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CF+ (structure unspecified)


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Reactions leading to CF+ (ion structure unspecified)

Precursor AP (eV) Other Products Method Reference Comment
CBrF322.9 ± 0.5?EIDibeler, Reese, et al., 1956 
CClF324. ± 1.2F+ClPIZhang, Cooper, et al., 1991 
CClF320.3 ± 0.1Cl+F2PISchenk, Oertel, et al., 1979 
CClF322.6 ± 0.5?EIDibeler, Reese, et al., 1956 
CCl2F215.3 ± 0.3Cl2+F(-)PISchenk, Oertel, et al., 1979 
CCl2F220.20F+2ClPIJochims, Lohr, et al., 1976 
CCl2F217.65F+Cl2PIJochims, Lohr, et al., 1976 
CCl2F219.5 ± 0.5?EIBaker and Tate, 1938 
CCl3F15.61 ± 0.053ClPISchenk, Oertel, et al., 1979 
CCl3F18.353ClPIJochims, Lohr, et al., 1976 
CCl3F15.7Cl2+ClPIJochims, Lohr, et al., 1976 
CFN16.35NPIDibeler and Liston, 1967 
CF218.5FEIGoto, Nakamura, et al., 1994 
CF214.6 ± 0.4FEITarnovsky, Kurunczi, et al., 1993 
CF2O27.0 ± 0.3?EIThynne and MacNeil, 1970 
CF322.22FEIGoto, Nakamura, et al., 1994 
CF321.4F2EIGoto, Nakamura, et al., 1994 
CF321.4 ± 0.42FEITarnovsky, Kurunczi, et al., 1993 
CF3I19.9 ± 0.3?EIMarriott and Craggs, 1956 
CF422.6 ± 0.5?EIDibeler, Reese, et al., 1956 
CF4O31.1 ± 0.5?EIThynne and MacNeil, 1970 
CHClF217. ± 0.?EIHobrock and Kiser, 1964 
CHCl2F16.9 ± 0.2?EIHobrock and Kiser, 1964 
CHF16.6HEIGoto, Nakamura, et al., 1994 
CHF220.5H+FEIGoto, Nakamura, et al., 1994 
CHF214.6HFEIGoto, Nakamura, et al., 1994 
CHF320.9HF+FEIGoto, Nakamura, et al., 1994 
CHF320.2 ± 0.4?EIHobrock and Kiser, 1964 
CH2F218.8?EILifshitz and Long, 1965 
C2ClF316.7 ± 0.1CClF2EISyrvatka, Gil'burd, et al., 1972 
C2Cl2F216.5 ± 0.1CFCl2EISyrvatka, Gil'burd, et al., 1972 
C2F413.76 ± 0.01CF3PIWalter, Lifshitz, et al., 1969 
C2F616.75?PINoutary, 1968 
C2F616.1?EISmith and Kevan, 1967 
C2F6S216.?EICullen, Frost, et al., 1970 
C2HF17.0 ± 0.1CHEIKloster-Jensen, Pascual, et al., 1970 
C2HF315.2?EILifshitz and Long, 1963 
C2H2F214.50CH2FPIFrenking, Koch, et al., 1984 
C2H2F214.4 ± 0.1?PIStadelmann and Vogt, 1980 
C2H2F214.50 ± 0.03CH2FPIJochims, Lohr, et al., 1979 
C2H2F214.45CH2FPIFrenking, Koch, et al., 1984 
C2H2F214.5 ± 0.1?PIStadelmann and Vogt, 1980 
C2H2F214.45 ± 0.03CH2FPIJochims, Lohr, et al., 1979 
C2H2F214.92CH2FPIFrenking, Koch, et al., 1984 
C2H2F214.92 ± 0.02CH2FPIReinke, Kraessig, et al., 1973 
C2H2F215.23?EILifshitz and Long, 1963 
C2H3F14.5 ± 0.1CH3PEDannacher, Schmelzer, et al., 1979 
C2H3F15.43?EILifshitz and Long, 1963 
C3ClF517.8?EILifshitz and Long, 1965, 2 
C3F3N13.3 ± 0.1?EIChelobov, Dubov, et al., 1969 
C3F618.1?EILifshitz and Long, 1965, 2 
C3F617.3?EILifshitz and Long, 1965, 2 
C3F813.5?EISmith and Kevan, 1967 
C3H2FN14.2 ± 0.1?EIChelobov, Dubov, et al., 1969 
C6F619.1 ± 0.1?EIPraet, Hubin-Franskin, et al., 1977 
C6F618.3 ± 0.1?EIPraet, Hubin-Franskin, et al., 1977 
C6F617.3 ± 0.3?EIDibeler, Reese, et al., 1957 
C6F615.6 ± 0.5?EIPraet, Hubin-Franskin, et al., 1977 
C7F1415.9 ± 0.2?EIJames and Carter, 1962 

