Perfluoro(methylcyclohexane) anion
- Formula: C7F14-
- Molecular weight: 350.0531
- IUPAC Standard InChI: InChI=1S/C7F13/c8-1-2(9,7(18,19)20)4(12,13)6(16,17)5(14,15)3(1,10)11/q-1
- IUPAC Standard InChIKey: YDPCVPKIVXXFRR-UHFFFAOYSA-N
- CAS Registry Number: 96759-86-3
- Chemical structure:
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Ion clustering data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess
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Clustering reactions
+
= (
•
)
By formula: C7F14- + CH4O = (C7F14- • CH4O)
Free energy of reaction
| ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 6.4 | 308. | PHPMS | Knighton, Zook, et al., 1990 | gas phase; M |
+
= (
•
)
By formula: C7F14- + C2H6OS = (C7F14- • C2H6OS)
Free energy of reaction
| ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 7.7 | 308. | PHPMS | Knighton, Zook, et al., 1990 | gas phase; M |
+
= (
•
)
By formula: C7F14- + C6H5NO2 = (C7F14- • C6H5NO2)
Free energy of reaction
| ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 6.7 | 300. | PHPMS | Chowdhury and Kebarle, 1986 | gas phase; M |
+
= C13H5F14NO2-
By formula: C7F14- + C6H5NO2 = C13H5F14NO2-
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrG° | 6.7 ± 1.0 | kcal/mol | IMRE | Chowdhury and Kebarle, 1986 | gas phase; B |
References
Go To: Top, Ion clustering data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Knighton, Zook, et al., 1990
Knighton, W.B.; Zook, D.R.; Grimsrud, E.P.,
Cluster-Assisted Decomposition Reactions of the Molecular Anions of SF6 and C7F14,
J. Am. Soc. Mass Spectrom., 1990, 1, 5, 372, https://doi.org/10.1016/1044-0305(90)85017-G
. [all data]
Chowdhury and Kebarle, 1986
Chowdhury, S.; Kebarle, P.,
Role of Binding Energies in A-.B and A.B- Complexes in the Kinetics of Gas Phase Electron Transfer Reactions:A- + B = A + B- Involving Perfluoro Compounds: SF6, C6F11CF3,
J. Chem. Phys., 1986, 85, 9, 4989, https://doi.org/10.1063/1.451687
. [all data]
Notes
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- Symbols used in this document:
T Temperature ΔrG° Free energy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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