SiF3Br+

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   G
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 67290 ± 320 gas Cradock, Ebsworth, et al., 1973
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 SiF3 stretch 755 ± 40 gas PE Cradock, Ebsworth, et al., 1973
3 Deformation 240 ± 40 gas PE Cradock, Ebsworth, et al., 1973

State:   F
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 51150 ± 320 gas Cradock, Ebsworth, et al., 1973

State:   E
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 45500 ± 320 gas Cradock, Ebsworth, et al., 1973
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 SiF3 stretch 850 ± 40 gas PE Cradock, Ebsworth, et al., 1973

State:   D
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 39530 ± 320 gas Cradock, Ebsworth, et al., 1973

State:   C
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 33640 ± 320 gas Cradock, Ebsworth, et al., 1973

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 29370 ± 320 gas Cradock, Ebsworth, et al., 1973

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 16860 ± 320 gas Cradock, Ebsworth, et al., 1973

Additional references: Jacox, 1994, page 295

Notes

xxEnergy separation between the band maxima of both the excited state and the ground state of a molecular cation, derived from a photoelectron spectrum.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cradock, Ebsworth, et al., 1973
Cradock, S.; Ebsworth, E.A.V.; Robertson, A., Photoelectron spectra of some silyl and germyl transition-metal carbonyls and related specis, J. Chem. Soc. Dalton Trans., 1973, 22. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Notes

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