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Dibeler, Reese, et al., 1956
Dibeler, V.H.; Reese, R.M.; Mohler, F.L., Ionization and dissociation of the trifluoromethyl halides by electron impact, J. Res. NBS, 1956, 57, 113. [all data]

Zhang, Cooper, et al., 1991
Zhang, W.; Cooper, G.; Ibuki, T.; Brion, C.E., Excitation and ionization of freon molecules. II. Absolute oscillator strengths for the photoabsorption (7.5-200 eV) and the ionic photofragmentation (12.5-80 eV) of CF3Cl, Chem. Phys., 1991, 151, 343. [all data]

Schenk, Oertel, et al., 1979
Schenk, H.; Oertel, H.; Baumgartel, H., Photoreactions of small organic molecules VII Photoionization studies on the ion-pair formation of the fluorochloromethanes CF2Cl2, CF3Cl, and CFCl3, Ber. Bunsen-Ges. Phys. Chem., 1979, 83, 683. [all data]

Jochims, Lohr, et al., 1976
Jochims, H.-W.; Lohr, W.; Baumgartel, H., Photoreactions of small organic molecules V. Absorption-, photoion- and resonancephotoelectron-spectra of CF3Cl, CF2Cl2, CFCl3 in the energy range 10-25 eV, Ber. Bunsen-Ges. Phys. Chem., 1976, 80, 130. [all data]

Baker and Tate, 1938
Baker, R.F.; Tate, J.T., Ionization and dissociation by electron impact in CCl2F2 and in CCl4 vapor, Phys. Rev., 1938, 53, 683. [all data]

Dibeler and Liston, 1967
Dibeler, V.H.; Liston, S.K., Mass-spectrometric study of photoionization. VIII.Dicyanogen and the cyanogen halides, J. Chem. Phys., 1967, 47, 4548. [all data]

Goto, Nakamura, et al., 1994
Goto, M.; Nakamura, K.; Toyoda, H.; Sugai, H., Cross section measurements for electron-impact dissociation of CHF3 into neutral and ionic fragments, Jpn. J. Appl. Phys. Part 1, 1994, 33, 3602. [all data]

Tarnovsky, Kurunczi, et al., 1993
Tarnovsky, V.; Kurunczi, P.; Rogozhnikov, D.; Becker, K., Absolute cross sections for the dissociative electron impact ionization of the CFx (x=1-3) free radicals, Int. J. Mass Spectrom. Ion Processes, 1993, 128, 181. [all data]

Thynne and MacNeil, 1970
Thynne, J.C.J.; MacNeil, K.A.G., Ionisation and dissociation of carbonyl fluoride and trifluoromethyl hypofluorite by electron impact, Intern. J. Mass Spectrom. Ion Phys., 1970, 5, 95. [all data]

Marriott and Craggs, 1956
Marriott, J.; Craggs, J.D., Ionization and dissociation by electron impact. I. Trifluoromethyl halides, J. Electron., 1956, 1, 405. [all data]

Hobrock and Kiser, 1964
Hobrock, D.L.; Kiser, R.W., Electron impact studies of some trihalomethanes: trichloromethane, dichlorofluoro-methane, chlorodifluoromethane, and trifluoromethane, J. Phys. Chem., 1964, 68, 575. [all data]

Lifshitz and Long, 1965
Lifshitz, C.; Long, F.A., Appearance potentials and mass spectra of fluorinated ethylenes. II. Heats offormation of fluorinated species and their positive ions, J. Phys. Chem., 1965, 69, 3731. [all data]

Syrvatka, Gil'burd, et al., 1972
Syrvatka, B.G.; Gil'burd, M.M.; Bel'ferman, A.L., Mass spectrometric study of chlorofluoro-substituted ethylenes, J. Org. Chem. USSR, 1972, 8, 1587, In original 1553. [all data]

