Benzene, (1-methylethyl)-

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Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
CapillaryOV-10160.909.1Chen, Liang, et al., 2001He; Column length: 50. m; Column diameter: 0.25 mm
CapillaryHP-10160.909.82Garay, 200050. m/0.2 mm/0.2 μm, H2
CapillaryOV-1150.930.Zhang, Chen, et al., 199725. m/0.2 mm/0.33 μm, N2
CapillaryOV-1150.930.Zhang, Chen, et al., 199725. m/0.2 mm/0.33 μm, N2
CapillaryOV-101150.935.1Cha and Lee, 1994Column length: 20. m; Column diameter: 0.5 mm
CapillaryOV-101180.942.5Cha and Lee, 1994Column length: 20. m; Column diameter: 0.5 mm
PackedSqualane100.908.Hongwei and Zhide, 1992H2, Silanized white support (80-100 mesh); Column length: 3. m
CapillaryHP-160.909.Zhang, Li, et al., 1992N2; Column length: 25. m; Column diameter: 0.20 mm
CapillaryHP-160.909.Zhang, Li, et al., 1992N2; Column length: 25. m; Column diameter: 0.20 mm
CapillaryHP-1100.919.Zhang, Li, et al., 1992N2; Column length: 25. m; Column diameter: 0.20 mm
CapillaryHP-1100.919.Zhang, Li, et al., 1992N2; Column length: 25. m; Column diameter: 0.20 mm
CapillaryOV-1100.919.5Matisová and Kurán, 199052. m/0.25 mm/0.38 μm, N2
CapillaryOV-1100.919.2Matisová and Kurán, 199052. m/0.25 mm/0.38 μm, H2
CapillaryPONA100.920.1Matisová and Kurán, 199050. m/0.2 mm/0.5 μm, H2
CapillaryOV-190.920.7Maurer, Engewald, et al., 1990Column length: 50. m; Column diameter: 0.32 mm
CapillaryOV-101100.919.Dimov and Mekenyan, 1989Column length: 50. m; Column diameter: 0.25 mm
CapillaryOV-101100.920.Matisová, Kovacicová, et al., 1989He; Column length: 50. m; Column diameter: 0.20 mm
CapillarySqualane50.892.9Lunskii and Paizanskaya, 1988He; Column length: 50. m; Column diameter: 0.22 mm
CapillarySqualane70.898.2Lunskii and Paizanskaya, 1988He; Column length: 50. m; Column diameter: 0.22 mm
CapillaryOV-101100.920.Matisová, Rukríglová, et al., 1988H2; Column length: 278. m; Column diameter: 0.25 mm
CapillaryOV-101100.920.Matisová, Rukríglová, et al., 1988H2; Column length: 278. m; Column diameter: 0.25 mm
CapillaryOV-101100.920.Matisová, Rukríglová, et al., 1988H2; Column length: 278. m; Column diameter: 0.25 mm
CapillaryOV-101100.920.Matisová, Rukríglová, et al., 1988H2; Column length: 278. m; Column diameter: 0.25 mm
CapillaryOV-101100.920.Engewald, Topalova, et al., 1987Column length: 50. m; Column diameter: 0.30 mm
CapillaryOV-101100.919.Boneva, Papazova, et al., 1983N2; Column length: 85. m; Column diameter: 0.28 mm
CapillaryOV-101100.920.Boneva, Papazova, et al., 1983N2; Column length: 85. m; Column diameter: 0.28 mm
CapillaryOV-101100.919.Boneva, Papazova, et al., 1983N2; Column length: 85. m; Column diameter: 0.28 mm
CapillaryOV-101110.922.Boneva, Papazova, et al., 1983N2; Column length: 85. m; Column diameter: 0.28 mm
CapillaryOV-10190.916.Boneva, Papazova, et al., 1983N2; Column length: 85. m; Column diameter: 0.28 mm
CapillarySqualane106.907.Kugucheva and Mashinsky, 1983He; Column length: 100. m
CapillarySqualane96.905.Kugucheva and Mashinsky, 1983He; Column length: 100. m
CapillaryDB-160.909.3Lubeck and Sutton, 1983Column length: 60. m; Column diameter: 0.264 mm
CapillaryDB-160.909.8Lubeck and Sutton, 198360. m/0.259 mm/1. μm
CapillarySE-3070.911.3Tóth, 1983N2; Column length: 15. m; Column diameter: 0.25 mm
PackedSE-30100.921.Winskowski, 1983Gaschrom Q; Column length: 2. m
CapillarySE-30130.929.Bredael, 1982Column length: 100. m; Column diameter: 0.5 mm
CapillarySE-3080.915.Bredael, 1982Column length: 100. m; Column diameter: 0.5 mm
CapillaryOV-101100.920.Gerasimenko and Nabivach, 1982N2; Column length: 50. m; Column diameter: 0.30 mm
CapillaryOV-101120.926.Gerasimenko and Nabivach, 1982N2; Column length: 50. m; Column diameter: 0.30 mm
CapillaryOV-101140.932.Gerasimenko and Nabivach, 1982N2; Column length: 50. m; Column diameter: 0.30 mm
CapillarySqualane86.904.1Macák, Nabivach, et al., 1982N2; Column length: 50. m; Column diameter: 0.25 mm
CapillarySqualane96.906.7Macák, Nabivach, et al., 1982N2; Column length: 50. m; Column diameter: 0.25 mm
CapillaryOV-101100.920.4Gerasimenko, Kirilenko, et al., 1981N2; Column length: 50. m; Column diameter: 0.3 mm
CapillaryOV-101120.925.6Gerasimenko, Kirilenko, et al., 1981N2; Column length: 50. m; Column diameter: 0.3 mm
