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C2H4+ (structure unspecified)


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Reactions leading to C2H4+ (ion structure unspecified)

Precursor AP (eV) Other Products Method Reference Comment
C2H5BF212.08 ± 0.01?EISteele, Nichols, et al., 1962 
C2H5Cl11.38 ± 0.02HClEIMaccoll and Mathur, 1980 
C2H5Cl11.33HClEIBaldwin, Maccoll, et al., 1966 
C2H5Cl3Si12.48 ± 0.05?EISteele, Nichols, et al., 1962, 2 
C2H5D12.52 ± 0.10HDEID'Or, Collin, et al., 1966 
C2H5N13.3 ± 0.2NHEIGallegos and Kiser, 1961 
C2H5NO12.9 ± 0.2?EIEastmond and Pratt, 1970 
C2H611. ± 1.H2PIAu, Cooper, et al., 1993 
C2H611.81 ± 0.05H2EIPlessis and Marmet, 1987 
C2H612.1 ± 0.4H2EIChatham, Hils, et al., 1984 
C2H612.1 ± 0.1H2PIPECOBombach, Dannacher, et al., 1984T = 0K
C2H612.1 ± 0.1H2EISuzuki and Maeda, 1977 
C2H612.08 ± 0.03H2PIChupka and Berkowitz, 1967 
C2H612.24 ± 0.10H2EID'Or, Collin, et al., 1966 
C2H6N212.9 ± 0.3?EIPrasil and Forst, 1968 
C2H6O12.0 ± 0.9H2OEIBowen and Maccoll, 1984 
C2H6O12.0H2OPIRefaey and Chupka, 1968 
C2H6OS13.7 ± 0.3?EIBlais, Cottin, et al., 1970 
C2H6S13.0 ± 0.3?EIGal'perin, Bogolyubov, et al., 1969 
C2H6S215.6 ± 0.3?EIGal'perin, Bogolyubov, et al., 1969 
C3H4O10.2 ± 0.1?EIRothgery, Holt, et al., 1975 
C3H5ClO13.6 ± 0.4?EIWada and Kiser, 1962 
C3H5F313.0 ± 0.2?EISteele and Stone, 1962 
C3H5N12.40 ± 0.05HCNEIFranklin, Wada, et al., 1966 
C3H5N12.83?EIHeerma and deRidder, 1970 
C3H612.4 ± 0.5?EIPeers and Vigny, 1968 
C3H6O12.4 ± 0.3?EIGallegos and Kiser, 1962 
C3H6O11.6 ± 0.2?EIGallegos and Kiser, 1961, 2 
C3H6O210.89 ± 0.05CH2O2PIPECOZha, Nishimura, et al., 1992 
C3H6O211.2?EIKing and Long, 1958 
C3H6O211.3H2O+COEIArakawa, 1991 
C3H6S13.6 ± 0.2?EIGallegos and Kiser, 1962 
C3H811. ± 1.CH4PIAu, Cooper, et al., 1993 
C3H811.69 ± 0.03CH4PIPECOGilman, Hsieh, et al., 1982 
C3H811.52CH4EIWolkoff and Holmes, 1978 
C3H811.55CH4EIHickling and Jennings, 1970 
C3H811.9CH4EIHickling and Jennings, 1970 
C3H811.72 ± 0.02CH4PIChupka and Berkowitz, 1967 
C3H811.5 ± 0.1CH4EILifshitz and Shapiro, 1966 
C3H811.70CH4EILifshitz and Shapiro, 1966 
C3H827.2 ± 0.5CH2++H2?EIEhrhardt and Tekaat, 1964 
C3H8O~11.9?PIRefaey and Chupka, 1968 
C4H4F413.15C2F4EIRavishankara and Hanrahan, 1975 
C4H612.6 ± 0.1C2H2EIDannacher, Flamme, et al., 1980 
C4H612.5 ± 0.1C2H2PIBrehm, 1966 
C4H811.65 ± 0.06C2H4PIPECOVan der Meij, Van Eck, et al., 1989 
C4H811.7 ± 0.2?EIMeisels, Park, et al., 1970 
C4H812.0 ± 0.25?EIMeisels, Park, et al., 1970 
C4H811.0 ± 0.15?EIMeisels, Park, et al., 1970 
C4H811.7 ± 0.25?EIMeisels, Park, et al., 1970 
C4H812.5 ± 0.2?EIMeisels, Park, et al., 1970 
C4H811.8 ± 0.25?EIMeisels, Park, et al., 1970 
C4H8O211.5 ± 0.1C2H4O2PIPECOButler, Fraser-Monteiro, et al., 1982T = 298K
C4H8O211.90 ± 0.102CH2O/C2H4O2PIPECOFraser-Monteiro, Fraser-Monteiro, et al., 1982T = 298K
C4H8O213.16?EICollin and Conde, 1966 
C4H10~11.65C2H6PIChupka and Berkowitz, 1967 
C4H10S14.5 ± 0.3?EIGal'perin, Bogolyubov, et al., 1969 
C4H10S213.2 ± 0.3?EIGal'perin, Bogolyubov, et al., 1969 
C4H10Se15.1 ± 0.3?EIBogolyubov, Grishin, et al., 1969 
C5H10O~13.8?EICollin and Conde-Caprace, 1966 
C8H20P210.0 ± 0.3?EIBogolyubov, Grishin, et al., 1969, 2 
C15H811.69 ± 0.05CH4PIPECOGilman, Hsieh, et al., 1982 
C15H811.91 ± 0.03<13>CH4PIPECOGilman, Hsieh, et al., 1982 

