Eugenol
- Formula: C10H12O2
- Molecular weight: 164.2011
- IUPAC Standard InChIKey: RRAFCDWBNXTKKO-UHFFFAOYSA-N
- CAS Registry Number: 97-53-0
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Phenol, 2-methoxy-4-(2-propenyl)-; Phenol, 4-allyl-2-methoxy-; p-Allylguaiacol; p-Eugenol; Caryophyllic acid; Engenol; Eugenic acid; 2-Methoxy-1-hydroxy-4-allylbenzene; 2-Methoxy-4-allylphenol; 4-Allyl-2-methoxyphenol; 4-Allylguaiacol; 4-Hydroxy-3-methoxyallylbenzene; NCI-C50453; 1-Hydroxy-2-methoxy-4-allylbenzene; 1-Hydroxy-2-methoxy-4-prop-2-enylbenzene; 2-Methoxy-4-(2-propenyl)phenol; 2-Methoxy-4-prop-2-enylphenol; 4-Allyl-1-hydroxy-2-methoxybenzene; 4-Allylcatechol-2-methyl ether; 1,3,4-Eugenol; FA 100; FEMA No. 2467; 2-Metoksy-4-allilofenol; 2-Hydroxy-5-allylanisole; Allylguaiacol; 4-(2-Propenyl)-2-methoxyphenol; NSC 209525; Phenol, 2-methoxy-4-(2-propen-1-yl)-; 4-allyl-2-methoxyphenol (eugenol); 4-(2-Propenyl)-2-methoxyphenol (eugenol); 4-Allyl-2-rnethoxyphenol (eugenol); Eugenol (2-Methoxy-4-(2-propenyl)phenol)
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Van Den Dool and Kratz RI, polar column, temperature ramp
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | DB-Wax | Innowax | BP-20 | HP-Innowax | HP-20M |
Column length (m) | 30. | 30. | 50. | 30. | 50. |
Carrier gas | He | H2 | He | He | He |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.22 | 0.25 | 0.2 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.2 |
Tstart (C) | 50. | 45. | 60. | 60. | 70. |
Tend (C) | 180. | 210. | 220. | 280. | 180. |
Heat rate (K/min) | 3.5 | 3.5 | 2. | 3. | 4. |
Initial hold (min) | 2. | 5. | 4. | ||
Final hold (min) | 25. | 20. | 20. | 15. | |
I | 2167. | 2186. | 2172. | 2156. | 2116. |
Reference | Botelho, Caldeira, et al., 2007 | Botelho, Caldeira, et al., 2007 | Boti, Koukoua, et al., 2007 | Kundakovic, Fokialakis, et al., 2007 | Politeo, Jukic, et al., 2007 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | DB-Wax | DB-Wax Etr | BP-20 | Innowax | DB-FFAP |
Column length (m) | 30. | 30. | 50. | 60. | 30. |
Carrier gas | He | He | He | He | He |
Substrate | |||||
Column diameter (mm) | 0.32 | 0.25 | 0.22 | 0.25 | 0.32 |
Phase thickness (μm) | 0.5 | 0.25 | 0.25 | 0.25 | 0.25 |
Tstart (C) | 40. | 40. | 60. | 40. | 40. |
Tend (C) | 240. | 250. | 220. | 230. | 230. |
Heat rate (K/min) | 7. | 5. | 2. | 4. | 6. |
Initial hold (min) | 3. | 4. | 1. | ||
Final hold (min) | 5. | 15. | 20. | 20. | |
I | 2182. | 2170. | 2177. | 2164. | 2179. |
Reference | Ruiz Perez-Cacho, Mahattanatawee, et al., 2007 | Aubert C. and Pitrat M., 2006 | Duquesnoy, Dinh, et al., 2006 | Lee, Lee, et al., 2006 | Zeller and Rychlik, 2006 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | DB-Wax | Supelcowax-10 | ZB-Wax | DB-Wax | DB-Wax |
Column length (m) | 60. | 30. | 30. | 30. | 30. |
Carrier gas | N2 | He | He | He | He |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.25 | 0.25 | 0.25 |
Phase thickness (μm) | 0.25 | 0.25 | 0.15 | 0.25 | 0.25 |
Tstart (C) | 70. | 60. | 35. | 40. | 40. |
Tend (C) | 230. | 240. | 220. | 240. | 240. |
Heat rate (K/min) | 2. | 3. | 1.8 | 6. | 6. |
Initial hold (min) | 2. | 5. | 10. | 10. | 10. |
Final hold (min) | 20. | 10. | 10. | 25. | 25. |
I | 2172. | 2164. | 2171. | 2146. | 2153. |
Reference | Choi, 2005 | Riu-Aumatell, Lopez-Tamames, et al., 2005 | Ledauphin, Saint-Clair, et al., 2004 | Varming, Andersen, et al., 2004 | Varming, Petersen, et al., 2004 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | DB-Wax | DB-Wax | HP-Wax | Carbowax 20M | DB-Wax |