CapillaryOV-101140.931.8Gerasimenko, Kirilenko, et al., 1981N2; Column length: 50. m; Column diameter: 0.3 mm
CapillarySE-3080.915.5Albaigés and Guardino, 1980He; Column length: 64. m; Column diameter: 0.25 mm
CapillarySqualane80.900.3Albaigés and Guardino, 1980He; Column length: 100. m; Column diameter: 0.25 mm
PackedSqualane100.907.Nabivach and Kirilenko, 1980He, Chromaton N-AW-HMDS; Column length: 1. m
CapillarySqualane86.903.4Nabivach and Kirilenko, 1979N2; Column length: 50. m
CapillarySqualane86.903.9Nabivach and Kirilenko, 1979N2; Column length: 50. m
CapillarySqualane86.904.1Nabivach and Kirilenko, 1979N2; Column length: 50. m
CapillarySqualane86.904.1Nabivach, Bur'yan, et al., 1978Column length: 50. m; Column diameter: 0.25 mm
CapillarySqualane96.906.7Nabivach, Bur'yan, et al., 1978Column length: 50. m; Column diameter: 0.25 mm
CapillarySqualane100.908.Engewald and Wennrich, 1976N2; Column length: 100. m; Column diameter: 0.23 mm
PackedSqualane100.939.Evans and Newton, 1976N2, Chromosorb G; Column length: 2. m
PackedSqualane100.939.Evans and Newton, 1976N2, Chromosorb G; Column length: 2. m
PackedSqualane100.939.Evans and Newton, 1976N2, Chromosorb G; Column length: 2. m
CapillarySqualane100.902.Lulova, Leont'eva, et al., 1976He; Column length: 120. m; Column diameter: 0.25 mm
CapillarySqualane100.902.Lulova, Leont'eva, et al., 1976He; Column length: 120. m; Column diameter: 0.25 mm
CapillarySqualane80.901.00Soják and Rijks, 1976H2; Column length: 100. m; Column diameter: 0.25 mm
PackedSE-30110.922.Mitra, Mohan, et al., 1974N2, Chrom W; Column length: 6.1 m
PackedSE-30120.927.Mitra, Mohan, et al., 1974N2, Chrom W; Column length: 6.1 m
PackedSE-30130.930.Mitra, Mohan, et al., 1974N2, Chrom W; Column length: 6.1 m
PackedSE-30140.932.Mitra, Mohan, et al., 1974N2, Chrom W; Column length: 6.1 m
CapillarySE-30130.929.Mitra, Mohan, et al., 1974, 2H2; Column length: 6.1 m; Column diameter: 3.18 mm
CapillarySE-30140.932.Mitra, Mohan, et al., 1974, 2H2; Column length: 6.1 m; Column diameter: 3.18 mm
CapillarySE-30150.935.Mitra, Mohan, et al., 1974, 2H2; Column length: 6.1 m; Column diameter: 3.18 mm
CapillarySE-30160.937.Mitra, Mohan, et al., 1974, 2H2; Column length: 6.1 m; Column diameter: 3.18 mm
CapillarySE-30170.940.Mitra, Mohan, et al., 1974, 2H2; Column length: 6.1 m; Column diameter: 3.18 mm
CapillarySE-3065.910.1Svob, Deur-Siftar, et al., 1974He; Column length: 25.5 m; Column diameter: 0.5 mm
CapillarySE-3065.910.1Svob, Deur-Siftar, et al., 1974He; Column length: 25.5 m; Column diameter: 0.5 mm
CapillarySE-3065.910.1Svob, Deur-Siftar, et al., 1974He; Column length: 25.5 m; Column diameter: 0.5 mm
CapillarySE-3065.910.1Svob, Deur-Siftar, et al., 1974He; Column length: 25.5 m; Column diameter: 0.5 mm
CapillarySE-3065.910.1Svob, Deur-Siftar, et al., 1974He; Column length: 25.5 m; Column diameter: 0.5 mm
CapillarySE-3065.910.1Svob and Deur-Siftar, 1974He; Column length: 25.5 m; Column diameter: 0.5 mm
CapillarySqualane100.908.0Svob and Deur-Siftar, 1974He; Column length: 10.5 m; Column diameter: 0.25 mm
CapillaryVacuum Grease Oil (VM-4)35.905.Sidorov, Petrova, et al., 1972 
CapillaryVacuum Grease Oil (VM-4)45.908.Sidorov, Petrova, et al., 1972 
CapillaryVacuum Grease Oil (VM-4)50.911.Sidorov, Petrova, et al., 1972 
CapillaryVacuum Grease Oil (VM-4)58.913.Sidorov, Petrova, et al., 1972 
CapillaryVacuum Grease Oil (VM-4)68.916.Sidorov, Petrova, et al., 1972 
PackedApiezon L100.915.Wagaman and Smith, 1971CH4; Column length: 3. m
CapillarySqualane80.903.1Wallaert, 1971Column length: 100. m; Column diameter: 0.25 mm
CapillarySqualane115.910.8Soják and Bucinská, 1970N2; Column length: 200. m; Column diameter: 0.2 mm
CapillarySqualane86.903.5Soják and Bucinská, 1970N2; Column length: 200. m; Column diameter: 0.2 mm
PackedApiezon L100.932.Bonastre and Grenier, 1967Chromosorb P; Column length: 10. m
PackedApiezon L120.940.Bonastre and Grenier, 1967Chromosorb P; Column length: 10. m
PackedApiezon L140.947.Bonastre and Grenier, 1967Chromosorb P; Column length: 10. m
PackedApiezon L80.924.Bonastre and Grenier, 1967Chromosorb P; Column length: 10. m
PackedSqualane120.909.Bonastre and Grenier, 1967Chromosorb P; Column length: 6. m
PackedSqualane140.915.Bonastre and Grenier, 1967Chromosorb P; Column length: 6. m

