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CH2S+ (structure unspecified)


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Reactions leading to CH2S+ (ion structure unspecified)

Precursor AP (eV) Other Products Method Reference Comment
CH4S10.58 ± 0.05H2PINourbakhsh, Norwood, et al., 1991 
CH4S10.55 ± 0.05H2PIKutina, Edwards, et al., 1982 
CH4S10.61 ± 0.05H2PIKutina, Edwards, et al., 1982T = 0K
CH4S10.8 ± 0.1H2PIAkopyan, Sergeev, et al., 1970 
CH4S~11.51H2PIKutina, Edwards, et al., 1982Ion is HCSH+
CH4S~11.57H2PIKutina, Edwards, et al., 1982T = 0K; Ion is HCSH+
C2H3F3S~14.?EICullen, Frost, et al., 1970 
C2H3F3S213.43 ± 0.24?EICullen, Frost, et al., 1970 
C2H4S12.7 ± 0.2?EIGallegos and Kiser, 1961 
C2H6OS11.5 ± 0.1?EIBlais, Cottin, et al., 1970 
C2H6S11.2 ± 0.3?EIGal'perin, Bogolyubov, et al., 1969 
C2H6S10.5 ± 0.1CH4PIErmolenko, Akopyan, et al., 1983 
C2H6S10.97 ± 0.13?EICullen, Frost, et al., 1970 
C2H6S10.46 ± 0.08CH4PIAkopyan, Sergeev, et al., 1970 
C2H6S210.61 ± 0.11?EICullen, Frost, et al., 1970 
C2H6S313.4 ± 0.3?EIHobrock and Kiser, 1963 
C3H6OS12.5 ± 0.2?EIConde-Caprace and Collin, 1972 
C3H6S12.4 ± 0.3?EIHobrock and Kiser, 1962 
C3H6S9.9C2H4PIPECOButler and Baer, 1983 
C3H6S10.4 ± 0.1?EIJones and Lossing, 1967 
C3H6S211. ± 0.4?EIConde-Caprace and Collin, 1972 
C3H8S13.6 ± 0.3?EIHobrock and Kiser, 1962, 2 
C4H8OS12.2 ± 0.3?EIConde-Caprace and Collin, 1969 
C4H8S11.4 ± 0.3?EIHobrock and Kiser, 1963, 2 
C4H8S10.5C3H6PIPECOButler and Baer, 1983 
C4H8S13.0 ± 0.2?EIGallegos and Kiser, 1962 
C4H8S213. ± 0.3?EIConde-Caprace and Collin, 1969 
C4H10S15.5 ± 0.4?EIHobrock and Kiser, 1963, 2 
C4H10S11.75 ± 0.03C2H4+CH4PIAkopyan, Sergeev, et al., 1970 
C4H10S12.5 ± 0.3?EIHobrock and Kiser, 1963 
C4H10S14.1 ± 0.3?EIHobrock and Kiser, 1962, 2 
C4H10S216.6 ± 0.3?EIGal'perin, Bogolyubov, et al., 1969 
C5H10O2S12.6 ± 0.12CH2O+C2H4EIConde-Caprace and Collin, 1972, 2 

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Nourbakhsh, Norwood, et al., 1991
Nourbakhsh, S.; Norwood, K.; Yin, H.-M.; Liao, C.-L.; Ng, C.Y., Vacuum ultraviolet photodissociation and photoionization studies of CH3SH and SH, J. Chem. Phys., 1991, 95, 946. [all data]

Kutina, Edwards, et al., 1982
Kutina, R.; Edwards, A.; Goodman, G.; Berkowitz, J., Photoionization mass spectrometry of CH3SH, CD3SH, and CH3SD: Heats of formation of CH3S+ (CH2SH+), CH2S+, CH2S, and HCS+, J. Chem. Phys., 1982, 77, 5508. [all data]

Akopyan, Sergeev, et al., 1970
Akopyan, M.E.; Sergeev, Yu.L.; Vilesov, F.I., Photionization in vapors of aliphatic sulfides. I. Methymercaptan, dimethyl and diethyl sulfides, High Energy Chem., 1970, 4, 265, In original 305. [all data]

