GA34 methyl ester TMS ether
- Formula: C26H42O6Si2
- Molecular weight: 506.7791
- IUPAC Standard InChI: InChI=1S/C26H42O6Si2/c1-15-12-25-13-16(15)10-11-18(25)26-14-17(31-33(4,5)6)21(32-34(7,8)9)24(2,23(28)30-26)20(26)19(25)22(27)29-3/h16-21H,1,10-14H2,2-9H3/t16-,17+,18?,19-,20?,21+,24+,25+,26-/m0/s1
- IUPAC Standard InChIKey: MABXSEMQIJETIP-PMDKZKSBSA-N
- Chemical structure:
This structure is also available as a 2d Mol file - Stereoisomers:
- Other names: GA34, MeTMSi; GA34, Me-TMS; Gibberellin GA34, methyl ester trimethylsilyl ether; GA34, methyl ester TMS
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- Other data available:
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Normal alkane RI, non-polar column, temperature ramp
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
| Column type | Capillary | Capillary |
|---|---|---|
| Active phase | DB-5 | DB-1 |
| Column length (m) | 15. | 15. |
| Carrier gas | Helium | |
| Substrate | ||
| Column diameter (mm) | 0.25 | 0.258 |
| Phase thickness (μm) | 0.25 | |
| Tstart (C) | 60. | 160. |
| Tend (C) | 300. | 280. |
| Heat rate (K/min) | 15. | 16. |
| Initial hold (min) | 2. | 2. |
| Final hold (min) | ||
| I | 2719. | 2653. |
| Reference | Park, Nakajima, et al., 2005 | Oyama, Yamauchi, et al., 1996 |
| Comment | MSDC-RI | MSDC-RI |
References
Go To: Top, Normal alkane RI, non-polar column, temperature ramp, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Park, Nakajima, et al., 2005
Park, S.-H.; Nakajima, M.; Sakane, M.; Xu, Z.-J.; Tomioka, K.; Yamaguchi, I.,
Gibberellin 2-oxidases from seedings of Adzuki bean (Vigna angularis) show high gibberellin-binding activity in the presence os 2-oxoglutarate and Co2+,
Biosci. Biotechnol. Biochem., 2005, 69, 8, 1498-1507, https://doi.org/10.1271/bbb.69.1498
. [all data]
Oyama, Yamauchi, et al., 1996
Oyama, N.; Yamauchi, T.; Yamane, H.; Murofushi, N.; Agatsuma, M.; Pour, M.; Mander, L.N.,
Identification of gibberellins and 9,15-cyclogibberellins in developing apple seeds,
Biosci. Biotechnol. Biochem., 1996, 60, 2, 305-308, https://doi.org/10.1271/bbb.60.305
. [all data]
Notes
Go To: Top, Normal alkane RI, non-polar column, temperature ramp, References
- Symbols used in this document:
Tend Final temperature Tstart Initial temperature - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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