Kovats' RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryDB-5932.Buchin, Salmon, et al., 200260. m/0.32 mm/1. μm, He, 40. C @ 5. min, 3. K/min, 230. C @ 2. min
CapillaryDB-5925.1Wang, Fingas, et al., 199430. m/0.32 mm/0.25 μm, He, 50. C @ 2. min, 6. K/min; Tend: 300. C
CapillarySE-54917.Rembold, Wallner, et al., 198930. m/0.25 mm/0.25 μm, He, 0. C @ 12. min, 12. K/min; Tend: 250. C
CapillaryOV-101909.Hayes and Pitzer, 1982110. m/0.25 mm/0.20 μm, He, 1. K/min; Tstart: 35. C; Tend: 200. C
CapillaryApiezon L927.Louis, 1971N2, 1. K/min; Column length: 50. m; Column diameter: 0.25 mm; Tstart: 60. C

Kovats' RI, non-polar column, custom temperature program

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Column type Active phase I Reference Comment
CapillarySPB-1911.Borse, Jagan Mohan Rao, et al., 200230. m/0.32 mm/0.25 μm, He; Program: 40C(3min) => 2C/min => 100C => 4C/min => 220C (7min)
CapillaryPetrocol DH-100912.2Haagen-Smit Laboratory, 1997He; Column length: 100. m; Column diameter: 0.2 mm; Program: 5C(10min) => 5C/min => 50C(48min) => 1.5C/min => 195C(91min)
CapillaryDB-1912.Hoekman, 199360. m/0.32 mm/1.0 μm, He; Program: -40 C for 12 min; -40 - 125 C at 3 deg.min; 125-185 C at 6 deg/min; 185 - 220 C at 20 deg/min; hold 220 C for 2 min
CapillarySqualane910.Papazova and Pankova, 1975N2; Column length: 100. m; Column diameter: 0.25 mm; Program: not specified

Kovats' RI, polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
CapillaryCarbowax 20M150.1158.Egazaryants and Maximov, 1998He; Column length: 15. m; Column diameter: 0.5 mm
CapillaryPEG-20M70.1176.9Tóth, 1983N2; Column length: 30. m; Column diameter: 0.3 mm
PackedCarbowax 20M115.1202.1Ellis and Still, 1979Chromosorb G
PackedCarbowax 20M115.1203.6Ellis and Still, 1979Chromosorb G
CapillaryCarbowax 20M100.1169.8Engewald and Wennrich, 1976N2; Column length: 100. m; Column diameter: 0.23 mm
CapillaryCarbowax 20M90.1154.9Döring, Estel, et al., 1974Column length: 100. m; Column diameter: 0.2 mm
PackedPEG-2000152.1232.Anderson, Jurel, et al., 1973He, Celite 545 (44-60 mesh); Column length: 3. m
PackedPEG-2000179.1236.Anderson, Jurel, et al., 1973He, Celite 545 (44-60 mesh); Column length: 3. m
PackedPolyethylene Glycol 4000100.1198.Bonastre and Grenier, 1967Chromosorb P; Column length: 6. m
PackedPolyethylene Glycol 4000120.1205.Bonastre and Grenier, 1967Chromosorb P; Column length: 6. m
PackedPolyethylene Glycol 4000140.1213.Bonastre and Grenier, 1967Chromosorb P; Column length: 6. m
PackedPolyethylene Glycol 400080.1191.Bonastre and Grenier, 1967Chromosorb P; Column length: 6. m

Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryCP-Sil 8CB-MS927.Elmore, Cooper, et al., 20050. m/0.25 mm/0.25 μm, He, 40. C @ 2. min, 4. K/min, 280. C @ 5. min
CapillaryPetrocol DH914.3Censullo, Jones, et al., 200350. m/0.25 mm/0.5 μm, He, 35. C @ 10. min, 3. K/min, 200. C @ 10. min
CapillaryDB-5919.4Song, Lai, et al., 200330. m/0.25 mm/0.25 μm, He, 2. K/min; Tstart: 40. C; Tend: 310. C
CapillaryDB-5922.2Song, Lai, et al., 200330. m/0.25 mm/0.25 μm, He, 4. K/min; Tstart: 40. C; Tend: 310. C
CapillaryDB-5923.6Song, Lai, et al., 200330. m/0.25 mm/0.25 μm, He, 6. K/min; Tstart: 40. C; Tend: 310. C
CapillaryDB-1906.9Sun and Stremple, 200330. m/0.25 mm/0.25 μm, He, 3. K/min; Tstart: 40. C; Tend: 325. C
CapillaryDB-5930.3Xu, van Stee, et al., 200330. m/0.25 mm/1. μm, He, 2.5 K/min; Tstart: 50. C; Tend: 200. C
CapillaryHP-5929.Couladis, Tsortanidou, et al., 200130. m/0.25 mm/0.25 μm, He, 3. K/min; Tstart: 60. C; Tend: 380. C
CapillaryHP-5926.Isidorov, Krajewska, et al., 200130. m/0.25 mm/0.25 μm, He, 3. K/min; Tstart: 40. C; Tend: 180. C
CapillaryOV-101910.8Yin, Liu, et al., 2001N2, 1. K/min; Column length: 80. m; Column diameter: 0.22 mm; Tstart: 30. C; Tend: 130. C
CapillarySE-54928.7Kivi-Etelätalo, Kostiainen, et al., 199750. m/0.32 mm/1. μm, He, 40. C @ 2. min, 10. K/min, 220. C @ 5. min
CapillaryPONA907.2Martos, Saraullo, et al., 199750. m/0.2 mm/0.5 μm, 35. C @ 0.5 min, 1. K/min, 220. C @ 8. min
CapillaryPONA907.9Martos, Saraullo, et al., 199750. m/0.2 mm/0.5 μm, 35. C @ 0.5 min, 1. K/min, 220. C @ 8. min
CapillaryDB-5919.4Lai and Song, 199530. m/0.25 mm/0.25 μm, He, 2. K/min; Tstart: 40. C; Tend: 310. C
CapillaryDB-5922.2Lai and Song, 199530. m/0.25 mm/0.25 μm, He, 4. K/min; Tstart: 40. C; Tend: 310. C
CapillaryDB-5923.6Lai and Song, 199530. m/0.25 mm/0.25 μm, He, 6. K/min; Tstart: 40. C; Tend: 310. C
CapillaryDB-1913.Peng, Hua, et al., 199230. m/0.32 mm/1.5 μm, 40. C @ 4. min, 8. K/min; Tend: 280. C
CapillaryPetrocol DH909.43White, Douglas, et al., 1992100. m/0.25 mm/0.5 μm, He, 1. K/min; Tstart: 30. C; Tend: 220. C
CapillaryPetrocol DH909.62White, Douglas, et al., 1992100. m/0.25 mm/0.5 μm, He, 1. K/min; Tstart: 30. C; Tend: 220. C
CapillaryPetrocol DH910.White, Hackett, et al., 1992100. m/0.25 mm/0.5 μm, He, 1. K/min; Tstart: 30. C; Tend: 220. C
CapillaryUltra-2934.3Akporhonor, le Vent, et al., 199025. m/0.2 mm/0.33 μm, N2, 15. K/min; Tstart: 60.01 C
CapillaryUltra-2929.2Akporhonor, le Vent, et al., 199025. m/0.2 mm/0.33 μm, N2, 2. K/min; Tstart: 60.01 C
CapillaryUltra-2931.6Akporhonor, le Vent, et al., 199025. m/0.2 mm/0.33 μm, N2, 7. K/min; Tstart: 60.01 C
CapillaryUltra-2946.5Akporhonor, le Vent, et al., 199025. m/0.2 mm/0.33 μm, N2, 15. K/min; Tstart: 120.01 C
CapillaryUltra-2941.6Akporhonor, le Vent, et al., 199025. m/0.2 mm/0.33 μm, N2, 2. K/min; Tstart: 120.01 C
CapillaryUltra-2944.9Akporhonor, le Vent, et al., 199025. m/0.2 mm/0.33 μm, N2, 7. K/min; Tstart: 120.01 C
CapillaryDB-5920.Morinaga, Hara, et al., 199015. m/0.53 mm/1.5 μm, He, 4. K/min; Tstart: 40. C; Tend: 90. C
CapillarySE-54914.9Shapi and Hesso, 199025. m/0.32 mm/0.15 μm, He, 40. C @ 1. min, 5. K/min, 280. C @ 15. min
CapillaryUltra-1909.07Steward and Pitzer, 198850. m/0.2 mm/0.33 μm, He, 2. K/min; Tstart: 0. C; Tend: 240. C
CapillaryHP-1910.7Bangjie, Xijian, et al., 1987N2, 10. K/min; Column length: 25. m; Column diameter: 0.2 mm; Tstart: 30. C
CapillaryHP-1906.Bangjie, Xijian, et al., 1987N2, 2. K/min; Column length: 25. m; Column diameter: 0.2 mm; Tstart: 30. C
CapillaryHP-1905.1Bangjie, Xijian, et al., 1987N2, 30. C @ 5. min, 5. K/min; Column length: 25. m; Column diameter: 0.2 mm
CapillarySE-30911.3Krupcík, Repka, et al., 198760. m/0.25 mm/1. μm, H2, 1. K/min; Tstart: 60. C
CapillaryOV-101909.Hayes and Pitzer, 1981108. m/0.25 mm/0.2 μm, 1. K/min; Tstart: 35. C; Tend: 200. C

