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Butyrolactone

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Enthalpy of vaporization at standard conditions (nominally 298.15 K, 1 atm.)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

DeltavapH° (kJ/mol) Method Reference Comment
47.6 ± 4.0N/AKlein, 1997Based on data from 293. - 333. K. See also Emel'yanenko, Kozlova, et al., 2008.; AC
55. ± 1.VWiberg and Waldron, 1991Heat of reduction; ALS
55.0N/AWiberg and Waldron, 1991DRB
55.2 ± 1.3EBWiberg and Waldron, 1991Based on data from 378. - 406. K.; AC
55.6 ± 1.4MMWiberg and Waldron, 1991Based on data from 345. - 370. K.; AC
54.4 ± 0.4CLeitao, Pilcher, et al., 1990See Brown, Conn, et al., 1989; ALS
54.4N/ALeitao, Pilcher, et al., 1990DRB
54.4 ± 0.4CLeitao, Pilcher, et al., 1990AC
48.9 ± 0.3N/ARamkumar and Kudchadker, 1990Based on data from 392. - 555. K. See also Emel'yanenko, Kozlova, et al., 2008.; AC
54.9 ± 0.2EBSteele, Chirico, et al., 1989Based on data from 361. - 522. K. See also Emel'yanenko, Kozlova, et al., 2008.; AC
53.46 ± 0.13VSteele, Chirico, et al., 1989, 2ALS
53.5N/ASteele, Chirico, et al., 1989, 2DRB
51.5EBIsmailov, Gabzalilova, et al., 1988Based on data from 357. - 435. K. See also Emel'yanenko, Kozlova, et al., 2008.; AC
54.6 ± 0.2GSJarim-Agaev, Afanasienko, et al., 1980Based on data from 273. - 478. K. See also Emel'yanenko, Kozlova, et al., 2008.; AC
53.1 ± 0.2EBJarim-Agaev, Afanasienko, et al., 1980Based on data from 413. - 478. K. See also Emel'yanenko, Kozlova, et al., 2008.; AC
48.0 ± 0.4EBYevstropov, Lebedev, et al., 1980See also Emel'yanenko, Kozlova, et al., 2008.; AC

References

Go To: Top, Enthalpy of vaporization at standard conditions (nominally 298.15 K, 1 atm.), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Klein, 1997
Klein, A., Thermodynamics of liquid mixtures with lactones, Fortschr.-Beric. VDI, Reihe 3: Verfahrenstechnik, 1997, 479, 1-206. [all data]

Emel'yanenko, Kozlova, et al., 2008
Emel'yanenko, Vladimir N.; Kozlova, Svetlana A.; Verevkin, Sergey P.; Roganov, Gennady N., Vapour pressures and enthalpies of vapourization of a series of the «947»-lactones, The Journal of Chemical Thermodynamics, 2008, 40, 6, 911-916, https://doi.org/10.1016/j.jct.2008.02.002 . [all data]

Wiberg and Waldron, 1991
Wiberg, K.B.; Waldron, R.F., Lactones. 2. Enthalpies of hydrolysis, reduction, and formation of the C4-C13 monocyclic lactones. strain energies and conformations, J. Am. Chem. Soc., 1991, 113, 7697-7705. [all data]

Leitao, Pilcher, et al., 1990
Leitao, M.L.P.; Pilcher, H.; Meng-Yan, Y.; Brown, J.M.; Conn, A.D., Enthalpies of combustion of «gamma»-butyrolactone, «gamma»-valerolactone, and «delta»-valerolactone, J. Chem. Thermodyn., 1990, 22, 885-891. [all data]

Brown, Conn, et al., 1989
Brown, J.M.; Conn, A.D.; Pilcher, G.; Leitao, M.L.P.; Yang, M.-Y., On the strain energy of 5-ring and 6-ring lactones, J. Chem. Soc., Chem. Commun., 1989, 1817-1819. [all data]

Ramkumar and Kudchadker, 1990
Ramkumar, D.H.S.; Kudchadker, A.P., Phase equilibria of water + «947»-butyrolactone system, Fluid Phase Equilibria, 1990, 55, 1-2, 207-215, https://doi.org/10.1016/0378-3812(90)85013-Z . [all data]

Steele, Chirico, et al., 1989
Steele, W.V.; Chirico, R.D.; Nguyen, A.; Hossenlopp, I.A.; Smith, N.K., Determination of some pure compound ideal-gas enthalpies of formation, AIChE Symp. Ser., 1989, 85, 271, 140. [all data]

Steele, Chirico, et al., 1989, 2
Steele, W.V.; Chirico, R.D.; Nguyen, A.; Hossenlopp, I.A.; Smith, N.K., Determination of some pure compound ideal-gas enthalpies of formation, AIChE Symp. Ser., 1989, 85, 140-162. [all data]

Ismailov, Gabzalilova, et al., 1988
Ismailov, T.S.; Gabzalilova, N.R.; Makhkamov, Kh.M., Complex study of physicochemical properties of «gamma»-butyrolactone, Uzb. Khim. Zh., 1988, 4, 48. [all data]

Jarim-Agaev, Afanasienko, et al., 1980
Jarim-Agaev, N.L.; Afanasienko, L.D.; Kalinichenko, V.P.; Tolmacheva, G.B., Ukr. Khim. Zhur., 1980, 46, 1331. [all data]

Yevstropov, Lebedev, et al., 1980
Yevstropov, A.A.; Lebedev, B.V.; Kiparisova, Ye.G.; Alekseyev, V.A.; Stashina, G.A., Thermodynamic parameters of transformation of «gamma»-butyrolactone into poly-«gamma»-butyrolactone at normal pressure in the range of 0-400°K, Polym. Sci. USSR, 1980, 22, 2685-2692. [all data]


Notes

Go To: Top, Enthalpy of vaporization at standard conditions (nominally 298.15 K, 1 atm.), References