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Perfluoro(methylcyclohexane) anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Deltafgas-3000. ± 13.kJ/molR-EAGrimsrud, Chowdhury, et al., 1985«DELTA»Gea(423 K) = -26.1 kcal/mol; «DELTA»Sea = -2.7 eu.

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Perfluoro(methylcyclohexane) anion + Benzene, nitro- = (Perfluoro(methylcyclohexane) anion bullet Benzene, nitro-)

By formula: C7F14- + C6H5NO2 = (C7F14- bullet C6H5NO2)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
28.300.PHPMSChowdhury and Kebarle, 1986gas phase; M

Perfluoro(methylcyclohexane) anion + Methyl Alcohol = (Perfluoro(methylcyclohexane) anion bullet Methyl Alcohol)

By formula: C7F14- + CH4O = (C7F14- bullet CH4O)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
27.308.PHPMSKnighton, Zook, et al., 1990gas phase; M

Perfluoro(methylcyclohexane) anion + Dimethyl Sulfoxide = (Perfluoro(methylcyclohexane) anion bullet Dimethyl Sulfoxide)

By formula: C7F14- + C2H6OS = (C7F14- bullet C2H6OS)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
32.308.PHPMSKnighton, Zook, et al., 1990gas phase; M

Perfluoro(methylcyclohexane) anion + Benzene, nitro- = C13H5F14NO2-

By formula: C7F14- + C6H5NO2 = C13H5F14NO2-

Quantity Value Units Method Reference Comment
Deltar28. ± 4.2kJ/molIMREChowdhury and Kebarle, 1986gas phase; B

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Grimsrud, Chowdhury, et al., 1985
Grimsrud, E.P.; Chowdhury, S.; Kebarle, P., Electron affinity of SF6 and perfluoromethylcyclohexane. The unusual kinetics of electron transfer reactions A- + B- + A, where A = SF6 or perfluorinated cycloalkanes, J. Chem. Phys., 1985, 83, 1059. [all data]

Chowdhury and Kebarle, 1986
Chowdhury, S.; Kebarle, P., Role of Binding Energies in A-.B and A.B- Complexes in the Kinetics of Gas Phase Electron Transfer Reactions:A- + B = A + B- Involving Perfluoro Compounds: SF6, C6F11CF3, J. Chem. Phys., 1986, 85, 9, 4989, https://doi.org/10.1063/1.451687 . [all data]

Knighton, Zook, et al., 1990
Knighton, W.B.; Zook, D.R.; Grimsrud, E.P., Cluster-Assisted Decomposition Reactions of the Molecular Anions of SF6 and C7F14, J. Am. Soc. Mass Spectrom., 1990, 1, 5, 372, https://doi.org/10.1016/1044-0305(90)85017-G . [all data]


Notes

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