Van Den Dool and Kratz RI, non-polar column, custom temperature program

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Column type Active phase I Reference Comment
CapillaryCP Sil 8 CB925.Oruna-Concha, Bakker, et al., 200260. m/0.25 mm/0.25 μm, He; Program: 0C => rapidly => 40C(8min) => 4C/min => 250C(10min)
CapillaryMethyl Silicone936.10Hassoun, Pilling, et al., 199950. m/0.25 mm/1. μm, He; Program: -50C(2min) => 49.9C/min => 35C(10min) => 3C/min => 200C(2min) => 40C/min => 240C(30min)
CapillaryDB-1910.Mattinen, Tuominen, et al., 199530. m/0.32 mm/1. μm, He; Program: 40C(3min) => 5C/min => 150C => 10C/min => 210C(30min)
PackedSE-30923.Peng, Ding, et al., 1988Supelcoport; Chromosorb; Column length: 3.05 m; Program: 40C(5min) => 10C/min => 200C or 250C (60min)

Van Den Dool and Kratz RI, polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryCP-Wax 52CB1161.Mahadevan and Farmer, 200660. C @ 5. min, 4. K/min, 220. C @ 30. min; Column length: 50. m; Column diameter: 0.32 mm
CapillarySupelcowax-101182.Elmore, Nisyrios, et al., 200560. m/0.25 mm/0.25 μm, He, 40. C @ 2. min, 4. K/min; Tend: 280. C
CapillaryCarbowax1192.3Censullo, Jones, et al., 200360. m/0.25 mm/0.5 μm, He, 50. C @ 10. min, 5. K/min, 250. C @ 10. min
CapillarySupelcowax-101177.Chung, 199960. m/0.25 mm/0.25 μm, He, 35. C @ 5. min, 2. K/min, 195. C @ 90. min
CapillaryDB-Wax1181.Shiratsuchi, Shimoda, et al., 199460. m/0.25 mm/0.25 μm, He, 2. K/min, 230. C @ 60. min; Tstart: 50. C
CapillaryDB-Wax1166.Peng, Hua, et al., 199230. m/0.53 mm/1. μm, 40. C @ 4. min, 8. K/min, 200. C @ 20. min

Normal alkane RI, non-polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
CapillaryMethyl Silicone120.932.Chen and Feng, 2006 
CapillaryOV-101100.918.Gerasimenko and Nabivach, 199550. m/0.30 mm/0.26 μm, Nitrogen
CapillaryOV-101100.919.Gerasimenko and Nabivach, 199550. m/0.30 mm/0.26 μm, Nitrogen
CapillaryOV-101100.920.Gerasimenko and Nabivach, 199550. m/0.30 mm/0.26 μm, Nitrogen
CapillaryOV-101100.920.Gerasimenko and Nabivach, 199550. m/0.30 mm/0.26 μm, Nitrogen
CapillaryOV-101100.920.Gerasimenko and Nabivach, 199550. m/0.30 mm/0.26 μm, Nitrogen
CapillaryOV-101100.920.Tian, 1993Column length: 50. m; Column diameter: 0.20 mm
CapillaryOV-101100.920.Tian, 1993Column length: 50. m; Column diameter: 0.20 mm
CapillaryOV-101120.925.Tian, 1993Column length: 50. m; Column diameter: 0.20 mm
CapillaryOV-101120.926.Tian, 1993Column length: 50. m; Column diameter: 0.20 mm
CapillaryOV-10132.903.Blazso, Ujszaszi, et al., 1980Column length: 20. m; Column diameter: 0.23 mm
CapillaryOV-10180.917.Blazso, Ujszaszi, et al., 1980Column length: 20. m; Column diameter: 0.23 mm
CapillarySqualane95.4903.Sojak and Vigdergauz, 1978H2
CapillarySqualane110.910.Papazova and Pankova, 1975N2; Column length: 100. m; Column diameter: 0.25 mm
PackedDC-400150.950.Anderson, 1968Helium, Gas-Pak (60-80 mesh); Column length: 3.0 m
PackedPolydimethyl siloxane110.925.Ferrand, 1962 

