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1,3-Dioxolan-2-one

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - H.Y. Afeefy, J.F. Liebman, and S.E. Stein
DH - E.S. Domalski and E.D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-682.8 ± 2.1kJ/molCcbChoi and Joncich, 1971Pedley's value is off by 24.20kcal/mol; ALS
Quantity Value Units Method Reference Comment
Deltacliquid-1069.3 ± 2.1kJ/molCcbChoi and Joncich, 1971Pedley's value is off by 24.20kcal/mol; Corresponding «DELTA»fliquid = -682.83 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
Deltafsolid-590.9kJ/molCcbVogdanis, Martens, et al., 1990ALS
Deltafsolid-586.3 ± 3.8kJ/molCcbCalhoun, 1983ALS
Deltafsolid-581.6 ± 0.4kJ/molCcbVasil'eva, Zhil'tosova, et al., 1972ALS
Quantity Value Units Method Reference Comment
Deltacsolid-1161.4kJ/molCcbVogdanis, Martens, et al., 1990Corresponding «DELTA»fsolid = -590.8 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacsolid-1165.9 ± 3.7kJ/molCcbCalhoun, 1983Corresponding «DELTA»fsolid = -586.32 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacsolid-1170.6 ± 0.4kJ/molCcbVasil'eva, Zhil'tosova, et al., 1972Corresponding «DELTA»fsolid = -581.58 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacsolid-1171.317kJ/molCcbSilvestro and Lenchitz, 1961Corresponding «DELTA»fsolid = -580.8727 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
solid,1 bar132.54J/mol*KN/AVasil'ev and Korkhov, 1974DH
solid,1 bar132.54J/mol*KN/AVasil'ev and Korkhov, 1973Extrapolation below 52 K.; DH

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
133.9323.15Peppel, 1958DH

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
117.44298.15Vasil'ev and Korkhov, 1974T = 52 to 340 K. Cp(liq) = 88.977 + 0.1586T J/mol*K (309 to 340 K).; DH
117.44298.15Vasil'ev and Korkhov, 1973T = 52 to 310 K. Full data deposited in VINITI, No. 326-73, 21 June 1973.; DH

References

Go To: Top, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Choi and Joncich, 1971
Choi, J.K.; Joncich, M.J., Heats of combustion, heats of formation and vapor pressures of some organic carbonates. Estimation of carbonate group contribution to heat of formation, J. Chem. Eng. Data, 1971, 16, 87-90. [all data]

Vogdanis, Martens, et al., 1990
Vogdanis, L.; Martens, B.; Uchtmann, H.; Hensel, F.; Heitz, W., Synthetic and thermodynamic investigations in the polymerization of ethylene carbonate, Makromol. Chem., 1990, 191, 456-472. [all data]

Calhoun, 1983
Calhoun, W.L., Enthalpies of combustion and formation of ethylene carbonate, J. Chem. Eng. Data, 1983, 28, 146-148. [all data]

Vasil'eva, Zhil'tosova, et al., 1972
Vasil'eva, T.F.; Zhil'tosova, E.N.; Vvedenski, A.A., Enthalpies of combustion of alkylene carbonates, Russ. J. Phys. Chem. (Engl. Transl.), 1972, 46, 316. [all data]

Silvestro and Lenchitz, 1961
Silvestro, G.; Lenchitz, C., Heat of combustion of ethylene carbonate, J. Phys. Chem., 1961, 65, 694-695. [all data]

Vasil'ev and Korkhov, 1974
Vasil'ev, I.A.; Korkhov, A.D., Thermodynamic properties of alkylene carbonates at low temperatures, Tr. Khim. Khim. Tekhnol., Gor'kii, 1974, 36, 103-105. [all data]

Vasil'ev and Korkhov, 1973
Vasil'ev, I.A.; Korkhov, A.D., The heat capacities and enthalpies of fusion and the thermodynamic properties of solid and liquid ethylene carbonate, Zhur. Fiz. Khim., 1973, 47, 2710. [all data]

Peppel, 1958
Peppel, W.J., Preparation and properties of the alkylene carbonates, Ind. Eng. Chem., 1958, 50, 767-770. [all data]


Notes

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