CHS+ (structure unspecified)


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Reactions leading to CHS+ (ion structure unspecified)

Precursor AP (eV) Other Products Method Reference Comment
CH2S11.533 ± 0.021HPIRuscic and Berkowitz, 1993 
CH4S≤13.61 ± 0.04H+H2PIKutina, Edwards, et al., 1982T = 0K
CH4S≤13.55 ± 0.04H+H2PIKutina, Edwards, et al., 1982 
CH4S15.8 ± 0.5?EIRuska and Franklin, 1969 
C2H3F3S14.88 ± 0.06?EICullen, Frost, et al., 1970 
C2H3F3S214.83 ± 0.08?EICullen, Frost, et al., 1970 
C2H3NS12.9 ± 0.2?EIHobrock, Shenkel, et al., 1963 
C2H4S11.13 ± 0.04CH3PIButler and Baer, 1982T = 0K
C2H4S11.07 ± 0.04CH3PIButler and Baer, 1982T = 298K
C2H4S12.3 ± 0.2CH3EIGallegos and Kiser, 1961 
C2H6OS10.69 ± 0.13?PIPECOZha, Nishimura, et al., 1988 
C2H6OS11.6 ± 0.2H2O+CH3EIPotzinger, Stracke, et al., 1975 
C2H6OS14.8 ± 0.1?EIBlais, Cottin, et al., 1970 
C2H6S17.7 ± 0.3?EIGal'perin, Bogolyubov, et al., 1969 
C2H6S14.0 ± 0.1CH4+HPIErmolenko, Akopyan, et al., 1983 
C2H6S14.16 ± 0.08?EICullen, Frost, et al., 1970 
C2H6S213.43 ± 0.09?EICullen, Frost, et al., 1970 
C2H6S314.5 ± 0.3?EIHobrock and Kiser, 1963 
C3H5NS15.2 ± 0.5?EIHobrock, Shenkel, et al., 1963 
C3H6OS12.9 ± 0.2?EIConde-Caprace and Collin, 1972 
C3H6S14.1 ± 0.2?EIHobrock and Kiser, 1962 
C3H6S10.4 ± 0.1C2H5PIButler and Baer, 1982T = 298K
C3H6S10.5 ± 0.1C2H5PIButler and Baer, 1982T = 0K
C3H6S13.9 ± 0.2?EIGallegos and Kiser, 1962 
C3H6S213. ± 0.4CHS+CH4?EIConde-Caprace and Collin, 1972 
C3H8S15.9 ± 0.4?EIHobrock and Kiser, 1962, 2 
C4H4S13.0 ± 0.2C3H3CEMSTedder and Vidaud, 1980 
C4H4S13.19 ± 0.04C3H3PEButler and Baer, 1980 
C4H4S13.0 ± 0.2?EIKhvostenko, 1962 
C4H8OS14.1?EIConde-Caprace and Collin, 1969 
C4H8S13.8 ± 0.3?EIHobrock and Kiser, 1963, 2 
C4H8S11.0 ± 0.1C3H7PIButler and Baer, 1982T = 298K
C4H8S11.1 ± 0.1C3H7PIButler and Baer, 1982T = 0K
C4H8S13.8 ± 0.2?EIGallegos and Kiser, 1962 
C4H10S16.4 ± 0.4?EIHobrock and Kiser, 1963, 2 
C4H10S15.3 ± 0.5?EIHobrock and Kiser, 1963 
C4H10S15.2 ± 0.4?EIHobrock and Kiser, 1962, 2 
C4H10S216.4 ± 0.3?EIGal'perin, Bogolyubov, et al., 1969 
C5H6S14.9 ± 0.3?EIBogolyubov, Plotnikov, et al., 1969 
C5H6S15.5 ± 0.3?EIBogolyubov, Plotnikov, et al., 1969 
C6H5DS12.7 ± 0.2?EIEarnshaw, Cook, et al., 1964 
C6H8S14.2 ± 0.3?EIBogolyubov, Plotnikov, et al., 1969 
C6H8S13.8 ± 0.3?EIBogolyubov, Plotnikov, et al., 1969 
C7H8S14.5?EIGowenlock, Kay, et al., 1963 
C8H10S12.5?EIGowenlock, Kay, et al., 1963 
C12H10S221.0 ± 0.3?EIGal'perin, Bogolyubov, et al., 1969 

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ruscic and Berkowitz, 1993
Ruscic, B.; Berkowitz, J., Photoionization mass spectrometry of CH2S and HCS, J. Chem. Phys., 1993, 98, 2568. [all data]

Kutina, Edwards, et al., 1982
Kutina, R.; Edwards, A.; Goodman, G.; Berkowitz, J., Photoionization mass spectrometry of CH3SH, CD3SH, and CH3SD: Heats of formation of CH3S+ (CH2SH+), CH2S+, CH2S, and HCS+, J. Chem. Phys., 1982, 77, 5508. [all data]

Ruska and Franklin, 1969
Ruska, W.E.W.; Franklin, J.L., Ion-molecule reactions in hydrogen sulfide, methanethiol and 2-thiapropane, Intern. J. Mass Spectrom. Ion Phys., 1969, 3, 221. [all data]

Cullen, Frost, et al., 1970
Cullen, W.R.; Frost, D.C.; Pun, M.T., Mass spectra, appearance potentials, heats of formation, and bond energies of some alkyl and perfluoroalkyl sulfides, Inorg. Chem., 1970, 9, 1976. [all data]

