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Aluminum, triethyl-

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C12H30Al2 (g) = 2Aluminum, triethyl- (g)

By formula: C12H30Al2 (g) = 2C6H15Al (g)

Quantity Value Units Method Reference Comment
Deltar18.2 ± 0.31kcal/molN/ASmith, 1972The values were derived from the thermochemistry of the equilibrium in the liquid phase and from vapor pressure data Smith, 1972.

3Water (g) + Aluminum, triethyl- (l) = AlH3O3 (amorphous) + 3Ethane (g)

By formula: 3H2O (g) + C6H15Al (l) = AlH3O3 (amorphous) + 3C2H6 (g)

Quantity Value Units Method Reference Comment
Deltar-154.7 ± 1.5kcal/molRSCFowell, 1961Please also see Cox and Pilcher, 1970. Liquid triethylaluminum contains a very small molar fraction of monomer at 298 K, ca. 0.1% Smith, 1967, so that the "real" liquid should be described as [Al(Et)3]2.

C12H30Al2 (l) = 2Aluminum, triethyl- (l)

By formula: C12H30Al2 (l) = 2C6H15Al (l)

Quantity Value Units Method Reference Comment
Deltar16.9 ± 0.24kcal/molEqSSmith, 1967 

AlI3 (cr) + 2Aluminum, triethyl- (l) = 3C4H10AlI (l)

By formula: AlI3 (cr) + 2C6H15Al (l) = 3C4H10AlI (l)

Quantity Value Units Method Reference Comment
Deltar-17.5 ± 0.33kcal/molRSCSmith, 1974Please also see Pedley and Rylance, 1977.

AlBr3 (cr) + 2Aluminum, triethyl- (l) = 3C4H10AlBr (l)

By formula: AlBr3 (cr) + 2C6H15Al (l) = 3C4H10AlBr (l)

Quantity Value Units Method Reference Comment
Deltar-21.8 ± 0.43kcal/molRSCSmith, 1974Please also see Pedley and Rylance, 1977.

AlCl3 (cr) + 2Aluminum, triethyl- (l) = 3Aluminum, chlorodiethyl- (l)

By formula: AlCl3 (cr) + 2C6H15Al (l) = 3C4H10AlCl (l)

Quantity Value Units Method Reference Comment
Deltar-16.0 ± 0.31kcal/molRSCSmith, 1974Please also see Pedley and Rylance, 1977.

C2H5AlI2 (l) + Aluminum, triethyl- (l) = 2C4H10AlI (l)

By formula: C2H5AlI2 (l) + C6H15Al (l) = 2C4H10AlI (l)

Quantity Value Units Method Reference Comment
Deltar-8.7 ± 0.2kcal/molRSCSmith, 1974Please also see Pedley and Rylance, 1977.

C2H5AlBr2 (l) + Aluminum, triethyl- (l) = 2C4H10AlBr (l)

By formula: C2H5AlBr2 (l) + C6H15Al (l) = 2C4H10AlBr (l)

Quantity Value Units Method Reference Comment
Deltar-9.5 ± 0.2kcal/molRSCSmith, 1974Please also see Pedley and Rylance, 1977.

Aluminum, dichloroethyl- (l) + Aluminum, triethyl- (l) = 2Aluminum, chlorodiethyl- (l)

By formula: C2H5AlCl2 (l) + C6H15Al (l) = 2C4H10AlCl (l)

Quantity Value Units Method Reference Comment
Deltar-9.4 ± 0.2kcal/molRSCSmith, 1974Please also see Pedley and Rylance, 1977.

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Smith, 1972
Smith, M.B., J. Organometal. Chem., 1972, 46, 31. [all data]

Fowell, 1961
Fowell, P.A., Ph. D. Thesis, University of Manchester, 1961. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Smith, 1967
Smith, M.B., J. Phys. Chem., 1967, 71, 364. [all data]

Smith, 1974
Smith, M.B., J. Organometal. Chem., 1974, 76, 171. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]


Notes

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