Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

C3H6+ (structure unspecified)


Gas phase ion energetics data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Reactions leading to C3H6+ (ion structure unspecified)

Precursor AP (eV) Other Products Method Reference Comment
C3H6BrNO11.15?EIDay, Gowenlock, et al., 1978 
C3H6ClNO11.35?EIDay, Gowenlock, et al., 1978 
C3H6N2O311.20?EIDay, Gowenlock, et al., 1978 
C3H7BF211.48 ± 0.02?EISteele, Nichols, et al., 1962 
C3H7Cl10.82HClPITraeger, 1980 
C3H7Cl10.89 ± 0.03HClEIMaccoll and Mathur, 1980 
C3H7Cl11.03HClEIBaldwin, Maccoll, et al., 1966 
C3H7Cl13.3 ± 0.03HClEIMaccoll and Mathur, 1980 
C3H7Cl10.3HClEIBaldwin, Maccoll, et al., 1966 
C3H7Cl3Si10.92?EISteele, Nichols, et al., 1962, 2 
C3H7NO10.8 ± 0.1?EICarmichael, Gowenlock, et al., 1972 
C3H812. ± 1.H2PIAu, Cooper, et al., 1993 
C3H811.75 ± 0.05H2PIChupka and Berkowitz, 1967 
C3H8O~12.0 ± 0.9H2OEIBowen and Maccoll, 1984 
C3H8O~12.0H2OPIRefaey and Chupka, 1968 
C3H8O10.56 ± 0.05H2OEIHolmes, Mommers, et al., 1984 
C3H8O10.65 ± 0.09H2OEIBowen and Maccoll, 1984 
C3H8O10.3H2OEIMcLafferty, Bente, et al., 1973 
C3H8O10.33 ± 0.03H2OEIJohnstone and Mellon, 1972 
C3H8O10.65 ± 0.03H2OPIRefaey and Chupka, 1968 
C3H8O10.50H2OPIChupka, 1959 
C3H10Si10.81 ± 0.04?EISteele, Nichols, et al., 1962, 2 
C4H6O9.85 ± 0.15COEIBranton and Pua, 1973 
C4H7N12.13?EIHeerma and deRidder, 1970 
C4H7N12.25?EIHeerma and deRidder, 1970 
C4H8O11.54?EICollin and Conde-Caprace, 1966 
C4H8O211.4 ± 0.1CH2O2PIPECOButler, Fraser-Monteiro, et al., 1982T = 298K
C4H8O210.7 ± 0.2HCOOHCEMSJalonen, Tedder, et al., 1980 
C4H1011.15CH4EIWolkoff and Holmes, 1978 
C4H1011.06CH4EIMatsumoto, Taniguchi, et al., 1970 
C4H1011.18CH4PIChupka and Berkowitz, 1967 
C4H1011.16 ± 0.03CH4PISteiner, Giese, et al., 1961 
C4H1010.89 ± 0.02CH4PIMead, Donchi, et al., 1980 
C4H1010.91CH4EIWolkoff and Holmes, 1978 
C4H1010.93 ± 0.03CH4PISteiner, Giese, et al., 1961 
C4H10O11.00 ± 0.03CH3OHPIPECOShao, Baer, et al., 1988 
C4H10O211.1 ± 0.1H2O+CH2OEIHolmes, Mommers, et al., 1984 
C4H10S13.5?EIHobrock and Kiser, 1963 
C4H10S12.5 ± 0.4?EIHobrock and Kiser, 1962 
C5H812.73 ± 0.03C2H2EIFranklin and Mogenis, 1967 
C5H812.76 ± 0.10C2H2EIPuttemans and Delvaux, 1973 
C5H9N9.39C2H3NPIAkopyan, Vilesov, et al., 1975 
C5H1010.68 ± 0.02C2H4PIBrand and Baer, 1984 
C5H1011.61 ± 0.08C2H4EIGross and Wilkins, 1971 
C5H1011.23 ± 0.04C2H4EINatalis and Laune, 1964 
C5H1011.29 ± 0.05C2H4EINatalis and Laune, 1964 
C5H1011.22 ± 0.04C2H4PIBrand and Baer, 1984 
C5H1011.45C2H4EIPuttemans, 1974 
C5H1011.74 ± 0.07C2H4EIGross and Wilkins, 1971 
C5H1011.70 ± 0.11C2H4EIGross and Wilkins, 1971 
C5H1010.76 ± 0.05C2H4PIBrand and Baer, 1984 
C5H1011.54 ± 0.10C2H4EIGross and Wilkins, 1971 
C5H1011.66 ± 0.06C2H4EIGross and Wilkins, 1971 
C5H1011.54 ± 0.02C2H4EIGross and Wilkins, 1971 
C5H1011.73 ± 0.11C2H4EIGross and Wilkins, 1971 
C5H1011.26C2H4EINatalis and Laune, 1964 
C5H10O11.90C2H4OEIMorgan, Derrick, et al., 1980 
C5H10O212.28?EICollin and Conde-Caprace, 1966 
C5H11F11.47?EILorquet-Julien, 1961 
C5H11N9.58C2H5NPIAkopyan, Vilesov, et al., 1975 
C5H1211.02C2H6PITraeger, Hudson, et al., 1996T = 0K
C5H1210.99 ± 0.02C2H6PISteiner, Giese, et al., 1961 
C5H1210.66C2H6PITraeger, Hudson, et al., 1996T = 0K
C5H1210.84 ± 0.025C2H6PISteiner, Giese, et al., 1961 
C6H1212.00 ± 0.07C3H6EIRabbih, Selim, et al., 1981 
C6H1211.23 ± 0.04C3H6PISergeev, Akopyan, et al., 1973 
C6H12O11.00C3H6OEIMorgan, Derrick, et al., 1980 
C6H1410.91 ± 0.05C3H8PISteiner, Giese, et al., 1961 
C6H1411.00 ± 0.035C3H8PISteiner, Giese, et al., 1961 
C6H1410.70 ± 0.02C3H8PISteiner, Giese, et al., 1961 
C7H1610.7 ± 0.1C4H10PIBrehm, 1966 
C7H1610.97 ± 0.08C4H10PISteiner, Giese, et al., 1961 
C8H12N4O211.35?EIDay, Gowenlock, et al., 1978 
C8H20P211.3 ± 0.3?EIBogolyubov, Grishin, et al., 1969 
C10H18N2O610.70?EIDay, Gowenlock, et al., 1978 
C12H22N2O411.30?EIDay, Gowenlock, et al., 1978 
C16H36Li411. ± 0.50?PIMcLean, Murray, et al., 1978 

