m; Column diameter: 0.22 mm; Program: 60C(0.5min) => 20C/min => 200C => 5C/min => 300C |
| Capillary | HP-1 | 2673. | Pearce, Hutt, et al., 2002 | Column length: 12. m; Column diameter: 0.22 mm; Program: 60C(0.5min) => 20C/min => 200C => 5C/min => 300C |
| Capillary | DB-5 | 2654. | Pearce, Hutt, et al., 2002 | Column length: 15. m; Column diameter: 0.25 mm; Program: 60C(0.5min) => 20C/min => 200C => 5C/min => 300C |
| Capillary | DB-5 | 2655. | Pearce, Hutt, et al., 2002 | Column length: 15. m; Column diameter: 0.25 mm; Program: 60C(0.5min) => 20C/min => 200C => 5C/min => 300C |
| Capillary | DB-1 | 2660. | Hisamatsu, Koshioka, et al., 1998 | 15. m/0.25 mm/0.33 μm; Program: 120(2min) => (16C/min) => 216(5min) => (8C/min) => 280C |
| Capillary | OV-1 | 2665. | Webb, Appleford, et al., 1998 | 25. m/0.2 mm/0.25 μm; Program: 60C(2min) => 10C/min => 150C => 3C/min => 300C |
| Capillary | BP-1 | 2672. | Webb, Appleford, et al., 1998 | 25. m/0.2 mm/0.1 μm; Program: 60C(2min) => 10C/min => 150C => 3C/min => 300C |
| Capillary | DB-1 | 2666. | Grünzweig, Rabinowitch, et al., 1997 | He; Column length: 30. m; Column diameter: 0.25 mm; Program: 40C (2min) => 10C/min => 150C => 3C/min => 300C |
| Capillary | DB-1 | 2671. | Grünzweig, Rabinowitch, et al., 1997 | He; Column length: 30. m; Column diameter: 0.25 mm; Program: 40C (2min) => 10C/min => 150C => 3C/min => 300C |
| Capillary | CP Sil 5 CB | 2675. | Kappers, Jordi, et al., 1997 | 30. m/0.25 mm/0.4 μm, He; Program: 200C => 25C/min => 250C => 4C/min => 280C(4min) |
| Capillary | CP Sil 5 CB | 2675. | Kappers, Jordi, et al., 1997 | 30. m/0.25 mm/0.4 μm, He; Program: 200C => 25C/min => 250C => 4C/min => 280C(4min) |
| Capillary | DB-1 | 2669. | Pearce, Koshioka, et al., 1994 | 15. m/0.22 mm/0.25 μm; Program: 60(0.1 min)-200 0C at 20 deg/min; 200-300 0C at 5 deg/min |
| Capillary | SE-52 | 2660. | Hedden, Hoad, et al., 1993 | 25. m/0.22 mm/0.25 μm, He; Program: 50C => 15C/min => 240C => 4C/min => 300C |
| Capillary | SE-52 | 2660. | Hedden, Hoad, et al., 1993 | 25. m/0.22 mm/0.25 μm, He; Program: 50C => 15C/min => 240C => 4C/min => 300C |
| Capillary | OV-1 | 2669. | Kobayashi, Gaskin, et al., 1993 | 25. m/0.2 mm/0.25 μm; Program: 50C(2min) => 10C/min => 150C => 3C/min => 300C |
| Capillary | OV-1 | 2657. | Gaskin, Gilmour, et al., 1984 | He; Column length: 25. m; Column diameter: 0.2 mm; Program: 60C(2min) => 13C/min => 150C => 3C/min => 280C(10min) |
Normal alkane RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | DB-5 | 2719. | Park, Nakajima, et al., 2005 | 15. m/0.25 mm/0.25 μm, Helium, 60. C @ 2. min, 15. K/min; Tend: 300. C |
| Capillary | DB-1 | 2653. | Oyama, Yamauchi, et al., 1996 | 160. C @ 2. min, 16. K/min; Column length: 15. m; Column diameter: 0.258 mm; Tend: 280. C |
Normal alkane RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | BPX-5 | 2672. | Lange, Kappler, et al., 2005 | 30. m/0.25 mm/0.25 μm, He; Program: 60 0C (1 min) 45 0C/min -> 220 0C 4 0C/min -> 300 0C |
| Capillary | OV-1 | 2678. | Sakamoto, Kobayashi, et al., 2001 | Program: not specified |
