C2H5S+ (structure unspecified)


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Reactions leading to C2H5S+ (ion structure unspecified)

Precursor AP (eV) Other Products Method Reference Comment
C2H5BrS10.1 ± 0.15BrEIBroer, Weringa, et al., 1979 
C2H6OS10.55 ± 0.07?PIPECOZha, Nishimura, et al., 1988 
C2H6OS10.5?EIAmos, Gillis, et al., 1969 
C2H6S11.5HEIAmos, Gillis, et al., 1969 
C2H6S10.85 ± 0.15HPIErmolenko, Akopyan, et al., 1983 
C2H6S10.93 ± 0.02HPIAkopyan, Sergeev, et al., 1970 
C2H6S11.5 ± 0.1HEIKeyes and Harrson, 1968 
C2H6S11.2 ± 0.1HEITaft, Martin, et al., 1965 
C2H6S210.4 ± 0.15SHEIBroer, Weringa, et al., 1979 
C2H6S210.08 ± 0.08SHPIPECOButler, Baer, et al., 1983T = 298K
C2H6S210.0?EIAmos, Gillis, et al., 1969 
C3H5D3S10.8 ± 0.1CD3EIKeyes and Harrson, 1968 
C3H6OS10.4 ± 0.1CHOEIConde-Caprace and Collin, 1972 
C3H6S211.4 ± 0.3CHSEIConde-Caprace and Collin, 1972 
C3H8S10.74CH3EIKeyes and Harrson, 1968 
C3H8S11.0 ± 0.15CH3EIBroer, Weringa, et al., 1979 
C3H8S10.7 ± 0.1CH3EIKeyes and Harrson, 1968 
C3H8S210.1 ± 0.15SCH3EIBroer, Weringa, et al., 1979 
C4H5D5S10.7 ± 0.1C2D5EIKeyes and Harrson, 1968 
C4H8OS10.3 ± 0.2?EIConde-Caprace and Collin, 1969 
C4H8S12.0 ± 0.2?EIHobrock and Kiser, 1963 
C4H8S210.6 ± 0.2?EIConde-Caprace and Collin, 1969 
C4H10S13.5 ± 0.3?EIHobrock and Kiser, 1963 
C4H10S10.23 ± 0.03C2H5PIAkopyan, Sergeev, et al., 1970 
C4H10S11.05C2H5EIGowenlock, Kay, et al., 1963 
C4H10S11.0 ± 0.1C2H5EIKeyes and Harrson, 1968 
C4H10S210.47?EIKeyes and Harrson, 1968 
C5H10O2S10.8 ± 0.2CH2O+CH3COEIConde-Caprace and Collin, 1972, 2 
C5H11NO2S12.43 ± 0.10?EISvec and Junk, 1967 
C6H14S12.2?EIGowenlock, Kay, et al., 1963 

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Broer, Weringa, et al., 1979
Broer, W.J.; Weringa, W.D.; Nieuwpoort, W.C., Rearrangements and fragmentations of [C2H5S]+ ions, Org. Mass Spectrom., 1979, 14, 543. [all data]

Zha, Nishimura, et al., 1988
Zha, Q.; Nishimura, T.; Meisels, G.G., Unimolecular dissociation of energy-selected dimethyl sulfoxide, Int. J. Mass Spectrom. Ion Processes, 1988, 83, 1. [all data]

Amos, Gillis, et al., 1969
Amos, D.; Gillis, R.G.; Occolowitz, J.L.; Pisani, J.F., The ions [CH3S]+, [C2H5S]+ and [CH3O]+ formed by electron-impact, Org. Mass Spectrom., 1969, 2, 209. [all data]

Ermolenko, Akopyan, et al., 1983
Ermolenko, A.I.; Akopyan, M.E.; Sergeev, Y.L., Decomposition of dimethyl sulfide molecular ions. Randomization of states during photoionization dissociation of molecules, High Energy Chem., 1983, 17, 25. [all data]

Akopyan, Sergeev, et al., 1970
Akopyan, M.E.; Sergeev, Yu.L.; Vilesov, F.I., Photionization in vapors of aliphatic sulfides. I. Methymercaptan, dimethyl and diethyl sulfides, High Energy Chem., 1970, 4, 265, In original 305. [all data]

Keyes and Harrson, 1968
Keyes, B.G.; Harrson, A.G., The fragmentation of aliphatic sulfur compounds by electron impact, J. Am. Chem. Soc., 1968, 90, 5671. [all data]

Taft, Martin, et al., 1965
Taft, R.W.; Martin, R.H.; Lampe, F.W., Stabilization energies of substituted methyl cations. The effect of strong demand on the resonance order, J. Am. Chem. Soc., 1965, 87, 2490. [all data]

Butler, Baer, et al., 1983
Butler, J.J.; Baer, T.; Evans, S.A., Jr., Energetics and structures of organosulfur ions: CH3SSCH3+, CH3SS+, C2H5S+, and CH2SH+, J. Am. Chem. Soc., 1983, 105, 3451. [all data]

Conde-Caprace and Collin, 1972
Conde-Caprace, G.; Collin, J.E., Ionization and dissociation of cyclic ethers thioethers by electron-impact. A comparison between 1,3-dioxolane, 1,3-dithiolane and 1,3-oxathiolane, Org. Mass Spectrom., 1972, 6, 415. [all data]

Conde-Caprace and Collin, 1969
Conde-Caprace, G.; Collin, J.E., Ionization and dissociation of cyclic ethers and thioethers by electronimpact. A comparison between 1,4 dioxane, 1,4 dithiane and 1,4 oxathiane, Org. Mass Spectrom., 1969, 2, 1277. [all data]

Hobrock and Kiser, 1963
Hobrock, B.G.; Kiser, R.W., Electron impact investigations of sulfur compounds. II. 3-Methyl-2-thiabutane, 4-thia-1-pentene, and 3,4-dithiahexane, J. Phys. Chem., 1963, 67, 648. [all data]

Gowenlock, Kay, et al., 1963
Gowenlock, B.G.; Kay, J.; Majer, J.R., Electron impact studies of some sulphides and disulphides, J. Chem. Soc. Faraday Trans., 1963, 59, 2463. [all data]

Conde-Caprace and Collin, 1972, 2
Conde-Caprace, G.; Collin, J.E., Electron impact induced fragmentation of 1,3,6-dioxathiocane, Org. Mass Spectrom., 1972, 6, 341. [all data]

Svec and Junk, 1967
Svec, H.J.; Junk, G.A., Electron-impact studies of substituted alkanes, J. Am. Chem. Soc., 1967, 89, 790. [all data]


Notes

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