Digermane, hexamethyl-

• Formula: C₆H₁₈Ge₂
• Molecular weight: 235.49
• IUPAC Standard InChI: InChI=1S/C6H18Ge2/c1-7(2,3)8(4,5)6/h1-6H3 Copy

  
• IUPAC Standard InChIKey: HLEHOFVKHRHBQI-UHFFFAOYSA-N Copy
• CAS Registry Number: 993-52-2
• Chemical structure:
  This structure is also available as a 2d Mol file
• Other names: Hexamethyldigermane
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• Information on this page:
  • Gas phase ion energetics data
  • References
  • Notes
• Other data available:
  • Mass spectrum (electron ionization)
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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to C₆H₁₈Ge₂⁺ (ion structure unspecified)

Ionization energy determinations

Appearance energy determinations

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Traven', Redchenko, et al., 1982
Traven', V.F.; Redchenko, V.V.; Bartenev, Y.; Stepanov, B.I., Photoelectron spectra of permethyl-di-, -tri-, and -tetra-germanes, J. Gen. Chem. USSR, 1982, 52, 310, In original 358. [all data]

Szepes, Koranyi, et al., 1981
Szepes, L.; Koranyi, T.; Naray-Szabo, G.; Modelli, A.; Distefano, G., Ultraviolet photoelectron spectra of group IV hexamethyl derivatives containing a metal-metal bond, J. Organomet. Chem., 1981, 217, 35. [all data]

Lappert, Pedley, et al., 1971
Lappert, M.F.; Pedley, J.B.; Simpson, J.; Spalding, T.R., Bonding studies of compounds of boron and the Group IV elements. VI. Mass spectrometric studies on compounds Me₄M and Me₃M-M'Me₃ (M and M'=C, Si, Ge, Sn, and Pb): thermochemical data, J. Organomet. Chem., 1971, 29, 195. [all data]

Mochida, Worley, et al., 1985
Mochida, K.; Worley, S.; Kochi, J., UV photoelectron spectra of peralkylated catenates of Group 4B elements (silicon, germanium, and tin), Bull. Chem. Soc. Jpn., 1985, 58, 3389. [all data]

deRidder and Dijkstra, 1968
deRidder, J.J.; Dijkstra, G., On the mass spectra of some alkyl digermanium compounds, Org. Mass Spectrom., 1968, 1, 647. [all data]

Pitt, Bursey, et al., 1970
Pitt, C.G.; Bursey, M.M.; Rogerson, P.F., Catenates of the group IV elements. Correlation of σ electron energies, J. Am. Chem. Soc., 1970, 92, 519. [all data]

Notes

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• Symbols used in this document:
  

  AE	Appearance energy

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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