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BrSCN+


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   G


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Txx = 55830 ± 560 gas Frost, MacDonald, et al., 1981

State:   F


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Txx = 37680 ± 320 gas Frost, MacDonald, et al., 1981

State:   E


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Txx = 30180 ± 320 gas Frost, MacDonald, et al., 1981

State:   D


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Txx = 25580 ± 320 gas Frost, MacDonald, et al., 1981


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 400 ± 60 gas PE Frost, MacDonald, et al., 1981

State:   C


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Txx = 19280 ± 320 gas Frost, MacDonald, et al., 1981


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 1 CN stretch 2050 ± 60 gas PE Frost, MacDonald, et al., 1981

State:   B


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Txx = 17180 ± 320 gas Frost, MacDonald, et al., 1981

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Txx = 13150 ± 320 gas Frost, MacDonald, et al., 1981

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' SBr stretch 450 ± 50 gas PE Frost, MacDonald, et al., 1981

Additional references: Jacox, 1994, page 194

Notes

xxEnergy separation between the band maxima of both the excited state and the ground state of a molecular cation, derived from a photoelectron spectrum.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Frost, MacDonald, et al., 1981
Frost, D.C.; MacDonald, C.B.; McDowell, C.A.; Westwood, N.P.C., Preparation and HeI photoelectron spectra of the halogen thiocyanates, XSCN (X = Cl and Br), J. Am. Chem. Soc., 1981, 103, 4423. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]


Notes

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