Walter, Lifshitz, et al., 1969
Walter, T.A.; Lifshitz, C.; Chupka, W.A.; Berkowitz, J., Mass-spectrometric study of the photoionization of C2F4 and CF4, J. Chem. Phys., 1969, 51, 3531. [all data]

Noutary, 1968
Noutary, C.J., Mass spectrometric study of some fluorocarbons and trifluoromethyl halides, J.Res. NBS, 1968, 72A, 479. [all data]

Smith and Kevan, 1967
Smith, D.; Kevan, L., Dissociative charge exchange of rare-gas ions with C2F6 and C3F8, J. Chem. Phys., 1967, 46, 1586. [all data]

Cullen, Frost, et al., 1970
Cullen, W.R.; Frost, D.C.; Pun, M.T., Mass spectra, appearance potentials, heats of formation, and bond energies of some alkyl and perfluoroalkyl sulfides, Inorg. Chem., 1970, 9, 1976. [all data]

Kloster-Jensen, Pascual, et al., 1970
Kloster-Jensen, E.; Pascual, C.; Vogt, J., Mass spectrometric studies of mono- and di-haloacetylenes,, Helv. Chim. Acta, 1970, 53, 2109. [all data]

Lifshitz and Long, 1963
Lifshitz, C.; Long, F.A., Appearance potentials and mass spectra of fluorinated ethylenes. I. Decomposition mechanisms and their energetics, J. Phys. Chem., 1963, 67, 2463. [all data]

Frenking, Koch, et al., 1984
Frenking, G.; Koch, W.; Schaale, M.; Baumgartel, H., The unimolecular decay of difluoroethene cations. An experimental and quantum-chemical study, Int. J. Mass Spectrom. Ion Phys., 1984, 61, 305. [all data]

Stadelmann and Vogt, 1980
Stadelmann, J.P.; Vogt, J., A photoelectron-photoion coincidence study of cis- and trans- difluoroethene, Int. J. Mass Spectrom. Ion Phys., 1980, 35, 83. [all data]

Jochims, Lohr, et al., 1979
Jochims, H.-W.; Lohr, W.; Baumgartel, H., Photoreactions of small organic molecules. VI. Photoionization processes of difluoroethylenes, Nouv. J. Chim., 1979, 3, 109. [all data]

Reinke, Kraessig, et al., 1973
Reinke, D.; Kraessig, R.; Baumgartel, H., Photoreactions of small organic molecules, Z. Naturforsch. A:, 1973, 28, 1021. [all data]

Dannacher, Schmelzer, et al., 1979
Dannacher, J.; Schmelzer, A.; Stadelmann, J.-P.; Vogt, J., A photoelectron-photoion coincidence study of vinylfluoride, Int. J. Mass Spectrom. Ion Phys., 1979, 31, 175. [all data]

Lifshitz and Long, 1965, 2
Lifshitz, C.; Long, F.A., Appearance potentials and mass spectra of C3F6, C3F5Cl, and c-C3F6, J. Phys. Chem., 1965, 69, 3741. [all data]

Chelobov, Dubov, et al., 1969
Chelobov, F.N.; Dubov, S.S.; Tikhomirov, M.V.; Dobrovitskii, M.I.; Gitel', P.O.; Rozenshtein, S.M., Processes in fluoroacrylonitriles under electron impact, Zh. Fiz. Khim., 1969, 43, 33, In original 15. [all data]

Praet, Hubin-Franskin, et al., 1977
Praet, M-Th.; Hubin-Franskin, M.J.; Delwiche, J.P.; Schoos, R., Ionization and dissociation of C6F6 isomers under electron impact, Org. Mass Spectrom., 1977, 12, 297. [all data]

Dibeler, Reese, et al., 1957
Dibeler, V.H.; Reese, R.M.; Mohler, F.L., Ionization and dissociation of hexafluorobenzene by electron impact, J. Chem. Phys., 1957, 26, 304. [all data]

James and Carter, 1962
James, L.H.; Carter, G., A mass spectrometric study of ionization and dissociation by electron impact ofperfluoro-methyl cyclohexane, J. Electron. Control, 1962, 13, 213. [all data]


Notes

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