Normal alkane RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryPolydimethyl siloxane: CP-Sil 5 CB916.Bramston-Cook, 201360. m/0.25 mm/1.0 μm, Helium, 45. C @ 1.45 min, 3.6 K/min, 210. C @ 2.72 min
CapillaryHP-5 MS922.Kotowska, Zalikowski, et al., 201230. m/0.25 mm/0.25 μm, Helium, 35. C @ 5. min, 3. K/min, 300. C @ 15. min
CapillaryPetrocol DH912.Supelco, 2012100. m/0.25 mm/0.50 μm, Helium, 20. C @ 15. min, 15. K/min, 220. C @ 30. min
CapillaryVF-5 MS923.Leffingwell and Alford, 201160. m/0.32 mm/0.25 μm, Helium, 2. K/min, 260. C @ 28. min; Tstart: 30. C
CapillaryVF-5 MS926.Leffingwell and Alford, 201160. m/0.32 mm/0.25 μm, Helium, 2. K/min, 260. C @ 28. min; Tstart: 30. C
CapillaryPONA915.Zhang, Ding, et al., 200950. m/0.20 mm/0.50 μm, Nitrogen, 35. C @ 15. min, 2. K/min, 200. C @ 10. min
CapillarySPB-5929.Vasta, Ratel, et al., 200760. m/0.32 mm/1. μm, 40. C @ 5. min, 3. K/min, 230. C @ 5. min
CapillaryRSL-200932.Jirovetz, Buchbauer, et al., 200530. m/0.25 mm/0.25 μm, 40. C @ 2. min, 6. K/min, 280. C @ 10. min
CapillaryDB-1915.Palá-Paúl, Velasco-Negueruela, et al., 200450. m/0.25 mm/0.25 μm, N2, 4. K/min; Tstart: 95. C; Tend: 240. C
CapillaryDB-5923.Tellez, Khan, et al., 200430. m/0.25 mm/0.25 μm, He, 3. K/min; Tstart: 60. C; Tend: 240. C
CapillaryDB-5956.Bos, Koulman, et al., 200230. m/0.249 mm/0.25 μm, He, 3. K/min, 300. C @ 5. min; Tstart: 60. C
CapillaryDB-5MS954.Damon, Hernández, et al., 2002He, 50. C @ 2. min, 15. K/min, 280. C @ 10. min; Column length: 30. m; Column diameter: 0.25 mm
CapillaryHP-5925.Isidorov and Jdanova, 20023. K/min; Column length: 30. m; Column diameter: 0.25 mm; Tstart: 50. C; Tend: 200. C
CapillaryDB-5927.Kobaisy, Tellez, et al., 200230. m/0.25 mm/0.25 μm, He, 3. K/min; Tstart: 60. C; Tend: 240. C
CapillarySPB-5926.Pino, Marbot, et al., 200230. m/0.25 mm/0.25 μm, Helium, 60. C @ 2. min, 4. K/min, 250. C @ 20. min
CapillaryBP-1919.Health Safety Executive, 200050. m/0.22 mm/0.75 μm, He, 5. K/min; Tstart: 50. C; Tend: 200. C
CapillaryDB-1956.Koulman, 199925. m/0.25 mm/0.25 μm, He, 4. K/min; Tstart: 50. C; Tend: 290. C
CapillaryOV-1912.Orav, Kailas, et al., 19992. K/min; Tstart: 50. C; Tend: 160. C
CapillaryOV-101908.Orav, Kailas, et al., 1999, 250. m/0.20 mm/0.50 μm, Helium, 30. C @ 6. min, 1. K/min; Tend: 100. C
CapillaryHP-5930.7Wang and Fingas, 199530. m/0.25 mm/0.25 μm, He, 35. C @ 2. min, 10. K/min, 300. C @ 10. min
CapillarySP-2100926.Fischer and Kusch, 1993He, 40. C @ 3. min, 5. K/min; Column length: 30. m; Column diameter: 0.25 mm; Tend: 280. C
CapillaryDB-1916.Ciccioli, Cecinato, et al., 199260. m/0.32 mm/1.2 μm, He, 30. C @ 10. min, 3. K/min; Tend: 240. C
CapillaryCP Sil 5 CB906.Hartgers, Damste, et al., 199225. m/0.32 mm/0.45 μm, He, 0. C @ 5. min, 3. K/min, 320. C @ 10. min
CapillaryOV-101938.Zenkevich and Ventura, 1991Helium, 50. C @ 0. min, 5. K/min, 240. C @ 0. min; Column length: 54. m; Column diameter: 0.26 mm
CapillaryDB-1961.Habu, Flath, et al., 19853. K/min; Column length: 50. m; Column diameter: 0.32 mm; Tstart: 0. C; Tend: 250. C
CapillarySE-30910.Heydanek and McGorrin, 1981He, 40. C @ 3. min, 3. K/min; Column length: 50. m; Column diameter: 0.5 mm; Tend: 170. C
PackedApiezon L915.Dahlmann, Köser, et al., 1979Chromosorb G-AW-DMCS, 10. K/min; Column length: 2. m; Tstart: 25. C
CapillarySF-96916.Donetzhuber, Johansson, et al., 1976Nitrogen, 3. K/min, 130. C @ 40. min; Column length: 111. m; Column diameter: 0.76 mm; Initial hold: 8. min

Normal alkane RI, non-polar column, custom temperature program

View large format table.

