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C2H4O+ (structure unspecified)


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Reactions leading to C2H4O+ (ion structure unspecified)

Precursor AP (eV) Other Products Method Reference Comment
C2H6O~10.45H2EIHolmes, Terlouw, et al., 1976 
C3H4O310.4CO2EITerlouw, Wezenberg, et al., 1983 
C3H4O310.7 ± 0.2CO2EITerlouw, Wezenberg, et al., 1983 
C3H4O310.32 ± 0.05CO2EIBuschek, Holmes, et al., 1987Ion is CH3OCH+
C3H4O311.34 ± 0.05CH2O2EIBuschek, Holmes, et al., 1987Ion is c-C2H4O+
C3H6O210.30CH2OEIHolmes, Terlouw, et al., 1976 
C3H6O210.87CH2OEIHolmes, Terlouw, et al., 1976 
C3H6O211.56?EICollin and Conde, 1966 
C3H6O310.49 ± 0.05CH2O2EIBuschek, Holmes, et al., 1987Ion is CH2OCH2+
C3H8O10.27 ± 0.09CH4EIBowen and Maccoll, 1984 
C3H8O10.26CH4EIHolmes, Burgers, et al., 1982 
C3H8O10.23 ± 0.02CH4PIPotapov and Sorokin, 1972 
C3H8O10.27 ± 0.03CH4PIRefaey and Chupka, 1968 
C4H8O10.19C2H4EIHolmes, Terlouw, et al., 1976 
C4H8O12.27C2H4EICollin and Conde-Caprace, 1966 
C4H8O10.52C2H4EIHolmes, Terlouw, et al., 1976 
C4H8O9.96 ± 0.03C2H4PIBouchoux, Alcaraz, et al., 1994 
C4H8O9.87C2H4EIHolmes, Terlouw, et al., 1976 
C4H8O210.39 ± 0.05C2H4OPIPECOFraser-Monteiro, Fraser-Monteiro, et al., 1982T = 298K
C4H8O210.90?EICollin and Conde, 1966 
C4H10O10.05 ± 0.02C2H6PIPECOShao, Baer, et al., 1988 
C4H10O10.12C2H6EIBowen and Maccoll, 1984 
C4H10O10.12C2H6EIHolmes, Burgers, et al., 1982 
C4H10O210.26C2H4OEIHolmes, Lossing, et al., 1991 
C5H10O11.40C3H6EIMorgan, Derrick, et al., 1980 
C5H10O10.57C3H6EIHolmes, Terlouw, et al., 1976 
C5H10O310.03?EICollin and Conde, 1966 
C5H12O10.1 ± 0.1C3H8EIGeorge and Holmes, 1990 
C6H12O11.40C4H8EIMorgan, Derrick, et al., 1980 
C6H12O11.40C4H8EIMorgan, Derrick, et al., 1980 
C6H12O10.882-C4H8EIHolmes, Terlouw, et al., 1976 
C6H12O11.60C4H8EIMorgan, Derrick, et al., 1980 
C6H14O~10.7?EIHolmes, Terlouw, et al., 1976 

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Holmes, Terlouw, et al., 1976
Holmes, J.L.; Terlouw, J.K.; Lossing, F.P., The thermochemistry of C2H4O+ ions, J. Phys. Chem., 1976, 80, 2860. [all data]

Terlouw, Wezenberg, et al., 1983
Terlouw, J.K.; Wezenberg, J.; Burgers, P.C.; Holmes, J.L., New stable isomers of [C2H4O]+ and [C2H4O2]+, the radical cations [CH2COH]+ and [CH3OCOH]+, J. Chem. Soc., Chem. Commun., 1983, 1121. [all data]

Buschek, Holmes, et al., 1987
Buschek, J.M.; Holmes, J.L.; Terlouw, J.K., CH3OCH+, a new stable C2H4O+ isomer, and a reassessment of the oxirane+ potential surface, J. Am. Chem. Soc., 1987, 109, 7321. [all data]

Collin and Conde, 1966
Collin, J.E.; Conde, G., L'ionisation et la dissociation des polyethers cycliques soumis a l'impact electronique, Bull. Classe Sci. Acad. Roy. Belg., 1966, 52, 978. [all data]

Bowen and Maccoll, 1984
Bowen, R.D.; Maccoll, A., Low energy, low temperature mass spectra, Org. Mass Spectrom., 1984, 19, 379. [all data]

Holmes, Burgers, et al., 1982
Holmes, J.L.; Burgers, P.C.; Mollah, Y.A., Alkane elimination from ionized alkanols, Org. Mass Spectrom., 1982, 17, 127. [all data]

Potapov and Sorokin, 1972
Potapov, V.K.; Sorokin, V.V., Kinetic energies of products of dissociative photoionization of molecules. I. Aliphatic ketones and alcohols, Khim. Vys. Energ., 1972, 6, 387. [all data]

Refaey and Chupka, 1968
Refaey, K.M.A.; Chupka, W.A., Photoionization of the lower aliphatic alcohols with mass analysis, J. Chem. Phys., 1968, 48, 5205. [all data]

Collin and Conde-Caprace, 1966
Collin, J.E.; Conde-Caprace, G., Ionization and dissociation of cyclic ethers by electron impact, Intern. J. Mass Spectrom. Ion Phys., 1966, 1, 213. [all data]

Bouchoux, Alcaraz, et al., 1994
Bouchoux, G.; Alcaraz, C.; Dutuit, O.; Nguyen, M.T., A photoionization and molecular orbital study of cyclobutanol and cyclobutylamine radical cations, Int. J. Mass Spectrom. Ion Processes, 1994, 137, 93. [all data]

Fraser-Monteiro, Fraser-Monteiro, et al., 1982
Fraser-Monteiro, M.L.; Fraser-Monteiro, L.; Butler, J.J.; Baer, T.; Hass, J.R., Thermochemistry and dissociation dynamics of state-selected C4H8O2+ ions. 1. 1,4-Dioxane, J. Phys. Chem., 1982, 86, 739. [all data]

Shao, Baer, et al., 1988
Shao, J.D.; Baer, T.; Lewis, D.K., Dissociation dynamics of energy-selected ion-dipole complexes. 2. Butyl alcohol ions, J. Phys. Chem., 1988, 92, 5123. [all data]

Holmes, Lossing, et al., 1991
Holmes, J.L.; Lossing, F.P.; Mayer, P.M., Heats of formation of oxygen-containing organic free radicals from appearance energy measurements, J. Am. Chem. Soc., 1991, 113, 9723. [all data]

Morgan, Derrick, et al., 1980
Morgan, R.P.; Derrick, P.J.; Loudon, A.G., Kinetics and mechanisms of the decompositions of the molecular ions of pentanal and its monomethyl- substituted homologues in the picosecond to microsecond time interval following field ionization, J. Chem. Soc. Perkin Trans. 2, 1980, 306. [all data]

George and Holmes, 1990
George, M.; Holmes, J.L., Intermediate ion structures in the fragmentation of metastable 3-methylbutan-2-ol radical cations, Org. Mass Spectrom., 1990, 25, 605. [all data]


Notes

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