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ClBS+


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   C


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Tx = 50500 ± 1000 gas Kirby, Kroto, et al., 1978

State:   B


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 26019 gas B-X 405 516 King, Kuhn, et al., 1986

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 24961.5 ± 0.4 gas A-X 392 440 King, Kuhn, et al., 1986


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

Sigma+ 1 BS stretch 1390.6 ± 0.8 gas EF King, Kuhn, et al., 1986
3 BCl stretch 516.0 ± 0.8 gas EF King, Kuhn, et al., 1986

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

Sigma+ 1 BS stretch 1347.8 ± 0.8 gas EF King, Kuhn, et al., 1986
3 BCl stretch 508.9 ± 0.8 gas EF King, Kuhn, et al., 1986

Additional references: Jacox, 1994, page 74; Jacox, 1998, page 183; Chau, Tang, et al., 1994

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kirby, Kroto, et al., 1978
Kirby, C.; Kroto, H.W.; Westwood, N.P.C., Detection of chlorothioborine, ClB=S, a new unstable triatomic molecule, by photoelectron microwave spectroscopy, J. Am. Chem. Soc., 1978, 100, 3766. [all data]

King, Kuhn, et al., 1986
King, M.A.; Kuhn, R.; Maier, J.P., ~A2.SIGMA.+ .fwdarw. ~X2.PI.i emission spectra of fluoro- and chlorothioboron cations, FBS+ and ClBS+, J. Phys. Chem., 1986, 90, 24, 6460, https://doi.org/10.1021/j100282a011 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Chau, Tang, et al., 1994
Chau, F.T.; Tang, Y.W.; Song, X., Geometries of thioborine and chlorothioboron cations, J. Electron Spectrosc. Relat. Phenom., 1994, 70, 1, 39, https://doi.org/10.1016/0368-2048(94)02209-I . [all data]


Notes

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