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Steele, Nichols, et al., 1962
Steele, W.C.; Nichols, L.D.; Stone, F.G.A., An electron impact investigation of some organoboron difluorides, J. Am. Chem. Soc., 1962, 84, 1154. [all data]

Maccoll and Mathur, 1980
Maccoll, A.; Mathur, D., Hydrogen chloride elimination from the molecular ions of alkyl chlorides, Org. Mass Spectrom., 1980, 15, 483. [all data]

Baldwin, Maccoll, et al., 1966
Baldwin, M.; Maccoll, A.; Miller, S.I., Ionization and appearance potentials from a study of alkyl chlorides, Advan. Mass Spectrom., 1966, 3, 259. [all data]

Steele, Nichols, et al., 1962, 2
Steele, W.C.; Nichols, L.D.; Stone, F.G.A., The determination of silicon-carbon and silicon-hydrogen bond dissociation energies by electron impact, J. Am. Chem. Soc., 1962, 84, 4441. [all data]

D'Or, Collin, et al., 1966
D'Or, L.; Collin, J.E.; Longree, J., Ionisation et dissociation de l'ethane sous l'impact electronique. Spectres de masse et phenomenes d'echange dans C2H6, C2H5D, CH3CD3 et C2D6, Bull. Classe Sci. Acad. Roy. Belg., 1966, 52, 518. [all data]

Gallegos and Kiser, 1961
Gallegos, E.; Kiser, R.W., Electron impact spectroscopy of ethylene sulfide and ethylenimine, J. Phys. Chem., 1961, 65, 1177. [all data]

Eastmond and Pratt, 1970
Eastmond, G.B.M.; Pratt, G.L., Pyrolyses in the presence of nitric oxide. Part III.Acetaldehyde oxime and nitrosoethane, J. Chem. Soc. A, 1970, 2337. [all data]

Au, Cooper, et al., 1993
Au, J.W.; Cooper, G.; Brion, C.E., The molecular and dissociative photoionization of ethane, propane, and n-butane: Absolute oscillator strengths (10-80 eV) and breakdown pathways, Chem. Phys., 1993, 173, 241. [all data]

Plessis and Marmet, 1987
Plessis, P.; Marmet, P., Electroionization study of ethane: Ionization and appearance energies, ion-pair formations and negative ions, Can. J. Chem., 1987, 65, 1424. [all data]

Chatham, Hils, et al., 1984
Chatham, H.; Hils, D.; Robertson, R.; Gallagher, A., Total and partial electron collisional ionization cross sections for CH4, C2H6, SiH4, and Si2H6, J. Chem. Phys., 1984, 81, 1770. [all data]