Hobrock, Shenkel, et al., 1963
Hobrock, B.G.; Shenkel, R.C.; Kiser, R.W., Singly and doubly-charged ions from methyl and ethyl isothiocyanates by electron impact, J. Phys. Chem., 1963, 67, 1684. [all data]

Butler and Baer, 1982
Butler, J.J.; Baer, T., Photoionization study of the heat of formation of HCS+, J. Am. Chem. Soc., 1982, 104, 5016. [all data]

Gallegos and Kiser, 1961
Gallegos, E.; Kiser, R.W., Electron impact spectroscopy of ethylene sulfide and ethylenimine, J. Phys. Chem., 1961, 65, 1177. [all data]

Zha, Nishimura, et al., 1988
Zha, Q.; Nishimura, T.; Meisels, G.G., Unimolecular dissociation of energy-selected dimethyl sulfoxide, Int. J. Mass Spectrom. Ion Processes, 1988, 83, 1. [all data]

Potzinger, Stracke, et al., 1975
Potzinger, P.; Stracke, H.-U.; Kupper, W.; Gollnick, K., Ionisierungs- und Auftrittspotentialmessungen an Dialkylsulfoxiden, Z. Naturforsch. A:, 1975, 30, 340. [all data]

Blais, Cottin, et al., 1970
Blais, J.-C.; Cottin, M.; Gitton, B., Ionisation positive et negative dans le dimethylsulfoxyde en phase gazeuse, J. Chim. Phys., 1970, 67, 1475. [all data]

Gal'perin, Bogolyubov, et al., 1969
Gal'perin, Ya.V.; Bogolyubov, G.M.; Grishin, N.N.; Petrov, A.A., Organic derivatives of elements of groups V and VI. VI. Mass spectra of compounds with S-S bonds, Zh. Obshch. Khim., 1969, 39, 1599, In original 1567. [all data]

Ermolenko, Akopyan, et al., 1983
Ermolenko, A.I.; Akopyan, M.E.; Sergeev, Y.L., Decomposition of dimethyl sulfide molecular ions. Randomization of states during photoionization dissociation of molecules, High Energy Chem., 1983, 17, 25. [all data]

Hobrock and Kiser, 1963
Hobrock, B.G.; Kiser, R.W., Electron impact investigations of sulfur compounds. III. 2-Thiapropane, 3-thiapentane, and 2,3,4-trithiapentane, J. Phys. Chem., 1963, 67, 1283. [all data]

Conde-Caprace and Collin, 1972
Conde-Caprace, G.; Collin, J.E., Ionization and dissociation of cyclic ethers thioethers by electron-impact. A comparison between 1,3-dioxolane, 1,3-dithiolane and 1,3-oxathiolane, Org. Mass Spectrom., 1972, 6, 415. [all data]

Hobrock and Kiser, 1962
Hobrock, B.G.; Kiser, R.W., Electron impact spectroscopy of propylene sulfide, J. Phys. Chem., 1962, 66, 1551. [all data]

Gallegos and Kiser, 1962
Gallegos, E.J.; Kiser, R.W., Electron impact spectroscopy of the four- and five-membered, saturated heterocyclic compounds containing nitrogen, oxygen and sulfur, J. Phys. Chem., 1962, 66, 136. [all data]

Hobrock and Kiser, 1962, 2
Hobrock, B.G.; Kiser, R.W., Electron impact spectroscopy of sulfur compounds. I. 2-Thiabutane, 2-thiapentane, and 2,3-dithiabutane, J. Phys. Chem., 1962, 66, 1648. [all data]

Tedder and Vidaud, 1980
Tedder, J.M.; Vidaud, P.H., Charge exchange mass spectra of thiophene, pyrrole and furan, J. Chem. Soc. Faraday Trans. 2, 1980, 76, 1516. [all data]

Butler and Baer, 1980
Butler, J.J.; Baer, T., Thermochemistry and dissociation dynamics of state-selected C4H4X ions. 1. Thiophene, J. Am. Chem. Soc., 1980, 102, 6764. [all data]

Khvostenko, 1962
Khvostenko, V.I., Ionisation of thiophen and some of its derivatives by electron impact, Zh. Fiz. Khim., 1962, 36, 384, In original 197. [all data]

Conde-Caprace and Collin, 1969
Conde-Caprace, G.; Collin, J.E., Ionization and dissociation of cyclic ethers and thioethers by electronimpact. A comparison between 1,4 dioxane, 1,4 dithiane and 1,4 oxathiane, Org. Mass Spectrom., 1969, 2, 1277. [all data]

Hobrock and Kiser, 1963, 2
Hobrock, B.G.; Kiser, R.W., Electron impact investigations of sulfur compounds. II. 3-Methyl-2-thiabutane, 4-thia-1-pentene, and 3,4-dithiahexane, J. Phys. Chem., 1963, 67, 648. [all data]

Bogolyubov, Plotnikov, et al., 1969
Bogolyubov, G.M.; Plotnikov, V.F.; Boiko, Yu.A.; Petrov, A.A., Organic derivatives of elements of groups V and VI. IX. Mass spectra of vinylacetylene sulfides, Zh. Obshch. Khim., 1969, 39, 2467, In original 2407. [all data]

Earnshaw, Cook, et al., 1964
Earnshaw, D.G.; Cook, G.L.; Dinneen, G.U., A study of selected ions in the mass spectra of benzenethiol and deuterated benzenethiol, J. Phys. Chem., 1964, 68, 296. [all data]

Gowenlock, Kay, et al., 1963
Gowenlock, B.G.; Kay, J.; Majer, J.R., Electron impact studies of some sulphides and disulphides, J. Chem. Soc. Faraday Trans., 1963, 59, 2463. [all data]


Notes

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