CHCl2+ (structure unspecified)
- Formula: CHCl2+
- Molecular weight: 83.924
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Reactions leading to CHCl2+ (ion structure unspecified)
Precursor | AP (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
CHBrCl2 | 11.0 ± 0.1 | Br | EI | Harrison and Shannon, 1962 | |
CHCl3 | 11.52 | Cl | EI | Holmes, Lossing, et al., 1988 | |
CHCl3 | 11.49 ± 0.02 | Cl | PI | Werner, Tsai, et al., 1974 | |
CHCl3 | 11.52 | Cl | EI | Lossing, 1972 | |
CHCl3 | 11.64 ± 0.20 | Cl | EI | Hobrock and Kiser, 1964 | |
CHCl3 | 11.7 ± 0.1 | Cl | EI | Harrison and Shannon, 1962 | |
CHCl3 | 12.43 ± 0.02 | Cl | EI | Reed and Snedden, 1956 | |
CH2Cl2 | 13.00 ± 0.10 | H | EI | Reed and Snedden, 1956 | |
C2H2Cl4 | 11.6 ± 0.1 | CHCl2 | EI | Harrison and Shannon, 1962 | |
C2H3Cl3 | 11.80 | CH2Cl | EI | Lossing, 1972 |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Harrison and Shannon, 1962
Harrison, A.G.; Shannon, T.W.,
An electron impact study of chloromethyl and dichloromethyl derivatives,
Can. J. Chem., 1962, 40, 1730. [all data]
Holmes, Lossing, et al., 1988
Holmes, J.L.; Lossing, F.P.; McFarlane, R.A.,
Stabilization energy and positional effects in halogen-substituted alkyl ions.,
Int. J. Mass Spectrom. Ion Phys., 1988, 86, 209. [all data]
Werner, Tsai, et al., 1974
Werner, A.S.; Tsai, B.P.; Baer, T.,
Photoionization study of the ionization potentials fragmentation paths of the chlorinated methanes carbon tetrabromide,
J. Chem. Phys., 1974, 60, 3650. [all data]
Lossing, 1972
Lossing, F.P.,
Free radicals by mass spectrometry. XLIV. Ionization potentials bond dissociation energies for chloro-and fluoromethyl radicals,
Bull. Soc. Chim. Belg., 1972, 81, 125. [all data]
Hobrock and Kiser, 1964
Hobrock, D.L.; Kiser, R.W.,
Electron impact studies of some trihalomethanes: trichloromethane, dichlorofluoro-methane, chlorodifluoromethane, and trifluoromethane,
J. Phys. Chem., 1964, 68, 575. [all data]
Reed and Snedden, 1956
Reed, R.I.; Snedden, W.,
Studies in electron impact methods. Part 6.-The formation of the methine and carbon ions,
J. Chem. Soc. Faraday Trans., 1956, 55, 876. [all data]
Notes
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- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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