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Benzenamine, 3-(trifluoromethyl)-


Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafliquid-163.96kcal/molCcbSwarts, 1909 
Quantity Value Units Method Reference Comment
Deltacliquid-830.95kcal/molCcbSwarts, 1919Not corrected for CODATA value of «DELTA»fH
Deltacliquid-825.8kcal/molCcbSwarts, 1909 

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C7H5F3N- + Hydrogen cation = Benzenamine, 3-(trifluoromethyl)-

By formula: C7H5F3N- + H+ = C7H6F3N

Quantity Value Units Method Reference Comment
Deltar356.9 ± 2.1kcal/molG+TSBartmess, Scott, et al., 1979gas phase; value altered from reference due to change in acidity scale; B
Quantity Value Units Method Reference Comment
Deltar349.6 ± 2.0kcal/molIMREBartmess, Scott, et al., 1979gas phase; value altered from reference due to change in acidity scale; B

N,N'-Di-(m-trifluoromethylphenyl)urea = Benzene, 1-isocyanato-3-(trifluoromethyl)- + Benzenamine, 3-(trifluoromethyl)-

By formula: C15H10F6N2O = C8H4F3NO + C7H6F3N

Quantity Value Units Method Reference Comment
Deltar46.7 ± 1.5kcal/molEqkChimishkyan, Svetlova, et al., 1984solid phase; Dissociation; ALS

References

Go To: Top, Condensed phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Swarts, 1909
Swarts, M.F., Sur la chaleur de formation de quelquesuns compounds organiques fluords, Recl. Trav. Chim. Pays-Bas, 1909, 28, 143-154. [all data]

Swarts, 1919
Swarts, F., Etudes thermochimiques sur les combinaisons organiques fluorees, J. Chim. Phys., 1919, 17, 3-70. [all data]

Bartmess, Scott, et al., 1979
Bartmess, J.E.; Scott, J.A.; McIver, R.T., Jr., The gas phase acidity scale from methanol to phenol, J. Am. Chem. Soc., 1979, 101, 6047. [all data]

Chimishkyan, Svetlova, et al., 1984
Chimishkyan, A.L.; Svetlova, L.P.; Leonova, T.V.; Gluyaev, N.D., Thermal decomposition of substituted ureas, J. Gen. Chem. USSR, 1984, 54, 1317-1320. [all data]


Notes

Go To: Top, Condensed phase thermochemistry data, Reaction thermochemistry data, References