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1,3,5-Trinitrobenzene

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafsolid-37. ± 1.kJ/molCcbLebedeva, Ryadnenko, et al., 1971Hfusion=4.0±0.1; ALS
Quantity Value Units Method Reference Comment
Deltacsolid-2753. ± 0.4kJ/molCcbLebedeva, Ryadnenko, et al., 1971Hfusion=4.0±0.1; ALS
Deltacsolid-2745.9 ± 2.8kJ/molCcbBadoche, 1939Reanalyzed by Cox and Pilcher, 1970, Original value = -2750.9 kJ/mol; ALS
Deltacsolid-2746.8 ± 2.8kJ/molCcbBurlot, 1939Reanalyzed by Cox and Pilcher, 1970, Original value = -2763.0 kJ/mol; ALS
Deltacsolid-2785.kJ/molCcbGarner and Abernethy, 1921ALS

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
214.6298.15Radomska and Radomski, 1980T = 180 to 400 K. Data given graphically; Cp calculated from equation. Thermodynamically stable modification I.; DH
222.7298.15Radomska and Radomski, 1980T = 180 to 380 K. Data given graphically; Cp calculated from equation. Metastable modification II.; DH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lebedeva, Ryadnenko, et al., 1971
Lebedeva, N.D.; Ryadnenko, V.L.; Kuznetsova, I.N., Heats of combustion and enthalpies of formation of certain aromatic nitro-derivatives, Russ. J. Phys. Chem. (Engl. Transl.), 1971, 45, 549. [all data]

Badoche, 1939
Badoche, M.M., Determinations des chaleurs de combustion de derives nitres de la serie benzenique, Bull. Soc. Chim. France, 1939, 6, 570-579. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Burlot, 1939
Burlot, E., Etude relative a la calorimetrie des explosifs, Mem. Poudres, 1939, 29, 226-260. [all data]

Garner and Abernethy, 1921
Garner, W.E.; Abernethy, C.L., Heats of combustion and formation of nitro-compounds. Part I. - Benzene, toluene, phenol and methylaniline series, Proc. Roy. Soc. London A, 1921, 213-235. [all data]

Radomska and Radomski, 1980
Radomska, M.; Radomski, R., Calorimetric studies of binary systems of 1,3,5-trinitrobenzene with naphthalene, anthracene, and carbazole. I. Phase transitions and heat capacities of the pure components and charge-transfer complexes, Thermochim. Acta, 1980, 40, 405-414. [all data]


Notes

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