Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

NOTICE: Due to scheduled maintenance at our Gaithersburg campus, this site will not be available from 5:00 pm EDT (21:00 UTC) on Friday October 25 until 5:00 pm (21:00 UTC) on Sunday October 27. We apologize for any inconvenience this outage may cause.

ClNO+


Vibrational and/or electronic energy levels

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   E


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 61800 ± 240 gas Frost, Lee, et al., 1975
Abbas, Dyke, et al., 1976


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 1 NO stretch 910 T gas PE Abbas, Dyke, et al., 1976
3 NCl stretch 520 ± 30 gas PE Abbas, Dyke, et al., 1976

State:   D


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 46800 ± 160 gas Frost, Lee, et al., 1975
Abbas, Dyke, et al., 1976


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 1 NO stretch 1250 ± 30 gas PE Frost, Lee, et al., 1975
Abbas, Dyke, et al., 1976
3 NCl stretch 580 T gas PE Abbas, Dyke, et al., 1976

State:   C


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 36550 ± 160 gas Frost, Lee, et al., 1975
Abbas, Dyke, et al., 1976


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 1 NO stretch 1560 ± 30 gas PE Abbas, Dyke, et al., 1976
3 NCl stretch 520 ± 30 gas PE Abbas, Dyke, et al., 1976

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 3 NCl stretch 540 ± 30 gas PE Abbas, Dyke, et al., 1976

Additional references: Jacox, 1994, page 93; Alderdice and Dixon, 1977

Notes

TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Frost, Lee, et al., 1975
Frost, D.C.; Lee, S.T.; McDowell, C.A.; Westwood, N.P.C., Photoelectron spectroscopic studies of some nitrosyl and nitryl halides nitric acid, J. Electron Spectrosc. Relat. Phenom., 1975, 7, 331. [all data]

Abbas, Dyke, et al., 1976
Abbas, M.I.; Dyke, J.M.; Morris, A., J. Chem. Soc., 1976, Faraday Trans. 2 814. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Alderdice and Dixon, 1977
Alderdice, R.S.; Dixon, R.N., J. Chem. Soc., 1977, Faraday Trans. 73, 245. [all data]


Notes

Go To: Top, Vibrational and/or electronic energy levels, References