Bombach, Dannacher, et al., 1984
Bombach, R.; Dannacher, J.; Stadelmann, J.-P., The rate/energy functions for the competitive fragmentation processes of ethylene and ethane cations, Int. J. Mass Spectrom. Ion Processes, 1984, 58, 217. [all data]

Suzuki and Maeda, 1977
Suzuki, I.H.; Maeda, K., Behavior of hydrogen atoms in the fragmentation of CH3CD3, Can. J. Chem., 1977, 55, 3124. [all data]

Chupka and Berkowitz, 1967
Chupka, W.A.; Berkowitz, J., Photoionization of ethane, propane, and n-butane with mass analysis, J. Chem. Phys., 1967, 47, 2921. [all data]

Prasil and Forst, 1968
Prasil, Z.; Forst, W., Mass spectrometry of azomethane, J. Am. Chem. Soc., 1968, 90, 3344. [all data]

Bowen and Maccoll, 1984
Bowen, R.D.; Maccoll, A., Low energy, low temperature mass spectra, Org. Mass Spectrom., 1984, 19, 379. [all data]

Refaey and Chupka, 1968
Refaey, K.M.A.; Chupka, W.A., Photoionization of the lower aliphatic alcohols with mass analysis, J. Chem. Phys., 1968, 48, 5205. [all data]

Blais, Cottin, et al., 1970
Blais, J.-C.; Cottin, M.; Gitton, B., Ionisation positive et negative dans le dimethylsulfoxyde en phase gazeuse, J. Chim. Phys., 1970, 67, 1475. [all data]

Gal'perin, Bogolyubov, et al., 1969
Gal'perin, Ya.V.; Bogolyubov, G.M.; Grishin, N.N.; Petrov, A.A., Organic derivatives of elements of groups V and VI. VI. Mass spectra of compounds with S-S bonds, Zh. Obshch. Khim., 1969, 39, 1599, In original 1567. [all data]

Rothgery, Holt, et al., 1975
Rothgery, E.F.; Holt, J.; McGee, H.A., Jr., Cryochemical synthesis and molecular energetics of cyclopropanone and some related compounds, J. Am. Chem. Soc., 1975, 97, 4971. [all data]

Wada and Kiser, 1962
Wada, Y.; Kiser, R.W., Electron impact spectroscopy of some substituted oxiranes, J. Phys. Chem., 1962, 66, 1652. [all data]

Steele and Stone, 1962
Steele, W.C.; Stone, F.G.A., An electron impact study of 1,1,1-trifluoroethane, 1,1,1-trifluoropropane and 3,3,3-trifluoropropene, J. Am. Chem. Soc., 1962, 84, 3450. [all data]

Franklin, Wada, et al., 1966
Franklin, J.L.; Wada, Y.; Natalis, P.; Hierl, P.M., Ion-molecule reactions in acetonitrile and propionitrile, J. Phys. Chem., 1966, 70, 2353. [all data]

Heerma and deRidder, 1970
Heerma, W.; deRidder, J.J., The electron-impact induced fragmentation of some alkyl isocyanides and alpha-branched alkyl cyanides, Org. Mass Spectrom., 1970, 3, 1439. [all data]

Peers and Vigny, 1968
Peers, A.M.; Vigny, P., Reactions molecule-ion dans le propylene, J. Chim. Phys., 1968, 65, 805. [all data]

Gallegos and Kiser, 1962
Gallegos, E.J.; Kiser, R.W., Electron impact spectroscopy of the four- and five-membered, saturated heterocyclic compounds containing nitrogen, oxygen and sulfur, J. Phys. Chem., 1962, 66, 136. [all data]

Gallegos and Kiser, 1961, 2
Gallegos, E.J.; Kiser, R.W., Electron impact spectroscopy of ethylene oxide and propylene oxide, J. Am. Chem. Soc., 1961, 83, 773. [all data]

Zha, Nishimura, et al., 1992
Zha, Q.; Nishimura, T.; Meisels, G.G., Unimolecular dissociation of energy-selected ethyl formate ions, Int. J. Mass Spectrom. Ion Processes, 1992, 120, 85. [all data]

