F5S+ (structure unspecified)
- Formula: F5S+
- Molecular weight: 127.056
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Reactions leading to F5S+ (ion structure unspecified)
| Precursor | AP (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| ClF5S | 12.32 | Cl | PI | Baumgartel, Jochims, et al., 1989 | |
| ClF5S | 13.2 ± 0.2 | Cl | EI | Harland and Thynne, 1969 | |
| F6S | 15.32 ± 0.04 | F | PI | Mitsuke, Suzuki, et al., 1990 | |
| F6S | ≤13.78 | F | IMB | Stone and Wytenberg, 1989 | T = 298K |
| F6S | 13.97 ± 0.04 | F | END | Tichy, Javahery, et al., 1987 | |
| F6S | ≤14.4 | F | IMB | Shul, Upschulte, et al., 1987 | |
| F6S | 14.62 ± 0.09 | F | IMB | Babcock and Streit, 1981 | |
| F6S | 15.3 ± 0.2 | F | PI | Sasanuma, Ishiguro, et al., 1979 | |
| F6S | 16.2 ± 0.2 | F | EI | Pullen and Stockdale, 1976 | |
| F6S | ≤14.53 ± 0.05 | F | PIPECO | Simm, Danby, et al., 1975 | |
| F6S | 15.50 ± 0.10 | F | EI | Hildenbrand, 1973 | |
| F6S | 15.75 ± 0.05 | F | PE | Delwiche, 1969 | |
| F6S | 15.75 ± 0.05 | F | EI | Delwiche, 1969 | |
| F6S | 15.29 | F | PI | Dibeler and Walker, 1966 | |
| F6S | 15.85 ± 0.15 | F | EI | Fox and Curran, 1961 | |
| F6S | 15.9 ± 0.2 | F | EI | Dibeler and Mohler, 1948 | |
| F7NS | 12.0 ± 0.2 | ? | EI | Paulett and Lustig, 1965 |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Baumgartel, Jochims, et al., 1989
Baumgartel, H.; Jochims, H.-W.; Ruhl, E.,
Photoionenspektroskopic an schwefelchloridpentafluorid SF5Cl, das ionisationspotential von schwefelpentafluorid SF5,
Z. Naturforsch. B:, 1989, 44, 21. [all data]
Harland and Thynne, 1969
Harland, P.; Thynne, J.C.J.,
Ionization and dissociation of pentafluorosulfur chloride by electron impact,
J. Phys. Chem., 1969, 73, 4031. [all data]
Mitsuke, Suzuki, et al., 1990
Mitsuke, K.; Suzuki, S.; Imamura, T.; Koyano, I.,
Negative-ion mass spectrometric study of ion-pair formation in the vacuum ultraviolet. III. SF6 Ü F- + SF5+,
J. Chem. Phys., 1990, 93, 8717. [all data]
Stone and Wytenberg, 1989
Stone, J.A.; Wytenberg, W.J.,
A high pressure mass spectrometric study of the formation and chemistry of the pentafluorosulphur cation (SF5+),
Int. J. Mass Spectrom. Ion Processes, 1989, 94, 269. [all data]
Tichy, Javahery, et al., 1987
Tichy, M.; Javahery, G.; Twiddy, N.D.; Ferguson, E.E.,
The thermal energy reactions HCl+ + SF6 Ü SF5+ + HF + Cl and HCl+ + CF4 Ü CF3+ + HF + Cl,
Int. J. Mass Spectrom. Ion Processes, 1987, 79, 231. [all data]
Shul, Upschulte, et al., 1987
Shul, R.J.; Upschulte, B.L.; Passarella, R.; Keesee, R.G.; Castleman, A.W.,
Thermal energy charge-transfer reactions of Ar+ and Ar2+,
J. Phys. Chem., 1987, 91, 2556. [all data]
Babcock and Streit, 1981
Babcock, L.M.; Streit, G.E.,
Ion-molecule reactions of SF6: Determination of I. P. (SF6), A. P.(SF5+/SF6), and D(SF5-F),
J. Chem. Phys., 1981, 74, 5700. [all data]
Sasanuma, Ishiguro, et al., 1979
Sasanuma, M.; Ishiguro, E.; Hayaisha, T.; Masuko, H.; Morioka, Y.; Nakajima, T.; Nakamura, M.,
Photoionisation of SF6 in the XUV region,
J. Phys. B:, 1979, 12, 4057. [all data]
Pullen and Stockdale, 1976
Pullen, B.P.; Stockdale, J.A.D.,
Dissociative ionization of SF6 by electron impact,
Int. J. Mass Spectrom. Ion Phys., 1976, 19, 35. [all data]
Simm, Danby, et al., 1975
Simm, I.G.; Danby, C.J.; Eland, J.H.D.; Mansell, P.I.,
Translational energy release in the loss of fluorine atoms from the ions SF6+, CF4+ and C2F6+,
J. Chem. Soc., 1975, 426. [all data]
Hildenbrand, 1973
Hildenbrand, D.L.,
Mass spectrometric studies of some gaseous sulfur fluorides,
J. Phys. Chem., 1973, 77, 897. [all data]
Delwiche, 1969
Delwiche, J.,
Ionization of sulphur hexafluoride by photon and electron impact,
Bull. Classe Sci. Acad. Roy. Belg., 1969, 55, 215. [all data]
Dibeler and Walker, 1966
Dibeler, V.H.; Walker, J.A.,
Photoionization efficiency curve for SF6 in the wavelength region 1050 to 600,
J. Chem. Phys., 1966, 44, 4405. [all data]
Fox and Curran, 1961
Fox, R.E.; Curran, R.K.,
Ionization processes in CCl4 and SF6 by electron beams,
J. Chem. Phys., 1961, 34, 1595. [all data]
Dibeler and Mohler, 1948
Dibeler, V.H.; Mohler, F.L.,
Dissociation of SF6, CF4, and SiF4 by electron impact,
J. Res. Natl. Bur. Stand. U.S., 1948, 40, 25. [all data]
Paulett and Lustig, 1965
Paulett, G.S.; Lustig, M.,
Sulfur-nitrogen and oxygen-nitrogen bond dissociation energies of some N-fluorinated amines,
J. Am. Chem. Soc., 1965, 87, 1020. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
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