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PH3+


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 21800 ± 120 U gas Maripuu, Reineck, et al., 1983

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1' 1 Sym. stretch 2461.6 ± 0.2 gas TPE Yang, Li, et al., 2006
a2 2 Umbrella 695.3 I gas PE TPE Maripuu, Reineck, et al., 1983
Yang, Li, et al., 2006
2 Umbrella 583.3 I gas TPE Yang, Li, et al., 2006
e 4 Deformation 1043.9 ± 0.2 gas TPE Yang, Li, et al., 2006

Additional references: Jacox, 1994, page 129

Notes

IComponent of an inversion doublet
UUpper bound
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Maripuu, Reineck, et al., 1983
Maripuu, R.; Reineck, I.; Agren, H.; Nian-Zu, W.; Rong, J.; Veenhuizen, H.; Al-Shamma, S.; Karlsson, L.; Siegbahn, K., The HeI excited electron spectrum of phosphine. An experimental and theoretical study, Mol. Phys., 1983, 48, 1255. [all data]

Yang, Li, et al., 2006
Yang, J.; Li, J.; Hao, Y.; Zhou, C.; Mo, Y., Inversion vibration of PH[sub 3][sup +](X [sup 2]A[sub 2][sup ´´]) studied by zero kinetic energy photoelectron spectroscopy, J. Chem. Phys., 2006, 125, 5, 054311, https://doi.org/10.1063/1.2229211 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]


Notes

Go To: Top, Vibrational and/or electronic energy levels, References