| Capillary | HP-1 | 2690. | Fos, Nuez, et al., 2000 | 25. m/0.20 mm/0.33 μm, Helium; Program: 60 0C (1 min) 20 0C/min -> 240 0C 4 0C/min -> 300 0C |
| Capillary | HP-1 | 2692. | Fos, Nuez, et al., 2000 | 25. m/0.20 mm/0.33 μm, Helium; Program: 60 0C (1 min) 20 0C/min -> 240 0C 4 0C/min -> 300 0C |
| Capillary | Ultra-2 | 2621. | Talon, Zeevaart, et al., 1991 | 25. m/0.32 mm/0.52 μm; Program: 50C => 40C/min => 220C => 8C/min => 280C |
References
Go To: Top, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Odén, Wang, et al., 1995
Odén, P.C.; Wang, Q.; Högberg, K.-A.; Werner, M.,
Transport and metabolism of gibberellins in relation to flower bud differentiation in Norway spruce (Picea abies),
Tree Physiol., 1995, 15, 7-8, 451-456, https://doi.org/10.1093/treephys/15.7-8.451
. [all data]
Talon, Koornneef, et al., 1990
Talon, M.; Koornneef, M.; Zeevaart, J.A.D.,
Endogenous gibberellins in Arabidopsis thaliana and possible steps blocked in the biosynthetic pathways of the semidwarf ga4 and ga5 mutants,
Proc. Nat. Acad. Sci. U.S.A., 1990, 87, 20, 7983-7987, https://doi.org/10.1073/pnas.87.20.7983
. [all data]
Hedden, Croker, et al., 1989
Hedden, P.; Croker, S.J.; Rademacher, W.; Jung, J.,
Effects of the triazole plant growth retardant BAS 111..W on gibberellin levels in oilseed rape, Brassica napus,
Physiol. Plant., 1989, 75, 4, 445-451, https://doi.org/10.1111/j.1399-3054.1989.tb05607.x
. [all data]
Frisse, Pimenta, et al., 2003
Frisse, A.; Pimenta, M.J.; Lange, T.,
Expression studies of gibberellin oxidases in developing pumpkin seeds,
Plant Physiol., 2003, 131, 3, 1220-1227, retrieved from http://www.plantphysiol.org, https://doi.org/10.1104/pp.015206
. [all data]
Pearce, Hutt, et al., 2002
Pearce, D.W.; Hutt, O.E.; Rood, S.B.; Mander, L.N.,
Gibberellins in shoots and developing capsules of Populus species,
Phytochemistry, 2002, 59, 6, 679-687, https://doi.org/10.1016/S0031-9422(02)00009-2
. [all data]
Hisamatsu, Koshioka, et al., 1998
Hisamatsu, T.; Koshioka, M.; Kubota, S.; Nishijima, T.; Yamane, H.; King, R.W.; Mander, L.N.,
Isolation and identification of GA112 (12β-hydroxy-GA12) in Matthiola incana,
Phytochemistry, 1998, 47, 1, 3-6, https://doi.org/10.1016/S0031-9422(97)00543-8
. [all data]
Webb, Appleford, et al., 1998
Webb, S.E.; Appleford, N.E.J.; Gaskin, P.; Lenton, J.R.,
Gibberellins in internodes and ears of wheat containing different dwarfing alleles,
Phytochemistry, 1998, 47, 5, 671-677, https://doi.org/10.1016/S0031-9422(97)00684-5
. [all data]
Grünzweig, Rabinowitch, et al., 1997
Grünzweig, J.M.; Rabinowitch, H.D.; Katan, J.; Wodner, M.; Ben-Tal, Y.,
Endogenous gibberellins in foliage of tomato (Lycopersicon esculentum),
Phytochemistry, 1997, 46, 5, 811-815, https://doi.org/10.1016/S0031-9422(97)00383-X
. [all data]
Kappers, Jordi, et al., 1997
Kappers, I.F.; Jordi, W.; Maas, F.M.; van der Plas, L.H.W.,
Gibberellins in leaves of Alstroemeria hybrida: identification and quantification in relation to leaf age,
J. Plant Growth Regul., 1997, 16, 4, 219-225, https://doi.org/10.1007/PL00007000
. [all data]
