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C4H8+ (structure unspecified)


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Reactions leading to C4H8+ (ion structure unspecified)

Precursor AP (eV) Other Products Method Reference Comment
C4H9Cl10.3 ± 0.1HClEIMaccoll and Mathur, 1980 
C4H9Cl10.95HClEIBaldwin, Maccoll, et al., 1966 
C4H9Cl9.56HClEIBaldwin, Maccoll, et al., 1966 
C4H9Cl10.75 ± 0.06HClEIMaccoll and Mathur, 1980 
C4H9Cl10.77HClEIBaldwin, Maccoll, et al., 1966 
C4H9Cl10.41 ± 0.08HClEIMaccoll and Mathur, 1980 
C4H9Cl10.71HClEIBaldwin, Maccoll, et al., 1966 
C4H10O10.18 ± 0.05H2OPIPECOShao, Baer, et al., 1988 
C4H10O10.20 ± 0.10H2OEIBowen and Maccoll, 1984 
C4H10O10.33 ± 0.03H2OPIPECOShao, Baer, et al., 1988 
C4H12Si9.89 ± 0.05?EISteele, Nichols, et al., 1962 
C5H9N12.00?PERowland, 1971Unpublished result of J.H.D. Eland
C5H10O11.88CH2O?EICollin and Conde-Caprace, 1966 
C5H1211.05CH4PITraeger, Hudson, et al., 1996T = 0K
C5H1211.00CH4EIWolkoff and Holmes, 1978 
C5H1210.93 ± 0.03CH4PISteiner, Giese, et al., 1961 
C5H1210.39 ± 0.02CH4PISteiner, Giese, et al., 1961 
C5H1210.72CH4PITraeger, Hudson, et al., 1996T = 0K
C5H1210.74 ± 0.02CH4PISteiner, Giese, et al., 1961 
C5H12O10.2 ± 0.1CH3OHEIBissonnette, George, et al., 1990 
C6H11Cl10.2 ± 0.01?PISergeev, Akopyan, et al., 1973 
C6H1211.15 ± 0.03C2H4EIRabbih, Selim, et al., 1981 
C6H1211.45C2H4EIPuttemans, 1974 
C6H1211.08 ± 0.01C2H4PISergeev, Akopyan, et al., 1973 
C6H12O11.10C2H4OEIMorgan, Derrick, et al., 1980 
C6H12O11.10C2H4OEIMorgan, Derrick, et al., 1980 
C6H12O9.86CH3CHOEIHolmes, Terlouw, et al., 1976 
C6H12O10.70C2H4OEIMorgan, Derrick, et al., 1980 
C6H1410.65 ± 0.015C2H6PISteiner, Giese, et al., 1961 
C6H1411.00 ± 0.015C2H6PISteiner, Giese, et al., 1961 
C6H1410.23 ± 0.015C2H6PISteiner, Giese, et al., 1961 
C6H1410.58 ± 0.015C2H6PISteiner, Giese, et al., 1961 
C6H14O9.89?EIHolmes, Terlouw, et al., 1976 
C6H14O10.1 ± 0.1CH3OCH3EIBissonnette, George, et al., 1990 
C6H14O10.5 ± 0.1C2H6OEIAudier, Bouchoux, et al., 1982 
C6H14O9.9 ± 0.1C2H6OHEIAudier, Bouchoux, et al., 1982 
C6H14O9.8 ± 0.1C2H6OEIAudier, Bouchoux, et al., 1982 
C7H1610.56 ± 0.05C3H8PIBrehm, 1966 
C7H1610.97 ± 0.03C3H8PISteiner, Giese, et al., 1961 
C8H1811.19 ± 0.07C4H10PISteiner, Giese, et al., 1961 
C13H10N2O410.3 ± 0.2?EISteele, Nichols, et al., 1962 

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Maccoll and Mathur, 1980
Maccoll, A.; Mathur, D., Hydrogen chloride elimination from the molecular ions of alkyl chlorides, Org. Mass Spectrom., 1980, 15, 483. [all data]

Baldwin, Maccoll, et al., 1966
Baldwin, M.; Maccoll, A.; Miller, S.I., Ionization and appearance potentials from a study of alkyl chlorides, Advan. Mass Spectrom., 1966, 3, 259. [all data]