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Day, Gowenlock, et al., 1978
Day, J.S.; Gowenlock, B.G.; Johnson, C.A.F.; McInally, I.D.; Pfab, J., Appearance potential studies of some geminal substituted C-nitroso- compounds, J. Chem. Soc. Perkin Trans. 2, 1978, 10, 1110. [all data]

Steele, Nichols, et al., 1962
Steele, W.C.; Nichols, L.D.; Stone, F.G.A., An electron impact investigation of some organoboron difluorides, J. Am. Chem. Soc., 1962, 84, 1154. [all data]

Traeger, 1980
Traeger, J.C., Photoionization mass spectrometry of the propyl halides, Int. J. Mass Spectrom. Ion Phys., 1980, 32, 309. [all data]

Maccoll and Mathur, 1980
Maccoll, A.; Mathur, D., Hydrogen chloride elimination from the molecular ions of alkyl chlorides, Org. Mass Spectrom., 1980, 15, 483. [all data]

Baldwin, Maccoll, et al., 1966
Baldwin, M.; Maccoll, A.; Miller, S.I., Ionization and appearance potentials from a study of alkyl chlorides, Advan. Mass Spectrom., 1966, 3, 259. [all data]

Steele, Nichols, et al., 1962, 2
Steele, W.C.; Nichols, L.D.; Stone, F.G.A., The determination of silicon-carbon and silicon-hydrogen bond dissociation energies by electron impact, J. Am. Chem. Soc., 1962, 84, 4441. [all data]

Carmichael, Gowenlock, et al., 1972
Carmichael, P.J.; Gowenlock, B.G.; Johnson, C.A.F., Carbon-nitrogen bond dissociation energy values in C-nitrosocompounds, Int. J. Chem. Kinet., 1972, 4, 339. [all data]

Au, Cooper, et al., 1993
Au, J.W.; Cooper, G.; Brion, C.E., The molecular and dissociative photoionization of ethane, propane, and n-butane: Absolute oscillator strengths (10-80 eV) and breakdown pathways, Chem. Phys., 1993, 173, 241. [all data]

Chupka and Berkowitz, 1967
Chupka, W.A.; Berkowitz, J., Photoionization of ethane, propane, and n-butane with mass analysis, J. Chem. Phys., 1967, 47, 2921. [all data]

