F2SO2+


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   G


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 53730 ± 140 gas DeKock, Lloyd, et al., 1972
Mines, Thomas, et al., 1972
Chadwick, Frost, et al., 1973


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 2 SF2 stretch 855 ± 30 gas PE DeKock, Lloyd, et al., 1972
Chadwick, Frost, et al., 1973
3 SO2 scissors 500 ± 20 gas PE DeKock, Lloyd, et al., 1972
Chadwick, Frost, et al., 1973

State:   F


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 49500 ± 140 gas DeKock, Lloyd, et al., 1972
Mines, Thomas, et al., 1972


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 2 SF2 stretch 850 ± 30 gas PE DeKock, Lloyd, et al., 1972
3 SO2 scissors 485 ± 40 gas PE DeKock, Lloyd, et al., 1972

State:   E


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 40580 ± 320 gas DeKock, Lloyd, et al., 1972
Mines, Thomas, et al., 1972
Chadwick, Frost, et al., 1973

State:   D


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 29340 ± 120 gas DeKock, Lloyd, et al., 1972
Mines, Thomas, et al., 1972
Chadwick, Frost, et al., 1973


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 SO2 stretch 1135 ± 16 gas PE DeKock, Lloyd, et al., 1972
Mines, Thomas, et al., 1972
Chadwick, Frost, et al., 1973
2 SF2 stretch 805 ± 30 gas PE DeKock, Lloyd, et al., 1972
Mines, Thomas, et al., 1972
Chadwick, Frost, et al., 1973
3 SO2 scissors 510 ± 20 gas PE DeKock, Lloyd, et al., 1972
Mines, Thomas, et al., 1972
Chadwick, Frost, et al., 1973

State:   C


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 17270 ± 130 gas DeKock, Lloyd, et al., 1972
Mines, Thomas, et al., 1972
Chadwick, Frost, et al., 1973


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 SO2 stretch 1025 ± 30 gas PE DeKock, Lloyd, et al., 1972
Mines, Thomas, et al., 1972
Chadwick, Frost, et al., 1973

State:   B


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 14600 ± 160 gas DeKock, Lloyd, et al., 1972
Mines, Thomas, et al., 1972
Chadwick, Frost, et al., 1973


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 4 SF2 scissors 340 ± 16 gas PE DeKock, Lloyd, et al., 1972
Mines, Thomas, et al., 1972
Chadwick, Frost, et al., 1973

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 4280 ± 240 gas DeKock, Lloyd, et al., 1972
Mines, Thomas, et al., 1972
Chadwick, Frost, et al., 1973


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 3 SO2 scissors 475 ± 60 gas PE DeKock, Lloyd, et al., 1972
Mines, Thomas, et al., 1972
Chadwick, Frost, et al., 1973

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 370 ± 40 gas PE DeKock, Lloyd, et al., 1972

Additional references: Jacox, 1994, page 300

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

DeKock, Lloyd, et al., 1972
DeKock, R.L.; Lloyd, D.R.; Hillier, I.H.; Saunders, V.R., Experimental and theoretical study of the electronic structures of sulphuryl fluoride and perchloryl fluoride, Proc. R. Soc. London A:, 1972, 328, 401. [all data]

Mines, Thomas, et al., 1972
Mines, G.W.; Thomas, R.K.; Thompson, H., Photoelectron spectra of compounds containing thionyl and sulphuryl groups, Proc. R. Soc. London A:, 1972, 329, 275. [all data]

Chadwick, Frost, et al., 1973
Chadwick, D.; Frost, D.C.; Herring, F.G.; Katrib, A.; McDowell, C.A.; McLean, R.A.N., Photoelectron spectra of sulfuryl and thionyl halides, Can. J. Chem., 1973, 51, 1893. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]


Notes

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