Shao, Baer, et al., 1988
Shao, J.D.; Baer, T.; Lewis, D.K., Dissociation dynamics of energy-selected ion-dipole complexes. 2. Butyl alcohol ions, J. Phys. Chem., 1988, 92, 5123. [all data]

Bowen and Maccoll, 1984
Bowen, R.D.; Maccoll, A., Low energy, low temperature mass spectra, Org. Mass Spectrom., 1984, 19, 379. [all data]

Steele, Nichols, et al., 1962
Steele, W.C.; Nichols, L.D.; Stone, F.G.A., The determination of silicon-carbon and silicon-hydrogen bond dissociation energies by electron impact, J. Am. Chem. Soc., 1962, 84, 4441. [all data]

Rowland, 1971
Rowland, C.G., Kinetic energy distributions of C12H8 fragment ions in the mass spectra of anthracene, phenanthrene and diphenylacetylene, Intern. J. Mass Spectrom. Ion Phys., 1971, 7, 79. [all data]

Collin and Conde-Caprace, 1966
Collin, J.E.; Conde-Caprace, G., Ionization and dissociation of cyclic ethers by electron impact, Intern. J. Mass Spectrom. Ion Phys., 1966, 1, 213. [all data]

Traeger, Hudson, et al., 1996
Traeger, J.C.; Hudson, C.E.; McAdoo, D.J., A photoionization study of the ion-neutral complexes [CH3CH+CH3CH2CH3] and [CH3CH2CH+CH3CH3] in the gas phase: Formation, H-transfer and C-C bond formation between partners, and channeling of energy into dissociation, J. Am. Soc. Mass Spectrom., 1996, 7, 73. [all data]

Wolkoff and Holmes, 1978
Wolkoff, P.; Holmes, J.L., Fragmentations of alkane molecular ions, J. Am. Chem. Soc., 1978, 100, 7346. [all data]

Steiner, Giese, et al., 1961
Steiner, B.; Giese, C.F.; Inghram, M.G., Photoionization of alkanes. Dissociation of excited molecular ions, J. Chem. Phys., 1961, 34, 189. [all data]

Bissonnette, George, et al., 1990
Bissonnette, M.; George, M.; Holmes, J.L., The experimental investigation of [C5H12O] ion structures related to neopentyl alcohol and its methyl ether, Int. J. Mass Spectrom. Ion Processes, 1990, 101, 309. [all data]

Sergeev, Akopyan, et al., 1973
Sergeev, Yu.L.; Akopyan, M.E.; Vilesov, F.I.; Chizhov, Yu.V., Photoionization processes in gaseous cyclohexane, and chloro- and bromocyclohexane, High Energy Chem., 1973, 7, 369, In original 418. [all data]

Rabbih, Selim, et al., 1981
Rabbih, M.A.; Selim, E.T.M.; Fahmey, M.A., Ionization & fragmentation of cyclohexane, Indian J. Pure Appl. Phys., 1981, 19, 962. [all data]

Puttemans, 1974
Puttemans, J.P., Ionisation de cycloalcanes (C5 a C12) en spectroscopie photoelectronique et par impact electronique, Ing. Chim. (Brussels), 1974, 56, 64. [all data]

Morgan, Derrick, et al., 1980
Morgan, R.P.; Derrick, P.J.; Loudon, A.G., Kinetics and mechanisms of the decompositions of the molecular ions of pentanal and its monomethyl- substituted homologues in the picosecond to microsecond time interval following field ionization, J. Chem. Soc. Perkin Trans. 2, 1980, 306. [all data]

Holmes, Terlouw, et al., 1976
Holmes, J.L.; Terlouw, J.K.; Lossing, F.P., The thermochemistry of C2H4O+ ions, J. Phys. Chem., 1976, 80, 2860. [all data]

Audier, Bouchoux, et al., 1982
Audier, H.E.; Bouchoux, G.; Hoppilliard, Y.; Milliet, A., The mechanism of formation of [C4H9O]+ ions from isobutyl etyhyl ether, Org. Mass Spectrom., 1982, 17, 382. [all data]

Brehm, 1966
Brehm, B., Massenspektrometrische Untersuchung der Photoionisation von Molekulen, Z. Naturforsch., 1966, 21a, 196. [all data]


Notes

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