Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

CF3+ (structure unspecified)


Gas phase ion energetics data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Reactions leading to CF3+ (ion structure unspecified)

Precursor AP (eV) Other Products Method Reference Comment
CBrF311.56 ± 0.02BrPIClay, Walters, et al., 1994 
CBrF311.71BrPINoutary, 1968 
CClF313. ± 1.ClPIZhang, Cooper, et al., 1991 
CClF312.55ClPIJochims, Lohr, et al., 1976 
CClF312.65ClPIAjello, Huntress, et al., 1976 
CClF312.63ClPINoutary, 1968 
CF3I11.26 ± 0.05IPIPECOBombach, Dannacher, et al., 1982 
CF3I11.27 ± 0.03IPIBerman, Beauchamp, et al., 1981T = 298K
CF3I11.36 ± 0.03IPIBerman, Beauchamp, et al., 1981T = 0K
CF3I10.89 ± 0.01IPINoutary, 1968 
CF3NO12.6 ± 0.1NOEISyrvatka and Gil'burd, 1973 
CF414.24 ± 0.07FENDFischer and Armentrout, 1990 
CF414.2 ± 0.1FDERTichy, Javahery, et al., 1987 
CF414.7 ± 0.3FPIPowis, 1980 
CF414.9 ± 0.1FPIPECOSimm, Danby, et al., 1975 
CF4<=14.84 ± 0.05FPIPECOBrehm, Frey, et al., 1974 
CF4<=15.35FPIWalter, Lifshitz, et al., 1969 
CF415.52 ± 0.02FPINoutary, 1968 
CF415.56 ± 0.01FPICook and Ching, 1965 
CF4O14.8 ± 0.2OF?EIThynne and MacNeil, 1970 
CF5NS14.23 ± 0.05?EIGlemser, Muller, et al., 1968 
CHF315.2HEIGoto, Nakamura, et al., 1994 
CHF314.14HPINoutary, 1968 
CHF314.03 ± 0.06HEIMartin, Lampe, et al., 1966 
C2F413.70 ± 0.02CFPIWalter, Lifshitz, et al., 1969 
C2F5I13.7 ± 0.05CF2+IPIPECOGolovin, Akopyan, et al., 1989 
C2F5I13.7 ± 0.1CF2,IEIHsieh and Hanrahan, 1977 
C2F613.62 ± 0.015CF3PINoutary, 1968 
C2F6S12.54 ± 0.06?EICullen, Frost, et al., 1970 
C2F6S212.07 ± 0.13?EICullen, Frost, et al., 1970 
C2H3F313.9CH3PILoguinov, Takhistov, et al., 1981 
C2H3F313.9 ± 0.1CH3EISimmie and Tschuikow-Roux, 1971 
C2H3F313.90 ± 0.03CH3EISteele and Stone, 1962 
C2H3F3S12.75 ± 0.05CH3SPIHagenow, Jochims, et al., 1989 
C2H3F3S13.07 ± 0.09?EICullen, Frost, et al., 1970 
C2H3F3S212.50 ± 0.08?EICullen, Frost, et al., 1970 
C3ClF515.63?EILifshitz and Long, 1965 
C3F615.0 ± 0.1?EIChelobov, Dubov, et al., 1963 
C3F615.38?EILifshitz and Long, 1965 
C3F6O13.8?EIMajer, Olavesen, et al., 1971 
C3F6O14.26 ± 0.10?EIHarland and Thynne, 1970 
C3F813.4 ± 0.1?EILifshitz and Grajower, 1969 
C3F813.22?PINoutary, 1968 
C3H3F315.0 ± 0.2?EISteele and Stone, 1962 
C3H3F3O14.6?EIMajer, Olavesen, et al., 1971 
C3H5F314.8 ± 0.1?EISteele and Stone, 1962 
C4F815.7?EIBibby and Carter, 1963 
C4F1013.22?PINoutary, 1968 
C4H2F413.9 ± 0.1C3H2FEISyrvatka, Gil'burd, et al., 1973 
C6F617.6 ± 0.5?EIPraet, Hubin-Franskin, et al., 1977 
C6F615.3 ± 0.5?EIPraet, Hubin-Franskin, et al., 1977 
C6F625.2 ± 0.4CF+C3+CF2EIPraet, Hubin-Franskin, et al., 1977 
C6F621.3 ± 0.4CF+C4F2EIPraet, Hubin-Franskin, et al., 1977 
C6F617.1?EIDibeler, Reese, et al., 1957 
C6F615. ± 0.4CF3EIPraet, Hubin-Franskin, et al., 1977 
C6F616.5 ± 0.5?EIPraet, Hubin-Franskin, et al., 1977 
C6F619.4 ± 0.4CF+C4F2EIPraet, Hubin-Franskin, et al., 1977 
C6F622.7 ± 0.4CF+C3+CF2EIPraet, Hubin-Franskin, et al., 1977 
C7F1414.4 ± 0.2?EIJames and Carter, 1962 

