GA7 methyl ester TMS ether
- Formula: C23H32O5Si
- Molecular weight: 416.5827
- IUPAC Standard InChI: InChI=1S/C23H32O5Si/c1-13-11-22-12-14(13)7-8-15(22)23-10-9-16(28-29(4,5)6)21(2,20(25)27-23)18(23)17(22)19(24)26-3/h9-10,14-18H,1,7-8,11-12H2,2-6H3/t14?,15-,16+,17-,18-,21-,22+,23-/m0/s1
- IUPAC Standard InChIKey: QYWOOSKTNLXOPW-DTOPKNIOSA-N
- Chemical structure:
This structure is also available as a 2d Mol file - Stereoisomers:
- Other names: [14C1]GA7 methyl ester TMS ether; [14C]GA7 methyl ester TMS ether
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Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Van Den Dool and Kratz RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | OV-1 | 2525. | Davis, Kobayashi, et al., 1999 | 25. m/0.2 mm/0.25 μm, He; Program: 60C(2min) => 10C/min => 150C => 3C/min => 300C(10min) |
| Capillary | OV-1 | 2525. | Davis, Kobayashi, et al., 1999 | 25. m/0.2 mm/0.25 μm, He; Program: 60C(2min) => 10C/min => 150C => 3C/min => 300C(10min) |
| Capillary | OV-1 | 2520. | Davis, Kobayashi, et al., 1999 | 25. m/0.2 mm/0.25 μm, He; Program: 60C(2min) => 10C/min => 150C => 3C/min => 300C(10min) |
| Capillary | OV-1 | 2522. | Davis, Kobayashi, et al., 1999 | 25. m/0.2 mm/0.25 μm, He; Program: 60C(2min) => 10C/min => 150C => 3C/min => 300C(10min) |
| Capillary | BP-1 | 2520. | MacMillan, Ward, et al., 1997 | 25. m/0.2 mm/0.1 μm, He; Program: 60C(2min) => 10C/min => 150C => 3C/min => 300C(10min) |
| Capillary | BP-1 | 2521. | MacMillan, Ward, et al., 1997 | 25. m/0.2 mm/0.1 μm, He; Program: 60C(2min) => 10C/min => 150C => 3C/min => 300C(10min) |
| Capillary | BP-1 | 2521. | MacMillan, Ward, et al., 1997 | 25. m/0.2 mm/0.1 μm, He; Program: 60C(2min) => 10C/min => 150C => 3C/min => 300C(10min) |
| Capillary | BP-1 | 2522. | MacMillan, Ward, et al., 1997 | 25. m/0.2 mm/0.1 μm, He; Program: 60C(2min) => 10C/min => 150C => 3C/min => 300C(10min) |
| Capillary | BP-1 | 2522. | MacMillan, Ward, et al., 1997 | 25. m/0.2 mm/0.1 μm, He; Program: 60C(2min) => 10C/min => 150C => 3C/min => 300C(10min) |
| Capillary | BP-1 | 2519. | MacMillan and Gaskin, 1996 | 25. m/0.2 mm/0.1 μm, He; Program: 60C(2min) => 10C/min => 150C => 3C/min => 300C(10min) |
Normal alkane RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | Ultra-2 | 2511. | Talon, Zeevaart, et al., 1991 | 25. m/0.32 mm/0.52 μm; Program: 50C => 40C/min => 220C => 8C/min => 280C |
References
Go To: Top, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Davis, Kobayashi, et al., 1999
Davis, G.; Kobayashi, M.; Phinney, B.O.; Lange, T.; Croker, S.J.; Gaskin, P.; MacMillan, J.,
Gibberellin biosynthesis in maize. Metabolic studies with GA15, GA24, GA25, GA7, and 2,3-dehydro-GA9,
Plant Physiol., 1999, 121, 3, 1037-1045, https://doi.org/10.1104/pp.121.3.1037
. [all data]
MacMillan, Ward, et al., 1997
MacMillan, J.; Ward, D.A.; Phillips, A.L.; Sánchez-Beltrán, M.J.; Gaskin, P.; Lange, T.; Hedden, P.,
Gibberellin biosynthesis from gibberellin A12-aldehyde in endosperm and embryos of Marah macrocarpus,
Plant Physiol., 1997, 113, 4, 1369-1377, https://doi.org/10.1104/pp.113.4.1369
. [all data]
MacMillan and Gaskin, 1996
MacMillan, J.; Gaskin, P.,
Gibberellins in endosperm and embryos of Marah macrocarpus,
Phytochemistry, 1996, 42, 5, 1263-1266, https://doi.org/10.1016/0031-9422(96)00179-3
. [all data]
Talon, Zeevaart, et al., 1991
Talon, M.; Zeevaart, J.A.D.; Gage, D.A.,
Identification of gibberellins in spinach and effects of light and darkness on their levels,
Plant Physiol., 1991, 97, 4, 1521-1526, https://doi.org/10.1104/pp.97.4.1521
. [all data]
Notes
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- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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