Fucose, tetrakis-TMS
- Formula: C18H44O5Si4
- Molecular weight: 452.8810
- IUPAC Standard InChI: InChI=1S/C18H44O5Si4/c1-15(20-24(2,3)4)17(22-26(8,9)10)18(23-27(11,12)13)16(14-19)21-25(5,6)7/h14-18H,1-13H3/t15-,16+,17+,18-/m1/s1
- IUPAC Standard InChIKey: HZBOSAPUGYAKKA-VSZNYVQBSA-N
- Chemical structure:
This structure is also available as a 2d Mol file - Stereoisomers:
- Other names: D(+)-Fucose, aldol, TMS
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Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | DB-5MS | 1740. | Medeiros and Simoneit, 2007 | 30. m/0.25 mm/0.25 μm, He, 65. C @ 2. min, 6. K/min, 300. C @ 15. min |
Normal alkane RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | HP-5 | 1704. | Isidorov, Lech, et al., 2008 | 30. m/0.25 mm/0.25 μm, Helium, 3. K/min, 300. C @ 30. min; Tstart: 50. C |
| Capillary | HP-5 | 1700. | Isidorov, Kotowska, et al., 2005 | 30. m/0.25 mm/0.25 μm, He, 5. K/min; Tstart: 50. C; Tend: 300. C |
References
Go To: Top, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Medeiros and Simoneit, 2007
Medeiros, P.M.; Simoneit, B.R.T.,
Analysis of sugars in environmental samples by gas chromatography-mass spectrometry,
J. Chromatogr. A, 2007, 1141, 2, 271-278, https://doi.org/10.1016/j.chroma.2006.12.017
. [all data]
Isidorov, Lech, et al., 2008
Isidorov, V.A.; Lech, P.; Zolciak, A.; Rusak, N.; Szczepaniak, L.,
Gas Chromatographic - nass spectrometric investigation of metabolites from the needles and roots of pine seedlings at early stages of pathogenic fungi Armillaria ostoyae attack,
Trees, 2008, 22, 4, 531-542, https://doi.org/10.1007/s00468-008-0213-z
. [all data]
Isidorov, Kotowska, et al., 2005
Isidorov, V.A.; Kotowska, U.; Vinogorova, V.T.,
GC Identification of organic compounds based on partition coefficients of their TMS derivatives in a hexane-acetonitrile system and retention indices,
Anal. Sci., 2005, 21, 12, 1483-1489, https://doi.org/10.2116/analsci.21.1483
. [all data]
Notes
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- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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