Column length (m) | 30. | 30. | 30. | 25. | 60. |
Carrier gas | N2 | He | N2 | ||
Substrate | |||||
Column diameter (mm) | 0.32 | 0.32 | 0.25 | 0.25 | 0.25 |
Phase thickness (μm) | 0.5 | 0.5 | 0.25 | 0.3 | 0.25 |
Tstart (C) | 40. | 40. | 60. | 50. | 70. |
Tend (C) | 245. | 245. | 220. | 200. | 230. |
Heat rate (K/min) | 3. | 2. | 5. | 3. | 2. |
Initial hold (min) | 3. | 3. | 10. | 1. | 2. |
Final hold (min) | 20. | 20. | 20. | 20. | |
I | 2164. | 2164. | 2165. | 2163. | 2175. |
Reference | Aubert, Ambid, et al., 2003 | Aubert, Günata, et al., 2003 | Bader, Caponi, et al., 2003 | Bicchi, Rubiolo, et al., 2003 | Choi, 2003 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | CP-Wax 52CB | DB-Wax | DB-Wax | RTX-Wax | Supelcowax-10 |
Column length (m) | 50. | 30. | 60. | 30. | 30. |
Carrier gas | He | N2 | He | He | |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.32 | 0.25 | 0.25 | 0.25 |
Phase thickness (μm) | 0.2 | 0.5 | 0.25 | 0.25 | 0.25 |
Tstart (C) | 32. | 40. | 70. | 45. | 50. |
Tend (C) | 220. | 240. | 230. | 250. | 230. |
Heat rate (K/min) | 1. | 7. | 2. | 3. | 3. |
Initial hold (min) | 1. | 6. | |||
Final hold (min) | 5. | 20. | 10. | 30. | |
I | 2151. | 2141. | 2166. | 2135. | 2173. |
Reference | Kjeldsen, Christensen, et al., 2003 | Valim, Rouseff, et al., 2003 | Choi, Kim. M.-S.L., et al., 2002 | Mondello, Zappia, et al., 2002 | Moreira, Trugo, et al., 2002 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | DB-Wax | DB-Wax | DB-Wax | DB-Wax | DB-Wax |
Column length (m) | 30. | 30. | 60. | 30. | 60. |
Carrier gas | He | He | He | He | N2 |
Substrate | |||||
Column diameter (mm) | 0.32 | 0.32 | 0.53 | 0.32 | 0.25 |
Phase thickness (μm) | 0.50 | 0.5 | 1.0 | 0.5 | 0.25 |
Tstart (C) | 40. | 60. | 50. | 60. | 70. |
Tend (C) | 240. | 245. | 220. | 245. | 230. |
Heat rate (K/min) | 7. | 3. | 3. | 3. | 2. |
Initial hold (min) | 3. | 3. | 2. | ||
Final hold (min) | 5. | 20. | 20. | 20. | |
I | 2184. | 2154. | 2166. | 2154. | 2172. |
Reference | Lin and Rouseff, 2001 | Wirth, Guo, et al., 2001 | Brophy, Goldsack, et al., 2000 | Bureau, Baumes, et al., 2000 | Choi and Sawamura, 2000 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | Supelcowax-10 | DB-Wax | Supelcowax-10 | DB-Wax | CP-Wax 52CB |
Column length (m) | 60. | 30. | 30. | 30. | 50. |
Carrier gas | He | He | He | H2 | |
Substrate | |||||
Column diameter (mm) | 0.25 | 0.25 | 0.32 | 0.25 | 0.32 |
Phase thickness (μm) | 0.25 | 0.25 | 0.25 | 0.25 | |
Tstart (C) | 35. | 40. | 75. | 60. | 60. |
Tend (C) | 195. | 200. | 200. | 220. | 220. |
Heat rate (K/min) | 2. | 2. | 2.5 | 2. | 4. |
Initial hold (min) | 5. | 3. | 5. | ||
Final hold (min) | 90. | 20. | 30. | ||
I | 2176. | 2153. | 2180. | 2145. | 2155. |
Reference | Chung, 2000 | Kim, Thuy, et al., 2000 | Lazari, Skaltsa, et al., 2000 | Chassagne, Boulanger, et al., 1999 | Chevance and Farmer, 1999 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | CP-Wax 52CB | CP-Wax 52CB | HP-Innowax | Carbowax 20M | DB-Wax |
Column length (m) | 50. | 50. | 60. | 25. | 30. |
Carrier gas | He | H2 | |||
Substrate | |||||
Column diameter (mm) | 0.32 | 0.32 | 0.25 | 0.25 | 0.32 |
Phase thickness (μm) | 0.3 | 0.5 | |||
Tstart (C) | 60. | 40. | 32. | 50. | 40. |
Tend (C) | 220. | 220. | 220. | 200. | 245. |
Heat rate (K/min) | 4. | 4. | 2. | 3. | 3. |
Initial hold (min) | 5. | 5. | 1. | 1. | 3. |
Final hold (min) | 30. | 30. | 40. | 20. | 20. |
I | 2162. | 2155. | 2184. | 2169. | 2117. |