Bowen and Maccoll, 1984
Bowen, R.D.; Maccoll, A., Low energy, low temperature mass spectra, Org. Mass Spectrom., 1984, 19, 379. [all data]

Refaey and Chupka, 1968
Refaey, K.M.A.; Chupka, W.A., Photoionization of the lower aliphatic alcohols with mass analysis, J. Chem. Phys., 1968, 48, 5205. [all data]

Holmes, Mommers, et al., 1984
Holmes, J.L.; Mommers, A.A.; Szulejko, J.E.; Terlouw, J.K., Two new stable [C3H8O]+ isomers: The radical cations [C3H6OH2]+, J. Chem. Soc., Chem. Commun., 1984, 165. [all data]

McLafferty, Bente, et al., 1973
McLafferty, F.W.; Bente, P.F., III; Kornfeld, R.; Tsai, S.-C.; Howe, I., Collisional activation spectra of organic ions, J. Am. Chem. Soc., 1973, 95, 2120. [all data]

Johnstone and Mellon, 1972
Johnstone, R.A.W.; Mellon, F.A., Electron-impact ionization and appearance potentials, J. Chem. Soc. Faraday Trans. 2, 1972, 68, 1209. [all data]

Chupka, 1959
Chupka, W.A., Effect of unimolecular decay kinetics on the interpretation of appearance potentials, J. Chem. Phys., 1959, 30, 191. [all data]

Branton and Pua, 1973
Branton, G.R.; Pua, C.K.N., Low energy electron impact ionization and fragmentation-cyclobutanone, Can. J. Chem., 1973, 51, 624. [all data]

Heerma and deRidder, 1970
Heerma, W.; deRidder, J.J., The electron-impact induced fragmentation of some alkyl isocyanides and alpha-branched alkyl cyanides, Org. Mass Spectrom., 1970, 3, 1439. [all data]

Collin and Conde-Caprace, 1966
Collin, J.E.; Conde-Caprace, G., Ionization and dissociation of cyclic ethers by electron impact, Intern. J. Mass Spectrom. Ion Phys., 1966, 1, 213. [all data]

Butler, Fraser-Monteiro, et al., 1982
Butler, J.J.; Fraser-Monteiro, M.L.; Fraser-Monteiro, L.; Baer, T.; Hass, J.R., Thermochemistry and dissociation dynamics of state-selected C4H8O2+ Ions. 2. Butanoic acid, J. Phys. Chem., 1982, 86, 747. [all data]

Jalonen, Tedder, et al., 1980
Jalonen, J.; Tedder, J.M.; Nidaud, P.H., Charge-exchange mass spectra of ethyl acetate, methyl proprionate and propyl formate, J. Chem. Soc. Faraday Trans. 2, 1980, 76, 1450. [all data]

Wolkoff and Holmes, 1978
Wolkoff, P.; Holmes, J.L., Fragmentations of alkane molecular ions, J. Am. Chem. Soc., 1978, 100, 7346. [all data]

Matsumoto, Taniguchi, et al., 1970
Matsumoto, A.; Taniguchi, S.; Hayakawa, T., Studies of dissociation of hydrogen and n-butane metastable ions by a pulsed ion source in Recent Developments in Mass Spectrometry, ed. K. Ogata and T. Hayakawa, Univ. Park Press, Baltimore, MD, 1970, 820. [all data]

Steiner, Giese, et al., 1961
Steiner, B.; Giese, C.F.; Inghram, M.G., Photoionization of alkanes. Dissociation of excited molecular ions, J. Chem. Phys., 1961, 34, 189. [all data]

Mead, Donchi, et al., 1980
Mead, P.T.; Donchi, K.F.; Traeger, J.C.; Christie, J.R.; Derrick, P.J., Secondary hydrogen isotope effect in the unimolecular decomposition of 2-methylpropane radical cations, J. Am. Chem. Soc., 1980, 102, 3364. [all data]

Shao, Baer, et al., 1988
Shao, J.D.; Baer, T.; Lewis, D.K., Dissociation dynamics of energy-selected ion-dipole complexes. 2. Butyl alcohol ions, J. Phys. Chem., 1988, 92, 5123. [all data]

Hobrock and Kiser, 1963
Hobrock, B.G.; Kiser, R.W., Electron impact investigations of sulfur compounds. II. 3-Methyl-2-thiabutane, 4-thia-1-pentene, and 3,4-dithiahexane, J. Phys. Chem., 1963, 67, 648. [all data]

