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CH3OCl+


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   F


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 54140 ± 560 gas Colbourne, Frost, et al., 1981

State:   D,E


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 45670 ± 560 gas Colbourne, Frost, et al., 1981

State:   C


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 25250 ± 560 gas Colbourne, Frost, et al., 1981

State:   B


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 21700 ± 560 gas Colbourne, Frost, et al., 1981

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 10890 ± 320 gas Colbourne, Frost, et al., 1981

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' OCl stretch 710 ± 50 gas PE Colbourne, Frost, et al., 1981

Additional references: Jacox, 1994, page 322

Notes

xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Colbourne, Frost, et al., 1981
Colbourne, D.; Frost, D.C.; McDowell, C.A.; Westwood, N.P.C., The He(I) photoelectron spectra of the alkyl hypochlorites, ROCl (R = Me, Et and t-Bu), J. Electron Spectrosc. Relat. Phenom., 1981, 23, 109. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]


Notes

Go To: Top, Vibrational and/or electronic energy levels, References