Reference | Chevance and Farmer, 1999, 2 | Chevance and Farmer, 1999, 2 | Christensen, Jakobsen, et al., 1999 | Bicchi, Rubiolo, et al., 1998 | Ollé, Baumes, et al., 1998 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | HP-Wax | DB-FFAP | DB-FFAP | BP-20 | DB-Wax |
Column length (m) | 50. | 30. | 30. | 50. | 25. |
Carrier gas | He | H2 | H2 | He | He |
Substrate | |||||
Column diameter (mm) | 0.2 | 0.32 | 0.32 | 0.22 | 0.25 |
Phase thickness (μm) | 0.4 | 0.25 | 0.25 | ||
Tstart (C) | 30. | 40. | 40. | 60. | 50. |
Tend (C) | 220. | 220. | 220. | 230. | 240. |
Heat rate (K/min) | 5. | 3. | 3. | 2. | 4. |
Initial hold (min) | 1. | 3. | |||
Final hold (min) | 30. | 35. | |||
I | 2210. | 2185. | 2186. | 2165. | 2139. |
Reference | Christensen, Jakobsen, et al., 1997 | Guillard, le Quere, et al., 1997 | Guillard, le Quere, et al., 1997 | Mariotti, Costa, et al., 1997 | Möllenbeck, König, et al., 1997 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | DB-Wax | DB-Wax | HP-20M | DB-Wax | CP-Wax 58CB |
Column length (m) | 30. | 30. | 50. | 30. | 30. |
Carrier gas | He | He | He | He | He |
Substrate | |||||
Column diameter (mm) | 0.32 | 0.32 | 0.25 | 0.25 | 0.25 |
Phase thickness (μm) | 0.5 | 0.5 | 0.25 | 0.22 | |
Tstart (C) | 50. | 50. | 60. | 50. | 40. |
Tend (C) | 230. | 230. | 190. | 220. | 220. |
Heat rate (K/min) | 2. | 2. | 3. | 4. | 3. |
Initial hold (min) | 3. | ||||
Final hold (min) | 20. | ||||
I | 2177. | 2176. | 2122. | 2130. | 2131. |
Reference | Coen, Engel, et al., 1995 | Coen, Engel, et al., 1995 | Chung, Eiserich, et al., 1993 | Humpf and Schreier, 1991 | Pabst, Barron, et al., 1991 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary |
---|---|---|---|
Active phase | DB-Wax | DB-Wax | Carbowax 20M |
Column length (m) | 30. | 30. | 50. |
Carrier gas | He | ||
Substrate | |||
Column diameter (mm) | 0.25 | 0.25 | 0.32 |
Phase thickness (μm) | |||
Tstart (C) | 50. | 50. | 50. |
Tend (C) | 240. | 240. | 200. |
Heat rate (K/min) | 2. | 2. | 2. |
Initial hold (min) | 5. | ||
Final hold (min) | 40. | ||
I | 2157.3 | 2159.4 | 2140. |
Reference | Chang, Sheng, et al., 1989 | Chang, Sheng, et al., 1989 | Chen, Kuo, et al., 1986 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI |
References
Go To: Top, Van Den Dool and Kratz RI, polar column, temperature ramp, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Botelho, Caldeira, et al., 2007
Botelho, G.; Caldeira, I.; Mendes-Faia, A.; Clímaco, M.C.,
Evaluation of two quantitative gas chromatography-olfactometry methods for clonal red wines differentiation,
Flavour Fragr. J., 2007, 22, 5, 414-420, https://doi.org/10.1002/ffj.1815
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Boti, Koukoua, et al., 2007
Boti, J.B.; Koukoua, G.; N'Guessan, T.Y.; Casanova, J.,
Chemical variability of Conyza sumatrensis and Microglossa pyrifolia from Côte d'Ivoire,
Flavour Fragr. J., 2007, 22, 1, 27-31, https://doi.org/10.1002/ffj.1743
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Kundakovic, Fokialakis, et al., 2007
Kundakovic, T.; Fokialakis, N.; Kovacevic, N.; Chinou, I.,
Essential oil composition of Achillea lingulata and A. umbellata,
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Politeo, Jukic, et al., 2007
Politeo, O.; Jukic, M.; Milos, M.,
Chemical composition and antioxidant capacity of free volatile aglycones from basil (Ocimum basilicum L.) compared with its essential oil,
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Ruiz Perez-Cacho, Mahattanatawee, et al., 2007
