B-Fructofuranose, TMS
- Formula: C21H52O6Si5
- Molecular weight: 541.0615
- IUPAC Standard InChI: InChI=1S/C21H52O6Si5/c1-28(2,3)22-16-18-19(25-30(7,8)9)20(26-31(10,11)12)21(24-18,27-32(13,14)15)17-23-29(4,5)6/h18-20H,16-17H2,1-15H3/t18-,19-,20+,21+/m0/s1
- IUPAC Standard InChIKey: PLNWQGWZBNJIQM-UWHLTILDSA-N
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
View 3d structure (requires JavaScript / HTML 5) - Species with the same structure:
- Stereoisomers:
- A-Fructofuranose, TMS
- α-Sorbose, TMS
- α-Allofuranose, TMS
- A-Psicofuranose, TMS
- A-Sorbofuranose, TMS
- A-Tagatofuranose, TMS
- B-Psicofuranose, TMS
- B-Sorbofuranose, TMS
- B-Tagatofuranose, TMS
- α-Mannofuranose, TMS
- α-Talofuranose, TMS
- β-Idofuranose, TMS
- β-Talofuranose, TMS
- D-(-)-Tagatofuranose, pentakis(trimethylsilyl) ether (isomer 1)
- D-(-)-Tagatofuranose, pentakis(trimethylsilyl) ether (isomer 2)
- D-Psicofuranose, pentakis(trimethylsilyl) ether (isomer 1)
- D-Psicofuranose, pentakis(trimethylsilyl) ether (isomer 2)
- L-(-)-Sorbofuranose, pentakis(trimethylsilyl) ether
- D-(-)-Fructofuranose, pentakis(trimethylsilyl) ether (isomer 1)
- D-(-)-Fructofuranose, pentakis(trimethylsilyl) ether (isomer 2)
- Other names: β-Fructose, TMS
- Information on this page:
- Other data available:
- Options:
Kovats' RI, non-polar column, isothermal
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
| Column type | Capillary | Packed |
|---|---|---|
| Active phase | OV-1 | SE-30 |
| Column length (m) | 25. | 3. |
| Carrier gas | N2 | |
| Substrate | Supelcoport (80-100mesh) | |
| Column diameter (mm) | 0.22 | |
| Phase thickness (μm) | ||
| Temperature (C) | 180. | 210. |
| I | 1857. | 1859. |
| Reference | Garcia-Raso, Fernandez-Diaz, et al., 1989 | Saura-Calixto, Cañellas, et al., 1984 |
| Comment | MSDC-RI | MSDC-RI |
References
Go To: Top, Kovats' RI, non-polar column, isothermal, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Garcia-Raso, Fernandez-Diaz, et al., 1989
Garcia-Raso, A.; Fernandez-Diaz, M.; Paez, M.I.; Sanz, J.; Martinez-Castro, I.,
Gas Chromatographic Retention of Carbohydrate Trimethylsilyl Ethers. III. Ketohexoses,
J. Chromatogr., 1989, 471, 205-216, https://doi.org/10.1016/S0021-9673(00)94168-2
. [all data]
Saura-Calixto, Cañellas, et al., 1984
Saura-Calixto, F.; Cañellas, J.; García-Raso, A.,
Gas chromatograph analysis of surgars and sugar-alcohols in the mesocarp, endocarp, and kernel of almond fruit,
J. Agric. Food Chem., 1984, 32, 5, 1018-1020, https://doi.org/10.1021/jf00125a017
. [all data]
Notes
Go To: Top, Kovats' RI, non-polar column, isothermal, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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