NH2BF2+

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   H
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 74200 ± 1600 gas Kingsmill, Werstiuk, et al., 1987

State:   G
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 63900 ± 1100 gas Kingsmill, Werstiuk, et al., 1987

State:   F
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 58500 ± 1100 gas Kroto and McNaughton, 1985
Kingsmill, Werstiuk, et al., 1987

State:   E
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 49700 ± 1100 gas Kingsmill, Werstiuk, et al., 1987

State:   D
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 48400 ± 1600 gas Kroto and McNaughton, 1985
Kingsmill, Werstiuk, et al., 1987

State:   B,C
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 35700 ± 1100 gas Kroto and McNaughton, 1985
Kingsmill, Werstiuk, et al., 1987

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 32400 ± 1100 gas Kroto and McNaughton, 1985
Kingsmill, Werstiuk, et al., 1987

Additional references: Jacox, 1994, page 332

Notes

xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kingsmill, Werstiuk, et al., 1987
Kingsmill, C.A.; Werstiuk, N.H.; Westwood, N.P.C., Helium (He I) photoelectron spectra of the unstable substituted aminoboranes, aminodifluoro-, aminodichloro-, and aminodibromoborane. An experimental and theoretical study, J. Am. Chem. Soc., 1987, 109, 10, 2870, https://doi.org/10.1021/ja00244a002 . [all data]

Kroto and McNaughton, 1985
Kroto, H.W.; McNaughton, D., Photoelectron spectra of the aminodifluoroboranes NH2BF2, NHMeBF2, and NMe2BF2, J. Chem. Soc. Dalton Trans., 1985, 1767. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Notes

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