Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Fe+ (structure unspecified)

Gas phase ion energetics data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Reactions leading to Fe+ (ion structure unspecified)

Precursor AP (eV) Other Products Method Reference Comment
Br2Fe16.6 ± 0.5?EIPorter and Schoonmaker, 1959 
CH2Fe3.5 ± 0.2CH2PIHettich and Freiser, 1986 
C5FeO514.595COPIPECOFieber-Erdmann, Holub-Krappe, et al., 1995 
C5FeO514.383 ± 0.0675COPIPECONorwood, Ali, et al., 1990 
C5FeO516.2 ± 0.25COEIClements and Sale, 1976 
C5FeO514.2 ± 0.15COPIDistefano, 1970 
C5FeO515.995COEIJunk and Svec, 1968 
C5FeO515.3 ± 0.15COEIBidinosti and McIntyre, 1967 
C5FeO514.7 ± 0.15COEIFoffani, Pignataro, et al., 1965 
C5FeO516.1 ± 0.25COEIWinters and Kiser, 1964 
C8H8FeO214.95 ± 0.15C5H5+2CO+CH3LS,EIBruch, Bunau, et al., 1995 
C10H8Cl2Fe15.0 ± 0.5?EIBarfuss, Grade, et al., 1987 
C10H8Cl2Fe13.7 ± 0.1?PIBarfuss, Emrich, et al., 1990 
C10H8Cl2Fe15.4 ± 0.3?EIBarfuss, Emrich, et al., 1990 
C10H10Fe14.3 ± 0.22C5H5PIBarfuss, Emrich, et al., 1990 
C10H10Fe14.7 ± 0.32C5H5EIBarfuss, Grade, et al., 1987 
C10H10Fe13.506 ± 0.0372C5H5PIBar, Heinis, et al., 1982 
C10H10Fe12.0 ± 1.52C5H5EIBegun and Compton, 1973 
C10H10Fe14.00 ± 0.252C5H5EIFlesch, Junk, et al., 1972 
C10H10Fe14.10 ± 0.152C5H5EIPuttemans and Hanson, 1971 
C10H10Fe14.4 ± 0.5?EIMuller and D'Or, 1967 
C10H18FeN3O4P17.0 ± 0.05?EISaalfeld, DeCorpo, et al., 1972 
C11H8FeO313.55 ± 0.153CO+C8H8EIOpitz, Bruch, et al., 1994 
C12H14Fe14.9 ± 0.3?EIBarfuss, Emrich, et al., 1990 
C12H14Fe16.7 ± 0.3?EIBarfuss, Emrich, et al., 1990 
C13H18FeO215.65 ± 0.20C10H10+2CO+CH3LS,EIBruch, Bunau, et al., 1995 
C14H10Fe2O2S220.21 ± 0.03?EIEfraty, Liebman, et al., 1978 
C14H10Fe2O3S20.94 ± 0.03?EIEfraty, Liebman, et al., 1978 
Cl2Fe16.5 ± 0.5?EISchoonmaker and Porter, 1958 
F2Fe16.5 ± 0.3?EIKent and Margrave, 1965 
F3Fe20.5 ± 0.3?EIZmbov and Margrave, 1967 
FeI213.63 ± 0.152IPIGrade and Rosinger, 1985 
FeI27.9 ± 0.2I2EIGrade and Rosinger, 1984 


Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Porter and Schoonmaker, 1959
Porter, R.F.; Schoonmaker, R.C., A mass spectrometric study of the vaporization of ferrous bromide, J. Phys. Chem., 1959, 63, 626. [all data]

Hettich and Freiser, 1986
Hettich, R.L.; Freiser, B.S., Gas-phase photodissociation of FeCH2+ and CoCH2+: Determination of the carbide, carbyne, and carbene bond energies, J. Am. Chem. Soc., 1986, 108, 2537. [all data]

Fieber-Erdmann, Holub-Krappe, et al., 1995
Fieber-Erdmann, M.; Holub-Krappe, E.; Broker, G.; Dujardin, G.; Ding, A., Fragmentation psectroscopy of photoionized Fe(CO)5: a molecular model for a heterogeneous cluster, Int. J. Mass Spectrom. Ion Processes, 1995, 149/150, 513. [all data]

Norwood, Ali, et al., 1990
Norwood, K.; Ali, A.; Flesch, G.D.; Ng, C.Y., A photoelectron-photoion coincidence study of Fe(CO)5, J. Am. Chem. Soc., 1990, 112, 7502. [all data]

Clements and Sale, 1976
Clements, P.J.; Sale, F.R., A mass spectrometric study of nickel tetracarbonyl, iron pentacarbonyl and binary mixtures of these compounds, Metall. Trans. B:, 1976, 7, 171. [all data]

Distefano, 1970
Distefano, G., Photoionization study of Fe(CO)5 and Ni(CO)4, J. Res. NBS, 1970, 74A, 233. [all data]

Junk and Svec, 1968
Junk, G.A.; Svec, H.J., Energetics of the ionization and dissociation of Ni(CO)4, Fe(CO)5, Cr(CO)6, Mo(CO)6 and W(CO)6, Z. Naturforsch., 1968, 23b, 1. [all data]