Hobrock and Kiser, 1962
Hobrock, B.G.; Kiser, R.W., Electron impact spectroscopy of sulfur compounds. I. 2-Thiabutane, 2-thiapentane, and 2,3-dithiabutane, J. Phys. Chem., 1962, 66, 1648. [all data]

Franklin and Mogenis, 1967
Franklin, J.L.; Mogenis, A., An electron impact study of ions from several dienes, J. Phys. Chem., 1967, 71, 2820. [all data]

Puttemans and Delvaux, 1973
Puttemans, J.-P.; Delvaux, J.C., Ionisation et fragmentation d'isomeres C5H8 sous impact electronique. Spiropentane - methylenecyclobutane - isoprene, Ing. Chim. Brussell, 1973, 55(267-8), 7. [all data]

Akopyan, Vilesov, et al., 1975
Akopyan, M.E.; Vilesov, F.I.; Loginov, Y.V., Photoionization of amines and the monomolecular decomposition of excited molecular ions, Khim. Vys. Energ., 1975, 9, 327. [all data]

Brand and Baer, 1984
Brand, W.A.; Baer, T., Dissociation dynamics of energy-selected C5H10+ ions, J. Am. Chem. Soc., 1984, 106, 3154. [all data]

Gross and Wilkins, 1971
Gross, M.L.; Wilkins, C.L., Computer-assisted ion cyclotron resonance appearance potential measurements for C5H10 isomers, Anal. Chem., 1971, 43, 1624. [all data]

Natalis and Laune, 1964
Natalis, P.; Laune, J., Etude du comportement d'isomeres geometriques sous l'impact electronique. IV. Cyclopropane, methylcyclopropane et dimethylcyclopropanes gem. cis et trans, Bull. Soc. Chim. Belges, 1964, 73, 944. [all data]

Puttemans, 1974
Puttemans, J.P., Ionisation de cycloalcanes (C5 a C12) en spectroscopie photoelectronique et par impact electronique, Ing. Chim. (Brussels), 1974, 56, 64. [all data]

Morgan, Derrick, et al., 1980
Morgan, R.P.; Derrick, P.J.; Loudon, A.G., Kinetics and mechanisms of the decompositions of the molecular ions of pentanal and its monomethyl- substituted homologues in the picosecond to microsecond time interval following field ionization, J. Chem. Soc. Perkin Trans. 2, 1980, 306. [all data]

Lorquet-Julien, 1961
Lorquet-Julien, J.C., Comportement du 1 fluoro- et du 1 chloropentane normal et des derives halogenescorrespondants du cyclopentane sous l'impact electronique, Bull. Soc. Roy. Sci. Liege, 1961, 30, 170. [all data]

Traeger, Hudson, et al., 1996
Traeger, J.C.; Hudson, C.E.; McAdoo, D.J., A photoionization study of the ion-neutral complexes [CH3CH+CH3CH2CH3] and [CH3CH2CH+CH3CH3] in the gas phase: Formation, H-transfer and C-C bond formation between partners, and channeling of energy into dissociation, J. Am. Soc. Mass Spectrom., 1996, 7, 73. [all data]

Rabbih, Selim, et al., 1981
Rabbih, M.A.; Selim, E.T.M.; Fahmey, M.A., Ionization & fragmentation of cyclohexane, Indian J. Pure Appl. Phys., 1981, 19, 962. [all data]

Sergeev, Akopyan, et al., 1973
Sergeev, Yu.L.; Akopyan, M.E.; Vilesov, F.I.; Chizhov, Yu.V., Photoionization processes in gaseous cyclohexane, and chloro- and bromocyclohexane, High Energy Chem., 1973, 7, 369, In original 418. [all data]

Brehm, 1966
Brehm, B., Massenspektrometrische Untersuchung der Photoionisation von Molekulen, Z. Naturforsch., 1966, 21a, 196. [all data]

Bogolyubov, Grishin, et al., 1969
Bogolyubov, G.M.; Grishin, N.N.; Petrov, A.A., Organic derivatives of group V and group VI elements. VIII.Mass spectra of phosphines and diphosphines, Zh. Obshch. Khim., 1969, 39, 1808, In original 1772. [all data]

McLean, Murray, et al., 1978
McLean, W.; Murray, P.T.; Baer, T.; Jarnagin, R.C., Dissociative photoionization of t-butyl-lithium, J. Chem. Phys., 1978, 69, 2715. [all data]


Notes

Go To: Top, Gas phase ion energetics data, References