Column type Active phase I Reference Comment
CapillaryHP-5 MS914.Kotowska, Zalikowski, et al., 201230. m/0.25 mm/0.25 μm, Helium; Program: not specified
CapillaryPolydimethyl siloxane with 5 % Ph groups924.Robinson, Adams, et al., 2012Program: not specified
CapillaryPolydimethyl siloxane with 5 % Ph groups927.Robinson, Adams, et al., 2012Program: not specified
CapillaryDB-5 MS931.Cajka, Hajslova, et al., 200730. m/0.25 mm/0.25 μm, Helium; Program: 45 0C (0.75 min) 10 0C/min -> 200 0C 30 0C/min -> 245 0C (1.25 min)
CapillaryDB-5919.Pellicer, 200730. m/0.32 mm/0.25 μm, Helium; Program: not specified
CapillaryDB-5919.Pellicer, 200730. m/0.32 mm/0.25 μm, Helium; Program: not specified
CapillaryDB-5919.Pellicer, 200730. m/0.32 mm/0.25 μm, Helium; Program: not specified
CapillaryDB-5919.Pellicer, 200730. m/0.32 mm/0.25 μm, Helium; Program: not specified
CapillaryDB-5919.Pellicer, 200730. m/0.32 mm/0.25 μm, Helium; Program: not specified
CapillaryDB-5919.Pellicer, 200730. m/0.32 mm/0.25 μm, Helium; Program: not specified
CapillaryDB-5919.Pellicer, 200730. m/0.32 mm/0.25 μm, Helium; Program: not specified
CapillaryDB-5919.Pellicer, 200730. m/0.32 mm/0.25 μm, Helium; Program: not specified
CapillaryDB-5920.Pellicer, 200730. m/0.32 mm/0.25 μm, Helium; Program: not specified
CapillaryDB-5922.Pellicer, 200730. m/0.32 mm/0.25 μm, Helium; Program: not specified
CapillaryDB-5922.Pellicer, 200730. m/0.32 mm/0.25 μm, Helium; Program: not specified
CapillaryDB-5923.Pellicer, 200730. m/0.32 mm/0.25 μm, Helium; Program: not specified
CapillaryMethyl Silicone920.Blunden, Aneja, et al., 200560. m/0.32 mm/1.0 μm, Helium; Program: -50 0C (2 min) 8 0C/min -> 200 0C (7.75 min) 25 0C -> 225 0C (8 min)
CapillaryOV-101920.Zhu and Wang, 2001Program: not specified
CapillaryDB-1909.Zhu and Wang, 2001Program: not specified
CapillaryMethyl Silicone914.Zenkevich, 1999Program: not specified
CapillarySPB-1925.Flanagan, Streete, et al., 199760. m/0.53 mm/5. μm, He; Program: 40C(6min) => 5C/min => 80C => 10C/min => 200C
CapillaryMethyl Silicone914.Zenkevich and Tsibulskaya, 1997Program: not specified
CapillaryDB-1923.Peng, 199630. m/0.53 mm/1.5 μm; Program: 40 0C (4 min) 8 0C/min -> 200 0C (1 min) 5 0C/min -> 280 0C (20 min)
CapillarySE-30911.Xiuhua, Zhang, et al., 1996Program: not specified
CapillarySE-30920.Xiuhua, Zhang, et al., 1996Program: not specified
CapillaryDB-5919.Sorimachi, Tanabe, et al., 1995He; Column length: 30. m; Program: not specified
CapillaryMethyl Silicone914.Zenkevich, 1995Program: not specified
CapillaryDB-1908.Ciccioli, Cecinato, et al., 199460. m/0.32 mm/0.25 μm; Program: not specified
CapillaryOV-101919.Dimov, Osman, et al., 1994Program: not specified
CapillaryDB-1908.Ciccioli, Brancaleoni, et al., 199360. m/0.32 mm/0.25 μm; Program: 3 min at 5 C; 5 - 50 C at 3 deg/min; 50 - 220 C at 5 deg/min
CapillaryDB-1912.Hathcock and Bertsch, 1993100. m/0.25 mm/0.5 μm; Program: not specified
CapillarySPB-1925.Strete, Ruprah, et al., 199260. m/0.53 mm/5.0 μm, Helium; Program: 40 0C (6 min) 5 0C/min -> 80 0C 10 0C/min -> 200 0C
CapillarySPB-1905.Strete, Ruprah, et al., 199260. m/0.53 mm/5.0 μm, Helium; Program: not specified
CapillarySqualane907.5Dimov and Mekenyan, 1989Program: not specified
CapillarySE-52933.van Langenhove and Schamp, 1986Column length: 100. m; Column diameter: 0.50 mm; Program: not specified
CapillaryOV-1, SE-30, Methyl silicone, SP-2100, OV-101, DB-1, etc.906.Waggott and Davies, 1984Hydrogen; Column length: 50. m; Column diameter: 0.32 mm; Program: not specified
CapillaryOV-1, SE-30, Methyl silicone, SP-2100, OV-101, DB-1, etc.913.Waggott and Davies, 1984Hydrogen; Column length: 50. m; Column diameter: 0.32 mm; Program: not specified
CapillaryOV-1, SE-30, Methyl silicone, SP-2100, OV-101, DB-1, etc.915.Waggott and Davies, 1984Hydrogen; Column length: 50. m; Column diameter: 0.32 mm; Program: not specified
CapillaryOV-1, SE-30, Methyl silicone, SP-2100, OV-101, DB-1, etc.921.Waggott and Davies, 1984Hydrogen; Column length: 50. m; Column diameter: 0.32 mm; Program: not specified
CapillaryOV-1905.Ramsey and Flanagan, 1982Program: not specified
CapillaryMethyl Silicone919.Bonchev, Mekenjan, et al., 1979Program: not specified
PackedSE-30929.Robinson and Odell, 1971N2, Chromosorb W; Column length: 6.1 m; Program: 50C910min) => 20C/min => 90(6min) => 10C/min => 150C(hold)
PackedSqualane904.Robinson and Odell, 1971N2, Embacel; Column length: 3.0 m; Program: 25C(5min) => 2C/min => 35 => 4C/min => 95C(hold)
PackedSE-30929.Robinson and Odell, 1971, 2Chrom W; Column length: 6.1 m; Program: 50C(10min) => 20C/min(2min) => 90C(6min) => 10C/min(6min) => (hold at 150C)

