Cl2CS+


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   H


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

To = 68420 ± 320 gas Chadwick, 1972
Wittel, Haas, et al., 1972
Mines, Thomas, et al., 1973

State:   G


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

To = 51480 ± 320 gas Chadwick, 1972
Wittel, Haas, et al., 1972
Mines, Thomas, et al., 1973

State:   F


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

To = 43410 ± 320 gas Chadwick, 1972
Wittel, Haas, et al., 1972
Mines, Thomas, et al., 1973


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 3 CCl2 scissors 270 ± 80 gas PE Mines, Thomas, et al., 1973

State:   E


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

To = 37280 ± 320 gas Chadwick, 1972
Wittel, Haas, et al., 1972
Mines, Thomas, et al., 1973


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 2 CCl2 stretch 380 ± 60 gas PE Chadwick, 1972
Mines, Thomas, et al., 1973

State:   D


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

Tx = 24850 ± 320 gas Chadwick, 1972
Wittel, Haas, et al., 1972
Mines, Thomas, et al., 1973


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 3 CCl2 scissors 260 ± 40 gas PE Chadwick, 1972
Mines, Thomas, et al., 1973

State:   C


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

Tx = 22350 ± 320 gas Chadwick, 1972
Wittel, Haas, et al., 1972
Mines, Thomas, et al., 1973


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 3 CCl2 scissors 255 ± 80 gas PE Mines, Thomas, et al., 1973

State:   B


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

To = 16620 ± 320 gas Chadwick, 1972
Wittel, Haas, et al., 1972
Mines, Thomas, et al., 1973

State:   A


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

To = 8390 ± 320 gas Chadwick, 1972
Wittel, Haas, et al., 1972
Mines, Thomas, et al., 1973


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 CS stretch 900 ± 60 gas PE Chadwick, 1972
Wittel, Haas, et al., 1972
Mines, Thomas, et al., 1973

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 CS stretch 1060 ± 40 T gas PE Chadwick, 1972
Mines, Thomas, et al., 1973
3 CCl2 scissors 265 ± 40 gas PE Chadwick, 1972
Mines, Thomas, et al., 1973

Additional references: Jacox, 1994, page 206

Notes

TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chadwick, 1972
Chadwick, D., Photoelectron spectra of phosgene and thiophosgene, Can. J. Chem., 1972, 50, 737. [all data]

Wittel, Haas, et al., 1972
Wittel, K.; Haas, A.; Bock, H., Photoelektronenspektren und Moleküleigenschaften, XVI Thiocarbonylhalogenide -- Orbitale und Ladungen, Chem. Ber., 1972, 105, 12, 3865, https://doi.org/10.1002/cber.19721051215 . [all data]

Mines, Thomas, et al., 1973
Mines, G.W.; Thomas, R.K.; Thompson, H., The photoelectron spectra of thiocarbonyl fluoride and thiocarbonyl chloride, Proc. R. Soc. London A:, 1973, 333, 171. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]


Notes

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