Perfluoro(methylcyclohexane) anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Δfgas-3000. ± 13.kJ/molR-EAGrimsrud, Chowdhury, et al., 1985ΔGea(423 K) = -26.1 kcal/mol; ΔSea = -2.7 eu.

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Perfluoro(methylcyclohexane) anion + Benzene, nitro- = (Perfluoro(methylcyclohexane) anion • Benzene, nitro-)

By formula: C7F14- + C6H5NO2 = (C7F14- • C6H5NO2)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
28.300.PHPMSChowdhury and Kebarle, 1986gas phase; M

Perfluoro(methylcyclohexane) anion + Methyl Alcohol = (Perfluoro(methylcyclohexane) anion • Methyl Alcohol)

By formula: C7F14- + CH4O = (C7F14- • CH4O)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
27.308.PHPMSKnighton, Zook, et al., 1990gas phase; M

Perfluoro(methylcyclohexane) anion + Dimethyl Sulfoxide = (Perfluoro(methylcyclohexane) anion • Dimethyl Sulfoxide)

By formula: C7F14- + C2H6OS = (C7F14- • C2H6OS)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
32.308.PHPMSKnighton, Zook, et al., 1990gas phase; M

Perfluoro(methylcyclohexane) anion + Benzene, nitro- = C13H5F14NO2-

By formula: C7F14- + C6H5NO2 = C13H5F14NO2-

Quantity Value Units Method Reference Comment
Δr28. ± 4.2kJ/molIMREChowdhury and Kebarle, 1986gas phase; B

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Perfluoro(methylcyclohexane) anion + Methyl Alcohol = (Perfluoro(methylcyclohexane) anion • Methyl Alcohol)

By formula: C7F14- + CH4O = (C7F14- • CH4O)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
27.308.PHPMSKnighton, Zook, et al., 1990gas phase; M

Perfluoro(methylcyclohexane) anion + Dimethyl Sulfoxide = (Perfluoro(methylcyclohexane) anion • Dimethyl Sulfoxide)

By formula: C7F14- + C2H6OS = (C7F14- • C2H6OS)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
32.308.PHPMSKnighton, Zook, et al., 1990gas phase; M

Perfluoro(methylcyclohexane) anion + Benzene, nitro- = (Perfluoro(methylcyclohexane) anion • Benzene, nitro-)

By formula: C7F14- + C6H5NO2 = (C7F14- • C6H5NO2)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
28.300.PHPMSChowdhury and Kebarle, 1986gas phase; M

Perfluoro(methylcyclohexane) anion + Benzene, nitro- = C13H5F14NO2-

By formula: C7F14- + C6H5NO2 = C13H5F14NO2-

Quantity Value Units Method Reference Comment
Δr28. ± 4.2kJ/molIMREChowdhury and Kebarle, 1986gas phase; B

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Grimsrud, Chowdhury, et al., 1985
Grimsrud, E.P.; Chowdhury, S.; Kebarle, P., Electron affinity of SF6 and perfluoromethylcyclohexane. The unusual kinetics of electron transfer reactions A- + B- + A, where A = SF6 or perfluorinated cycloalkanes, J. Chem. Phys., 1985, 83, 1059. [all data]

Chowdhury and Kebarle, 1986
Chowdhury, S.; Kebarle, P., Role of Binding Energies in A-.B and A.B- Complexes in the Kinetics of Gas Phase Electron Transfer Reactions:A- + B = A + B- Involving Perfluoro Compounds: SF6, C6F11CF3, J. Chem. Phys., 1986, 85, 9, 4989, https://doi.org/10.1063/1.451687 . [all data]

Knighton, Zook, et al., 1990
Knighton, W.B.; Zook, D.R.; Grimsrud, E.P., Cluster-Assisted Decomposition Reactions of the Molecular Anions of SF6 and C7F14, J. Am. Soc. Mass Spectrom., 1990, 1, 5, 372, https://doi.org/10.1016/1044-0305(90)85017-G . [all data]


Notes

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