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Clay, Walters, et al., 1994
Clay, J.T.; Walters, E.A.; Grover, J.R.; Willcox, M.V., Photoionization of gas-phase bromotrifluoromethane and its comlexes with methanol: State dependence of intracluster reactions, J. Chem. Phys., 1994, 101, 2069. [all data]

Noutary, 1968
Noutary, C.J., Mass spectrometric study of some fluorocarbons and trifluoromethyl halides, J.Res. NBS, 1968, 72A, 479. [all data]

Zhang, Cooper, et al., 1991
Zhang, W.; Cooper, G.; Ibuki, T.; Brion, C.E., Excitation and ionization of freon molecules. II. Absolute oscillator strengths for the photoabsorption (7.5-200 eV) and the ionic photofragmentation (12.5-80 eV) of CF3Cl, Chem. Phys., 1991, 151, 343. [all data]

Jochims, Lohr, et al., 1976
Jochims, H.-W.; Lohr, W.; Baumgartel, H., Photoreactions of small organic molecules V. Absorption-, photoion- and resonancephotoelectron-spectra of CF3Cl, CF2Cl2, CFCl3 in the energy range 10-25 eV, Ber. Bunsen-Ges. Phys. Chem., 1976, 80, 130. [all data]

Ajello, Huntress, et al., 1976
Ajello, J.M.; Huntress, W.T., Jr.; Rayermann, P., A photoionization mass spectrometer study of CFCl3, CF2Cl2 and CF3Cl, J. Chem. Phys., 1976, 64, 4746. [all data]

Bombach, Dannacher, et al., 1982
Bombach, R.; Dannacher, J.; Stadelmann, J.-P.; Vogt, J.; Thorne, L.R.; Beauchamp, J.L., Photoelectron-photoion coincidence study of CF3I. Implications for the CW IR laser multiphoton dissociation of CF3I+, Chem. Phys., 1982, 66, 403. [all data]

Berman, Beauchamp, et al., 1981
Berman, D.W.; Beauchamp, J.L.; Thorne, L.R., Ion cyclotron resonance and photoionization investigations of the thermochemistry and reactions of ions derived from CF3I, Int. J. Mass Spectrom. Ion Phys., 1981, 39, 47. [all data]

Syrvatka and Gil'burd, 1973
Syrvatka, B.G.; Gil'burd, M.M., Mass-spectrometric study of trifluoronitrosomethane, Russ. J. Phys. Chem., 1973, 47, 1215. [all data]

Fischer and Armentrout, 1990
Fischer, E.R.; Armentrout, P.B., The appearance energy of CF3+ from CF4: Ion/molecule reactions related to the thermochemistry of CF3+., Int. J. Mass Spectrom. Ion Processes, 1990, 101, 1. [all data]

Tichy, Javahery, et al., 1987
Tichy, M.; Javahery, G.; Twiddy, N.D.; Ferguson, E.E., The thermal energy reactions HCl+ + SF6 Ü SF5+ + HF + Cl and HCl+ + CF4 Ü CF3+ + HF + Cl, Int. J. Mass Spectrom. Ion Processes, 1987, 79, 231. [all data]

Powis, 1980
Powis, I., The dissociation of state-selected CF3X+ molecular ions, Mol. Phys., 1980, 39, 311. [all data]

Simm, Danby, et al., 1975
Simm, I.G.; Danby, C.J.; Eland, J.H.D.; Mansell, P.I., Translational energy release in the loss of fluorine atoms from the ions SF6+, CF4+ and C2F6+, J. Chem. Soc., 1975, 426. [all data]

Brehm, Frey, et al., 1974
Brehm, B.; Frey, R.; Kustler, A.; Eland, J.H.D., Kinetic energy release in ion fragmentation: N2O+, COS+ and CF4+ decays, Int. J. Mass Spectrom. Ion Processes, 1974, 79, 251. [all data]

Walter, Lifshitz, et al., 1969
Walter, T.A.; Lifshitz, C.; Chupka, W.A.; Berkowitz, J., Mass-spectrometric study of the photoionization of C2F4 and CF4, J. Chem. Phys., 1969, 51, 3531. [all data]

Cook and Ching, 1965
Cook, G.R.; Ching, B.K., Photoionization and absorption cross sections and fluorescence of CF4, J. Chem. Phys., 1965, 43, 1794. [all data]

Thynne and MacNeil, 1970
Thynne, J.C.J.; MacNeil, K.A.G., Ionisation and dissociation of carbonyl fluoride and trifluoromethyl hypofluorite by electron impact, Intern. J. Mass Spectrom. Ion Phys., 1970, 5, 95. [all data]

Glemser, Muller, et al., 1968
Glemser, O.; Muller, A.; Bohler, D.; Krebs, B., Die N-S-Bindung: Bindungslangen Kraftkonstanten, Bindungsgrade und Bindungsenergien, Z. Anorg. Allgem. Chem., 1968, 357, 184. [all data]