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Identification of Sulfur Volatiles in Canned Orange Juices Lacking Orange Flavor,
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Aubert C. and Pitrat M., 2006
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Volatile compounds in the skin and pulp of Queen Anne's pocket melon,
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Characteristic odor components of kumquat (Fortunella japonica Swingle) peel oil,
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Riu-Aumatell, Lopez-Tamames, et al., 2005
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Varming, Petersen, et al., 2004
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Aubert, Ambid, et al., 2003
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Composition of the essential oil of Ballota undulata, B. nigra ssp. foetida and B. saxatilis,
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Choi, 2003
Choi, H.-S.,
Character impact odorants of Citrus Hallabong [(C. unshiu Marcov × C. sinensis Osbeck) × C. reticulata Blanco] cold-pressed peel oil,
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Kjeldsen, Christensen, et al., 2003
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Valim, Rouseff, et al., 2003
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Gas chromatographic-olfactometric characterization of aroma compounds in two types of cashew apple nectar,
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Choi, Kim. M.-S.L., et al., 2002
Choi, H.-S.; Kim. M.-S.L.; Sawamura, M.,
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Mondello, Zappia, et al., 2002
Mondello, L.; Zappia, G.; Cotroneo, A.; Bonaccorsi, I.; Chowdhury, J.U.; Yusuf, M.; Dugo, G.,
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Moreira, Trugo, et al., 2002
Moreira, R.F.A.; Trugo, L.C.; Pietroluongo, M.; de Maria, C.A.B.,
Flavor composition of cashew (Anacardium occidentale) and marmeleiro (Croton species) honeys,
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Lin and Rouseff, 2001
Lin, J.; Rouseff, R.L.,
Characterization of aroma-impact compounds in cold-pressed grapefruit oil using time-intensity GC-olfactometry and GC-MS,
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Wirth, Guo, et al., 2001
Wirth, J.; Guo, W.; Baumes, R.; Günata, Z.,
Volatile compounds released by enzymatic hydrolysis of glycoconjugates of leaves and grape berries from Vitis vinifera muscat of Alexandria and Shiraz cultivars,
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Brophy, Goldsack, et al., 2000
Brophy, J.J.; Goldsack, R.J.; Punruckvong, A.; Bean, A.R.; Forster, P.I.; Lepschi, B.J.; Doran, J.C.; Rozefelds, A.C.,
Leaf essential oils of the genus Leptospermum (Myrtaceae) in eastern Australia. Part 7. Leptospermum petersonii, L. liversidgei and allies,
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Bureau, Baumes, et al., 2000
Bureau, S.M.; Baumes, R.L.; Razungles, A.J.,
Effects of vine or bunch shading on the glycosylated flavor precursors in grapes of Vitis vinifera L. Cv. Syrah,
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Choi and Sawamura, 2000
Choi, H.-S.; Sawamura, M.,
Composition of the essential oil of Citrus tamurana Hort. ex Tanaka (Hyuganatsu),
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Chung, 2000
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Notes
Go To: Top, Van Den Dool and Kratz RI, polar column, temperature ramp, References
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