Cullen, Frost, et al., 1970
Cullen, W.R.; Frost, D.C.; Pun, M.T., Mass spectra, appearance potentials, heats of formation, and bond energies of some alkyl and perfluoroalkyl sulfides, Inorg. Chem., 1970, 9, 1976. [all data]

Gallegos and Kiser, 1961
Gallegos, E.; Kiser, R.W., Electron impact spectroscopy of ethylene sulfide and ethylenimine, J. Phys. Chem., 1961, 65, 1177. [all data]

Blais, Cottin, et al., 1970
Blais, J.-C.; Cottin, M.; Gitton, B., Ionisation positive et negative dans le dimethylsulfoxyde en phase gazeuse, J. Chim. Phys., 1970, 67, 1475. [all data]

Gal'perin, Bogolyubov, et al., 1969
Gal'perin, Ya.V.; Bogolyubov, G.M.; Grishin, N.N.; Petrov, A.A., Organic derivatives of elements of groups V and VI. VI. Mass spectra of compounds with S-S bonds, Zh. Obshch. Khim., 1969, 39, 1599, In original 1567. [all data]

Ermolenko, Akopyan, et al., 1983
Ermolenko, A.I.; Akopyan, M.E.; Sergeev, Y.L., Decomposition of dimethyl sulfide molecular ions. Randomization of states during photoionization dissociation of molecules, High Energy Chem., 1983, 17, 25. [all data]

Hobrock and Kiser, 1963
Hobrock, B.G.; Kiser, R.W., Electron impact investigations of sulfur compounds. III. 2-Thiapropane, 3-thiapentane, and 2,3,4-trithiapentane, J. Phys. Chem., 1963, 67, 1283. [all data]

Conde-Caprace and Collin, 1972
Conde-Caprace, G.; Collin, J.E., Ionization and dissociation of cyclic ethers thioethers by electron-impact. A comparison between 1,3-dioxolane, 1,3-dithiolane and 1,3-oxathiolane, Org. Mass Spectrom., 1972, 6, 415. [all data]

Hobrock and Kiser, 1962
Hobrock, B.G.; Kiser, R.W., Electron impact spectroscopy of propylene sulfide, J. Phys. Chem., 1962, 66, 1551. [all data]

Butler and Baer, 1983
Butler, J.J.; Baer, T., A photoionization study of organosulfur ring compounds: Thiirane, thietane and tetrahydrothiophene, Org. Mass Spectrom., 1983, 18, 248. [all data]

Jones and Lossing, 1967
Jones, A.; Lossing, F.P., The ionization potential and heat of formation of thioformaldehyde, J. Phys. Chem., 1967, 71, 4111. [all data]

Hobrock and Kiser, 1962, 2
Hobrock, B.G.; Kiser, R.W., Electron impact spectroscopy of sulfur compounds. I. 2-Thiabutane, 2-thiapentane, and 2,3-dithiabutane, J. Phys. Chem., 1962, 66, 1648. [all data]

Conde-Caprace and Collin, 1969
Conde-Caprace, G.; Collin, J.E., Ionization and dissociation of cyclic ethers and thioethers by electronimpact. A comparison between 1,4 dioxane, 1,4 dithiane and 1,4 oxathiane, Org. Mass Spectrom., 1969, 2, 1277. [all data]

Hobrock and Kiser, 1963, 2
Hobrock, B.G.; Kiser, R.W., Electron impact investigations of sulfur compounds. II. 3-Methyl-2-thiabutane, 4-thia-1-pentene, and 3,4-dithiahexane, J. Phys. Chem., 1963, 67, 648. [all data]

Gallegos and Kiser, 1962
Gallegos, E.J.; Kiser, R.W., Electron impact spectroscopy of the four- and five-membered, saturated heterocyclic compounds containing nitrogen, oxygen and sulfur, J. Phys. Chem., 1962, 66, 136. [all data]

Conde-Caprace and Collin, 1972, 2
Conde-Caprace, G.; Collin, J.E., Electron impact induced fragmentation of 1,3,6-dioxathiocane, Org. Mass Spectrom., 1972, 6, 341. [all data]


Notes

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