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FClCS+


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   F


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Txx = 62930 ± 400 gas Wittel, Haas, et al., 1972

State:   E


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Txx = 51640 ± 400 gas Wittel, Haas, et al., 1972

State:   D


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Txx = 32110 ± 320 gas Wittel, Haas, et al., 1972


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 CS stretch 1130 ± 40 gas PE Wittel, Haas, et al., 1972

State:   C


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Txx = 27270 ± 320 gas Wittel, Haas, et al., 1972


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 1 CS stretch 1130 ± 40 gas PE Wittel, Haas, et al., 1972

State:   B


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Txx = 21380 ± 320 gas Wittel, Haas, et al., 1972

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Txx = 8070 ± 320 gas Wittel, Haas, et al., 1972


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 1 CS stretch 1080 ± 40 gas PE Wittel, Haas, et al., 1972

Additional references: Jacox, 1994, page 205

Notes

xxEnergy separation between the band maxima of both the excited state and the ground state of a molecular cation, derived from a photoelectron spectrum.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wittel, Haas, et al., 1972
Wittel, K.; Haas, A.; Bock, H., Photoelektronenspektren und Moleküleigenschaften, XVI Thiocarbonylhalogenide -- Orbitale und Ladungen, Chem. Ber., 1972, 105, 12, 3865, https://doi.org/10.1002/cber.19721051215 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]


Notes

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