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1,3-Dioxolan-2-one

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tfus310. ± 3.KAVGN/AAverage of 7 values; Individual data points
Quantity Value Units Method Reference Comment
Ttriple309.47KN/AMarsh, 1987Uncertainty assigned by TRC = 0.004 K; recommended as calibration standard; TRC
Ttriple309.49KN/AVasil'ev and Korkhov, 1973Uncertainty assigned by TRC = 0.02 K; TRC
Quantity Value Units Method Reference Comment
Deltavap80. ± 80.kJ/molAVGN/AAverage of 6 values; Individual data points

Reduced pressure boiling point

Tboil (K) Pressure (bar) Reference Comment
516.70.987Aldrich Chemical Company Inc., 1990BS

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
59.6396.AStephenson and Malanowski, 1987Based on data from 381. - 437. K.; AC
60.3383.EBHong, Wakslak, et al., 1982Based on data from 368. - 449. K.; AC
56.3423.EBHong, Wakslak, et al., 1982Based on data from 368. - 449. K.; AC
55.0433.EBHong, Wakslak, et al., 1982Based on data from 368. - 433. K.; AC
56.484423.VPeppel, 1958ALS

Enthalpy of sublimation

DeltasubH (kJ/mol) Temperature (K) Method Reference Comment
68.7285.AStephenson and Malanowski, 1987Based on data from 273. - 297. K.; AC

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Method Reference Comment
13.295309.49N/AVasil'ev and Korkhov, 1974DH
13.295309.49N/AVasil'ev and Korkhov, 1973DH
13.02311.2DSCDing, 2004AC
13.3309.5N/AVasil'ev and Korkhov, 1973AC

Entropy of fusion

DeltafusS (J/mol*K) Temperature (K) Reference Comment
42.96309.49Vasil'ev and Korkhov, 1974DH
42.96309.49Vasil'ev and Korkhov, 1973DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Marsh, 1987
Marsh, K.N., Recommended Reference Materials for the Realization of Physicochemical Properties, Blackwell Sci. Pub., Oxford, 1987. [all data]

Vasil'ev and Korkhov, 1973
Vasil'ev, I.A.; Korkhov, A.D., The heat capacities and enthalpies of fusion and the thermodynamic properties of solid and liquid ethylene carbonate, Zhur. Fiz. Khim., 1973, 47, 2710. [all data]

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Hong, Wakslak, et al., 1982
Hong, C.S.; Wakslak, R.; Finston, H.; Fried, V., Some thermodynamic properties of systems containing propylene carbonate and ethylene carbonate, J. Chem. Eng. Data, 1982, 27, 2, 146-148, https://doi.org/10.1021/je00028a012 . [all data]

Peppel, 1958
Peppel, W.J., Preparation and properties of the alkylene carbonates, Ind. Eng. Chem., 1958, 50, 767-770. [all data]

Vasil'ev and Korkhov, 1974
Vasil'ev, I.A.; Korkhov, A.D., Thermodynamic properties of alkylene carbonates at low temperatures, Tr. Khim. Khim. Tekhnol., Gor'kii, 1974, 36, 103-105. [all data]

Ding, 2004
Ding, Michael S., Liquid-Solid Phase Equilibria and Thermodynamic Modeling for Binary Organic Carbonates, J. Chem. Eng. Data, 2004, 49, 2, 276-282, https://doi.org/10.1021/je034134e . [all data]


Notes

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