Pearce, Koshioka, et al., 1994
Pearce, D.W.; Koshioka, M.; Pharis, R.P.,
Chromatography of gibberellins,
J. Chromatogr. A, 1994, 658, 1, 91-122, https://doi.org/10.1016/0021-9673(94)85210-3
. [all data]
Hedden, Hoad, et al., 1993
Hedden, P.; Hoad, G.V.; Gaskin, P.; Lewis, M.J.; Green, J.R.; Furber, M.; Mander, L.N.,
Kaurenoids and gibberellins, including the newly characterized gibberellin A88, in developing apple seeds,
Phytochemistry, 1993, 32, 2, 231-237, https://doi.org/10.1016/S0031-9422(00)94973-2
. [all data]
Kobayashi, Gaskin, et al., 1993
Kobayashi, M.; Gaskin, P.; Spray, C.R.; Suzuki, Y.; Phinney, B.O.; MacMillan, J.,
Metabolism and biological activity of Gibberellin A4 in vegetative shoots of Zea mays, Oryza sativa, and Arabidopsis thaliana,
Plant Physiol., 1993, 102, 379-386. [all data]
Gaskin, Gilmour, et al., 1984
Gaskin, P.; Gilmour, S.J.; Lenton, J.R.; MacMillan, J.; Sponsel, V.M.,
Endogenous gibberellins and kauranoids identified from developing and germinating barley grain,
J. Plant Growth Regul., 1984, 2, 1-4, 229-242, https://doi.org/10.1007/BF02042252
. [all data]
Park, Nakajima, et al., 2005
Park, S.-H.; Nakajima, M.; Sakane, M.; Xu, Z.-J.; Tomioka, K.; Yamaguchi, I.,
Gibberellin 2-oxidases from seedings of Adzuki bean (Vigna angularis) show high gibberellin-binding activity in the presence os 2-oxoglutarate and Co2+,
Biosci. Biotechnol. Biochem., 2005, 69, 8, 1498-1507, https://doi.org/10.1271/bbb.69.1498
. [all data]
Oyama, Yamauchi, et al., 1996
Oyama, N.; Yamauchi, T.; Yamane, H.; Murofushi, N.; Agatsuma, M.; Pour, M.; Mander, L.N.,
Identification of gibberellins and 9,15-cyclogibberellins in developing apple seeds,
Biosci. Biotechnol. Biochem., 1996, 60, 2, 305-308, https://doi.org/10.1271/bbb.60.305
. [all data]
Lange, Kappler, et al., 2005
Lange, T.; Kappler, J.; Fischer, A.; Frisse, A.; Padeffke, T.; Schmidtke, S.; Lange, M.J.P.,
Gibberellin biosynthesis in developing pumpkin seedlings,
Plant Physiol., 2005, 139, 1, 213-223, https://doi.org/10.1104/pp.105.064162
. [all data]
Sakamoto, Kobayashi, et al., 2001
Sakamoto, T.; Kobayashi, M.; Itoh, H.; Tahiri, A.; Kayano, T.; Tanaka, H.; Iwahori, S.; Matsuoka, M.,
Expression of a gibberellin 2-oxidase gene around the shoot apex is related to phase transition in rice,
Plant Physiology, 2001, 125, 3, 1508-1516, https://doi.org/10.1104/pp.125.3.1508
. [all data]
Fos, Nuez, et al., 2000
Fos, M.; Nuez, F.; Garcia-Martinez, J.L.,
The gene pat-2, which induces natural partenocarpy, alters the gibberellin content in unpollinated tomato ovaries,
Plant Physiol., 2000, 122, 2, 471-479, https://doi.org/10.1104/pp.122.2.471
. [all data]
Talon, Zeevaart, et al., 1991
Talon, M.; Zeevaart, J.A.D.; Gage, D.A.,
Identification of gibberellins in spinach and effects of light and darkness on their levels,
Plant Physiol., 1991, 97, 4, 1521-1526, https://doi.org/10.1104/pp.97.4.1521
. [all data]
Notes
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- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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