Normal alkane RI, polar column, isothermal

View large format table.

Column type Active phase Temperature (C) I Reference Comment
CapillaryPEG-40M100.1186.Nesterov, Nesterova, et al., 2000Column length: 50. m
CapillaryPEG-40M100.1189.Nesterov, Nesterova, et al., 2000Column length: 50. m
CapillaryPEG-40M120.1200.Nesterov, Nesterova, et al., 2000Column length: 50. m
CapillaryPEG-40M140.1211.Nesterov, Nesterova, et al., 2000Column length: 50. m
CapillaryPEG-40M160.1225.Nesterov, Nesterova, et al., 2000Column length: 50. m
CapillaryPEG-40M60.1169.Nesterov, Nesterova, et al., 2000Column length: 50. m
CapillaryPEG-40M80.1179.Nesterov, Nesterova, et al., 2000Column length: 50. m
CapillaryCarbowax 20M90.1155.Sutter, Peterson, et al., 1997 

Normal alkane RI, polar column, temperature ramp

View large format table.

Column type Active phase I Reference Comment
CapillaryHP-Innowax1168.Feng, Zhuang, et al., 201160. m/0.25 mm/0.25 μm, Helium, 60. C @ 1. min, 3. K/min, 220. C @ 5. min
CapillaryBP-201185.Rawat, Gulati, et al., 200730. m/0.25 mm/0.25 μm, He, 70. C @ 4. min, 4. K/min, 220. C @ 5. min
CapillaryDB-Wax1168.Tanaka, Yamauchi, et al., 200330. m/0.25 mm/0.25 μm, 30. C @ 1. min, 4. K/min; Tend: 250. C
CapillaryDB-Wax1172.Tanaka, Yamauchi, et al., 200330. m/0.25 mm/0.25 μm, 30. C @ 1. min, 4. K/min; Tend: 250. C
CapillaryCarbowax 20M1150.Herain, MRAVEC, et al., 199170. C @ 21. min, 5. K/min, 150. C @ 999. min

Normal alkane RI, polar column, custom temperature program

View large format table.

Column type Active phase I Reference Comment
CapillaryHP-Innowax1171.Feng, Zhuang, et al., 201160. m/0.25 mm/0.25 μm, Helium; Program: not specified
CapillaryInnowax FSC1183.Baser K.H.C., Ozek G., et al., 200660. m/0.25 mm/0.25 μm, He; Program: 60C(10min) => 4C/min => 220C (10min) => 1C/min => 240C
CapillaryCarbowax 20M1155.Ivanciuc, Ivanciuc, et al., 2001Program: not specified
CapillaryDB-Wax1182.Peng, 199630. m/0.53 mm/1.0 μm; Program: 40 0C (4 min) 4 0C/min -> 200 0C (20 min)
CapillaryPEG-20M1177.Xiuhua, Zhang, et al., 1996Program: not specified
CapillaryDB-Wax1182.Peng, Yang, et al., 1991Program: not specified
CapillaryCarbowax 20M1164.Dimov and Mekenyan, 1989Program: not specified
CapillaryCarbowax 400, Carbowax 20M, Carbowax 1540, Carbowax 4000, Superox 06, PEG 20M, etc.1161.Waggott and Davies, 1984Hydrogen; Column length: 50. m; Column diameter: 0.32 mm; Program: not specified
CapillaryCarbowax 20M1162.Ramsey and Flanagan, 1982Program: not specified

Lee's RI, non-polar column, temperature ramp

View large format table.

Column type Active phase I Reference Comment
CapillaryHP-5134.Shao, Wang, et al., 200630. m/0.3 mm/0.25 μm, He, 50. C @ 5. min, 5. K/min, 200. C @ 15. min

References

Go To: Top, Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

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Notes

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