King and Long, 1958
King, A.B.; Long, F.A., Mass spectra of some simple esters and their interpretation by quasi-equilibrium theory, J. Chem. Phys., 1958, 29, 374. [all data]

Arakawa, 1991
Arakawa, R., Mass spectral study of ionized-hydroxyacetone dissociation, Bull. Chem. Soc. Jpn., 1991, 64, 1022. [all data]

Gilman, Hsieh, et al., 1982
Gilman, J.P.; Hsieh, T.; Meisels, G.G., Carbon skeletal rearrangement of the propane ion, J. Chem. Phys., 1982, 76, 3497. [all data]

Wolkoff and Holmes, 1978
Wolkoff, P.; Holmes, J.L., Fragmentations of alkane molecular ions, J. Am. Chem. Soc., 1978, 100, 7346. [all data]

Hickling and Jennings, 1970
Hickling, R.D.; Jennings, K.R., Kinetic shifts and metastable transitions, Org. Mass Spectrom., 1970, 3, 1499. [all data]

Lifshitz and Shapiro, 1966
Lifshitz, C.; Shapiro, M., Isotope effects on metastable transitions: C3H8 and C3D8, J. Chem. Phys., 1966, 45, 4242. [all data]

Ehrhardt and Tekaat, 1964
Ehrhardt, H.; Tekaat, T., Auftrittspotentialmessungen an ionisierten Molekulbruchstucken mit kinetischer Anfangsenergie, Z. Naturforsch., 1964, 19a, 1382. [all data]

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Ravishankara, A.R.; Hanrahan, R.J., An electron impact investigation of 1,1,2,2-tetrafluorocyclobutane, J. Phys. Chem., 1975, 79, 876. [all data]

Dannacher, Flamme, et al., 1980
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Brehm, 1966
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Van der Meij, C.E.; Van Eck, J.; Niehaus, A., The decomposition of C4H8 complexes at controlled internal energies, Chem. Phys., 1989, 130, 325. [all data]

Meisels, Park, et al., 1970
Meisels, G.G.; Park, J.Y.; Giessner, B.G., Ionization and dissociation of C4H8 isomers, J. Am. Chem. Soc., 1970, 92, 254. [all data]

Butler, Fraser-Monteiro, et al., 1982
Butler, J.J.; Fraser-Monteiro, M.L.; Fraser-Monteiro, L.; Baer, T.; Hass, J.R., Thermochemistry and dissociation dynamics of state-selected C4H8O2+ Ions. 2. Butanoic acid, J. Phys. Chem., 1982, 86, 747. [all data]

Fraser-Monteiro, Fraser-Monteiro, et al., 1982
Fraser-Monteiro, M.L.; Fraser-Monteiro, L.; Butler, J.J.; Baer, T.; Hass, J.R., Thermochemistry and dissociation dynamics of state-selected C4H8O2+ ions. 1. 1,4-Dioxane, J. Phys. Chem., 1982, 86, 739. [all data]

Collin and Conde, 1966
Collin, J.E.; Conde, G., L'ionisation et la dissociation des polyethers cycliques soumis a l'impact electronique, Bull. Classe Sci. Acad. Roy. Belg., 1966, 52, 978. [all data]

Bogolyubov, Grishin, et al., 1969
Bogolyubov, G.M.; Grishin, N.N.; Petrov, A.A., Organic derivatives of group V and group VI elements. X. Mass spectra of tetraethyldistibine, diethyl diselenide, diethyl ditelluride, and the corresponding monoderivatives. Interpretation of mass-spectral intensities, Zh. Obshch. Khim., 1969, 39, 2244, In original 2190. [all data]

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Collin, J.E.; Conde-Caprace, G., Ionization and dissociation of cyclic ethers by electron impact, Intern. J. Mass Spectrom. Ion Phys., 1966, 1, 213. [all data]

Bogolyubov, Grishin, et al., 1969, 2
Bogolyubov, G.M.; Grishin, N.N.; Petrov, A.A., Organic derivatives of group V and group VI elements. VIII.Mass spectra of phosphines and diphosphines, Zh. Obshch. Khim., 1969, 39, 1808, In original 1772. [all data]


Notes

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