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m-Nitroaniline

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafsolid-8.17 ± 0.29kcal/molCcrNishiyama, Sakiyama, et al., 1983ALS
Deltafsolid-9.2 ± 0.1kcal/molCcbLebedeva, Gutner, et al., 1971Hfusion=5.7±0.2, see Lebedeva, Rjadnenko, et al., 1969; ALS
Deltafsolid-6.76kcal/molCcbMedard and Thomas, 1957Heat of combustion corrected for pressure; ALS
Deltafsolid-15.17kcal/molCcbRinkenbach, 1930Author hf298_condensed[kcal/mol]=-17.50; ALS
Quantity Value Units Method Reference Comment
Deltacsolid-761.07 ± 0.21kcal/molCcrNishiyama, Sakiyama, et al., 1983ALS
Deltacsolid-760.1 ± 0.1kcal/molCcbLebedeva, Gutner, et al., 1971Hfusion=5.7±0.2, see Lebedeva, Rjadnenko, et al., 1969; ALS
Deltacsolid-762.49kcal/molCcbMedard and Thomas, 1957Heat of combustion corrected for pressure; ALS
Deltacsolid-754.09kcal/molCcbRinkenbach, 1930Author hf298_condensed[kcal/mol]=-17.50; ALS

Constant pressure heat capacity of solid

Cp,solid (cal/mol*K) Temperature (K) Reference Comment
37.964298.15Nishiyama, Sakiyama, et al., 1983Cp given as 1.15 J/g*K.; DH
44.60323.Satoh and Sogabe, 1941T = 0 to 100°C. Mean value.; DH
40.20298.Andrews, Lynn, et al., 1926T = 22 to 210°C.; DH
40.01297.9Andrews, 1926T = 110 to 344 K. Value is unsmoothed experimental datum.; DH

References

Go To: Top, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Nishiyama, Sakiyama, et al., 1983
Nishiyama, K.; Sakiyama, M.; Seki, S., Enthalpies of combustion of organic compounds. V. 3- and 4-nitroanilines, Bull. Chem. Soc. Jpn., 1983, 56, 3171-3172. [all data]

Lebedeva, Gutner, et al., 1971
Lebedeva, N.D.; Gutner, N.M.; Ryadnenko, V.L., Heats of combustion and formation of certain aromatic amino-derivatives, Russ. J. Phys. Chem. (Engl. Transl.), 1971, 45, 561-562. [all data]

Lebedeva, Rjadnenko, et al., 1969
Lebedeva, N.D.; Rjadnenko, B.L.; Gutner, N.M., Heats of formation of some N-containing organic compounds, Int. Conf. Calorim. Therm. (Warsaw, Poland), 1969, 1-8. [all data]

Medard and Thomas, 1957
Medard, L.; Thomas, M., Chaleur de combustion de onze substances explosives ou apparentees a des explosifs, Mem. Poudres, 1957, 39, 195-208. [all data]

Rinkenbach, 1930
Rinkenbach, W.H., The heats of combustion and formation of aromatic nitro compounds, J. Am. Chem. Soc., 1930, 52, 115-120. [all data]

Satoh and Sogabe, 1941
Satoh, S.; Sogabe, T., The heat capacities of some organic compounds containing nitrogen and the atomic heat of nitrogen. (3), Sci., Pap. Inst. Phys. Chem. Res. (Tokyo), 1941, 38, 238-245. [all data]

Andrews, Lynn, et al., 1926
Andrews, D.H.; Lynn, G.; Johnston, J., The heat capacities and heat of crystallization of some isomeric aromatic compounds, J. Am. Chem. Soc., 1926, 48, 1274-1287. [all data]

Andrews, 1926
Andrews, D.H., The specific heats of some isomers of the type ortho, meta and para C6H4XY from 110 to 340K, J. Am. Chem. Soc., 1926, 48, 1287-1298. [all data]


Notes

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