Bidinosti and McIntyre, 1967
Bidinosti, D.R.; McIntyre, N.S., Electron-impact study of some binary metal carbonyls, Can. J. Chem., 1967, 45, 641. [all data]

Foffani, Pignataro, et al., 1965
Foffani, A.; Pignataro, S.; Cantone, B.; Grasso, F., Mass spectra of metal hexacarbonyls, Z. Physik. Chem. (Frankfurt), 1965, 45, 79. [all data]

Winters and Kiser, 1964
Winters, R.E.; Kiser, R.W., A mass spectrometric investigation of nickel tetracarbonyl and iron pentacarbonyl, Inorg. Chem., 1964, 3, 699. [all data]

Bruch, Bunau, et al., 1995
Bruch, D.; Bunau, G.v.; Schindler, W.; Kisch, H., Electron impact and multiphoton ionization and fragmentation of dicarbonyl cyclopentadienyl methyl iron and pentamethylcyclopentadienyl dicarbonyl methyl iron, Int. J. Mass Spectrom. Ion Processes, 1995, 148, 105. [all data]

Barfuss, Grade, et al., 1987
Barfuss, S.; Grade, M.; Hirschwald, W.; Rosinger, W., The stability and decomposition of gaseous chloroferrocenes, J. Vac. Sci. Technol. A:, 1987, 5, 1451. [all data]

Barfuss, Emrich, et al., 1990
Barfuss, S.; Emrich, R.-H.; Hirschwald, W.; Dowben, P.A.; Boag, N.M., A mass spectrometric investigation of chloro-, bromo- and methyl-ferrocenes by electron and photon impact ionisation, J. Org. Chem., 1990, 391, 209. [all data]

Bar, Heinis, et al., 1982
Bar, R.; Heinis, T.; Nager, C.; Jungen, M., Photoionization of ferrocene, Chem. Phys. Lett., 1982, 91, 440. [all data]

Begun and Compton, 1973
Begun, G.M.; Compton, R.N., Electron impact ionization studies of ferrocene, cobaltocene, nickelocene, and magnesocene, J. Chem. Phys., 1973, 58, 2271. [all data]

Flesch, Junk, et al., 1972
Flesch, G.D.; Junk, G.A.; Svec, H.J., Ionization efficiency data and fragmentation mechanisms for ferrocene, nickelocene, and ruthenocene, J. Chem. Soc. Dalton Trans., 1972, 1102. [all data]

Puttemans and Hanson, 1971
Puttemans, J.-P.; Hanson, A., Etude energetique du ferrocene et du cobaltocene par impact electronique. Enthalpie de formation du radical cyclopentadienyle, Ing. Chim. (Brussels), 1971, 53, 17. [all data]

Muller and D'Or, 1967
Muller, J.; D'Or, L., Massenspektrometrische Untersuchungen an Dicyclopentadienylkomplexen von Ubergangsmetallen, J.Organometal. Chem., 1967, 10, 313. [all data]

Saalfeld, DeCorpo, et al., 1972
Saalfeld, F.E.; DeCorpo, J.J.; McDowell, M.V., The mass spectra of some metal carbonyl complexes of tris(dimethylamino)phosphine, J. Organomet. Chem., 1972, 44, 333. [all data]

Opitz, Bruch, et al., 1994
Opitz, J.; Bruch, D.; VonBunau, G., Multiphoton excitation of tricarbonyl-cyclooctatetraene-iron. Wavelength-dependent competition between ionization and dissociation, Int. J. Mass Spectrom. Ion Processes, 1994, 135, 181. [all data]

Efraty, Liebman, et al., 1978
Efraty, A.; Liebman, D.; Huang, M.H.A.; Weston, C.A.; Angelici, R.J., Mass spectra of organometallic compounds. 7. Electron-impact study of some cyclopentadienylmetal thiocarbonyl-bridged dimers, Inorg. Chem., 1978, 17, 2831. [all data]

Schoonmaker and Porter, 1958
Schoonmaker, R.C.; Porter, R.F., Mass spectrometric study of ferrous chloride vapor, J. Chem. Phys., 1958, 29, 116. [all data]

Kent and Margrave, 1965
Kent, R.A.; Margrave, J.L., Mass spectrometric studies at high temperatures. VIII. The sublimation pressure of iron(II) fluoride, J. Am. Chem. Soc., 1965, 87, 4754. [all data]

Zmbov and Margrave, 1967
Zmbov, K.F.; Margrave, J.L., Mass spectrometric studies at high temperatures. XV.Sublimation pressures of chromium, manganese and iron trifluoridcs and the heat of dissociation of Fe,F,(g), J. Inorg. Nucl. Chem., 1967, 29, 673. [all data]

Grade and Rosinger, 1985
Grade, M.; Rosinger, W., Correlation of electronic structures and stabilities of gaseous FeI2, Fe2I2 and Fe2I4 molecules, solid [FeI2], and iodine adsorbed on [Fe], Surf. Sci., 1985, 156, 920. [all data]

Grade and Rosinger, 1984
Grade, M.; Rosinger, W., A mass spectrometric investigation of iron(II)-iodide, Ber. Bunsen-Ges. Phys. Chem., 1984, 88, 767. [all data]


Go To: Top, Gas phase ion energetics data, References