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Furfural

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
GT - Glushko Thermocenter, Russian Academy of Sciences, Moscow

Quantity Value Units Method Reference Comment
Deltafgas-149.6kJ/molN/AAvramescu and Isagescu, 1978Value computed using «DELTA»fHliquid° value of -200.2 kj/mol from Avramescu and Isagescu, 1978 and «DELTA»vapH° value of 50.63±0.42 kj/mol from missing citation.; DRB
Deltafgas-151.04kJ/molCmKudchadker and Kudchadker, 1975ALS
Deltafgas-144.3kJ/molN/AMiller, 1936Value computed using «DELTA»fHliquid° value of -194.9 kj/mol from Miller, 1936 and «DELTA»vapH° value of 50.63±0.42 kj/mol from missing citation.; DRB
Deltafgas-151.4kJ/molN/ALandrieu, Baylocq, et al., 1929Value computed using «DELTA»fHliquid° value of -202 kj/mol from Landrieu, Baylocq, et al., 1929 and «DELTA»vapH° value of 50.63±0.42 kj/mol from missing citation.; DRB

Constant pressure heat capacity of gas

Cp,gas (J/mol*K) Temperature (K) Reference Comment
46.95100.Kudchadker S.A., 1975GT
56.92150.
69.35200.
90.68273.15
98.09298.15
98.63300.
125.94400.
148.11500.
165.50600.
179.15700.
190.02800.
198.79900.
205.971000.
211.911100.
216.871200.
221.041300.
224.581400.
227.601500.

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-200.2kJ/molCcbAvramescu and Isagescu, 1978ALS
Deltafliquid-194.9kJ/molCcbMiller, 1936%hf calculated possible error by author; ALS
Deltafliquid-202.kJ/molCcbLandrieu, Baylocq, et al., 1929ALS
Quantity Value Units Method Reference Comment
Deltacliquid-2339.0 ± 0.08kJ/molCcbAvramescu and Isagescu, 1978Corresponding «DELTA»fliquid = -200.2 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-2344.kJ/molCcbMiller, 1936%hf calculated possible error by author; Corresponding «DELTA»fliquid = -195. kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-2338.kJ/molCcbLandrieu, Baylocq, et al., 1929Corresponding «DELTA»fliquid = -202. kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
liquid218.0J/mol*KN/AMiller, 1935Extrapolation below 90 K, 52.38 J/mol*K.; DH

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
159.5293.Rastorguev and Ganiev, 1967T = 293 to 373 K.; DH
162.8298.15Omel'chenko, 1962T = 288 to 412 K.; DH
158.2298.von Reis, 1881T = 290 to 347 K.; DH

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Avramescu and Isagescu, 1978
Avramescu, F.; Isagescu, D.A., Heats of combustion of mono- and difurfurylidene acetone, Rev. Roum. Chim., 1978, 23, 655-659. [all data]

Kudchadker and Kudchadker, 1975
Kudchadker, S.A.; Kudchadker, A.P., Thermodynamic properties of oxygen compounds. III. Benzaldehyde and furfural (2-furaldehyde), Ber. Bunsenges. Phys. Chem., 1975, 12, 432-437. [all data]

Miller, 1936
Miller, P., The free energy of furfural and some of its derivatives, Iowa State Coll. J. Sci., 1936, 10, 91-93. [all data]

Landrieu, Baylocq, et al., 1929
Landrieu, P.; Baylocq, F.; Johnson, J.R., Etude thermochimique dans la serie furanique, Bull. Soc. Chim. France, 1929, 45, 36-49. [all data]

Kudchadker S.A., 1975
Kudchadker S.A., Thermodynamic properties of oxygen compounds. III. Benzaldehyde and furfural (2-furaldehyde), Thermochim. Acta, 1975, 12, 432-437. [all data]

Miller, 1935
Miller, P., The free energy of furfural and some of its derivatives, Iowa State Coll. J. Sci., 1935, 10, 91-93. [all data]

Rastorguev and Ganiev, 1967
Rastorguev, Yu.L.; Ganiev, Yu.A., Study of the heat capacity of selected solvents, Izv. Vyssh. Uchebn. Zaved. Neft Gaz. 10, 1967, No.1, 79-82. [all data]

Omel'chenko, 1962
Omel'chenko, F.S., Specific heat of furfural, Izv. Vyssh. Ucheb. Zaved. Pishch. Tekhnol., 1962, No. 2, 151-152. [all data]

von Reis, 1881
von Reis, M.A., Die specifische Wärme flüssiger organischer Verbindungen und ihre Beziehung zu deren Moleculargewicht, Ann. Physik [3], 1881, 13, 447-464. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, References