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Acetic acid, hydroxy-, methyl ester

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LL - Sharon G. Lias and Joel F. Liebman

Ionization energy determinations

IE (eV) Method Reference Comment
10.42 ± 0.05EIBurgers, Holmes, et al., 1987LBLHLM

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CH3O+10.82 ± 0.05C2H3O2EISuh, Kingsmill, et al., 1995Unpublished result of F.P.Lossing; LL
CH5O+[CH3OH2+]11.5 ± 0.1CO+CHOEIBurgers, Holmes, et al., 1987LBLHLM
C2H3O2+11.38 ± 0.05CH2OHEIBlanchette, Holmes, et al., 1986LBLHLM
C2H3O3+10.50CH3EIBurgers, Holmes, et al., 1987LBLHLM
C2H5O2+10.74 ± 0.05CHOEISuh, Kingsmill, et al., 1995Unpublished result of F.P.Lossing; LL
C2H6O2+[CH3O··H··O=CH2+]10.9 ± 0.2COEIBurgers, Holmes, et al., 1987LBLHLM

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Burgers, Holmes, et al., 1987
Burgers, P.C.; Holmes, J.L.; Hop, C.E.C.A.; Postma, R.; Ruttink, P.J.A.; Terlouw, J.K., The isomeric [C2H6O2]+ hydrogen-bridged radical cations [CH2-O(H)...H...O=CH2]+, [CH3-O...H...O=CH2]+, and [CH3-O(H)...H...O=CH]+: Theory and experiment, J. Am. Chem. Soc., 1987, 109, 7315. [all data]

Suh, Kingsmill, et al., 1995
Suh, D.; Kingsmill, C.A.; Ruttink, P.J.A.; Burgers, P.C.; Terlouw, J.K., C-H...O and O...H...O bonded intermediates in the dissociation of low energy methyl glycolate radical cations, Int. J. Mass Spectrom. Ion Processes, 1995, 146/147, 305. [all data]

Blanchette, Holmes, et al., 1986
Blanchette, M.C.; Holmes, J.L.; Hop, C.E.C.A.; Lossing, F.P.; Postma, R.; Ruttink, P.J.A.; Terlouw, J.K., Theory and experiment in concert; the CH3O-C=O+ ion and its isomers, J. Am. Chem. Soc., 1986, 108, 7589. [all data]


Notes

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