Goto, Nakamura, et al., 1994
Goto, M.; Nakamura, K.; Toyoda, H.; Sugai, H., Cross section measurements for electron-impact dissociation of CHF3 into neutral and ionic fragments, Jpn. J. Appl. Phys. Part 1, 1994, 33, 3602. [all data]

Martin, Lampe, et al., 1966
Martin, R.H.; Lampe, F.W.; Taft, R.W., An electron-impact study of ionization and dissociation in methoxy- and halogen- substituted methanes, J. Am. Chem. Soc., 1966, 88, 1353. [all data]

Golovin, Akopyan, et al., 1989
Golovin, A.V.; Akopyan, M.E.; Reingand, L.M.; Chistyakov, A.B., Energetics and mechanism of C2F5I photoionization processes, High Energy Chem., 1989, 23, 301, In original 387. [all data]

Hsieh and Hanrahan, 1977
Hsieh, T.; Hanrahan, R.J., An electron impact investigation of pentafluoroethyl iodide, Int. J. Mass Spectrom. Ion Phys., 1977, 23, 201. [all data]

Cullen, Frost, et al., 1970
Cullen, W.R.; Frost, D.C.; Pun, M.T., Mass spectra, appearance potentials, heats of formation, and bond energies of some alkyl and perfluoroalkyl sulfides, Inorg. Chem., 1970, 9, 1976. [all data]

Loguinov, Takhistov, et al., 1981
Loguinov, Y.; Takhistov, V.V.; Vatlina, L.P., Photoionization studies of substituted trimethylamines, Org. Mass Spectrom., 1981, 16, 239. [all data]

Simmie and Tschuikow-Roux, 1971
Simmie, J.M.; Tschuikow-Roux, E., Mass spectrum, appearance potentials and bond dissociation energies of 1,1,1-trifluoroethane, Int. J. Mass Spectrom. Ion Phys., 1971, 7, 41. [all data]

Steele and Stone, 1962
Steele, W.C.; Stone, F.G.A., An electron impact study of 1,1,1-trifluoroethane, 1,1,1-trifluoropropane and 3,3,3-trifluoropropene, J. Am. Chem. Soc., 1962, 84, 3450. [all data]

Hagenow, Jochims, et al., 1989
Hagenow, G.; Jochims, H.-W.; Sawatzki, J.; Minkwitz, R.; Baumgartel, H., Photoionisationsmassenspektren von methyl(trifluormethyl)sulfan CH3SCF3, Z. Naturforsch. B:, 1989, 44, 17. [all data]

Lifshitz and Long, 1965
Lifshitz, C.; Long, F.A., Appearance potentials and mass spectra of C3F6, C3F5Cl, and c-C3F6, J. Phys. Chem., 1965, 69, 3741. [all data]

Chelobov, Dubov, et al., 1963
Chelobov, F.N.; Dubov, S.S.; Tikhomirov, M.I.; Dobrovitskii, M.I., Ionization and dissociation of hexafluoropropylene by electrons of different energies, Dokl. Akad. Nauk SSSR, 1963, 151, 631, In original 670. [all data]

Majer, Olavesen, et al., 1971
Majer, J.R.; Olavesen, C.; Robb, J.C., Wavelength effect in the photolysis of halogenated ketones, J. Chem. Soc. B, 1971, 48. [all data]

Harland and Thynne, 1970
Harland, P.; Thynne, J.C.J., Positive and negative ion formation in hexafluoroacetone by electron impact, J. Phys. Chem., 1970, 74, 52. [all data]

Lifshitz and Grajower, 1969
Lifshitz, C.; Grajower, R., Dissociative electron capture and dissociative ionization in perfluoropropane, Intern. J. Mass Spectrom. Ion Phys., 1969, 3, 211. [all data]

Bibby and Carter, 1963
Bibby, M.M.; Carter, G., Ionization and dissociation in some fluorocarbon gases, J. Chem. Soc. Faraday Trans., 1963, 59, 2455. [all data]

Syrvatka, Gil'burd, et al., 1973
Syrvatka, B.G.; Gil'burd, M.M.; Bel'ferman, A.L., Ion-dissociative processes of some halogen containing butadienes and particles structure, Zh. Org. Khim., 1973, 9, 1117. [all data]

Praet, Hubin-Franskin, et al., 1977
Praet, M-Th.; Hubin-Franskin, M.J.; Delwiche, J.P.; Schoos, R., Ionization and dissociation of C6F6 isomers under electron impact, Org. Mass Spectrom., 1977, 12, 297. [all data]

Dibeler, Reese, et al., 1957
Dibeler, V.H.; Reese, R.M.; Mohler, F.L., Ionization and dissociation of hexafluorobenzene by electron impact, J. Chem. Phys., 1957, 26, 304. [all data]

James and Carter, 1962
James, L.H.; Carter, G., A mass spectrometric study of ionization and dissociation by electron impact ofperfluoro-methyl cyclohexane, J. Electron. Control, 1962, 13, 213. [all data]


Notes

Go To: Top, Gas phase ion energetics data, References