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Aluminum, chlorodiethyl-


Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafliquid-382.2 ± 3.5kJ/molReviewMartinho SimõesSelected data. The enthalpy of formation relies on -187.3 ± 5.1 kJ/mol for the enthalpy of formation of Al(Et)3(l).
Deltafliquid-423.1 ± 3.6kJ/molReviewMartinho Simões 
Deltafliquid-237.8 ± 3.0kJ/molReviewMartinho Simões 
Quantity Value Units Method Reference Comment
Deltacliquid-3627.5 ± 2.9kJ/molCC-SBPawlenko, 1969The enthalpy of combustion was corrected according to the method used in Pawlenko, 1969.

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Reference Comment
50.5293.Buchan, Potemski, et al., 1991Based on data from 278. - 318. K.; AC
53.9373.Buchan, Potemski, et al., 1991Based on data from 273. - 473. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
317. - 398.5.795952812.315.258Fic and Dvorak, 1965Coefficents calculated by NIST from author's data.

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

2Hydrogen chloride (g) + Aluminum, chlorodiethyl- (l) = AlCl3 (cr) + 2Ethane (g)

By formula: 2HCl (g) + C4H10AlCl (l) = AlCl3 (cr) + 2C2H6 (g)

Quantity Value Units Method Reference Comment
Deltar-265.0 ± 3.3kJ/molRSCShaulov and Shmyreva, 1968The reaction enthalpy was derived from data in Shaulov and Shmyreva, 1968.

AlCl3 (cr) + 2Aluminum, triethyl- (l) = 3Aluminum, chlorodiethyl- (l)

By formula: AlCl3 (cr) + 2C6H15Al (l) = 3C4H10AlCl (l)

Quantity Value Units Method Reference Comment
Deltar-66.8 ± 1.3kJ/molRSCSmith, 1974Please also see Pedley and Rylance, 1977.

Aluminum, dichloroethyl- (l) + Aluminum, chlorodiethyl- (l) = C6H15Al2Cl3 (l)

By formula: C2H5AlCl2 (l) + C4H10AlCl (l) = C6H15Al2Cl3 (l)

Quantity Value Units Method Reference Comment
Deltar-2.3 ± 0.2kJ/molRSCSmith, 1974Please also see Pedley and Rylance, 1977.

Aluminum, dichloroethyl- (l) + Aluminum, triethyl- (l) = 2Aluminum, chlorodiethyl- (l)

By formula: C2H5AlCl2 (l) + C6H15Al (l) = 2C4H10AlCl (l)

Quantity Value Units Method Reference Comment
Deltar-39.5 ± 0.8kJ/molRSCSmith, 1974Please also see Pedley and Rylance, 1977.

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin D.HENNEBERG, MAX-PLANCK INSTITUTE, MULHEIM, WEST GERMANY
NIST MS number 62193

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References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Pawlenko, 1969
Pawlenko, S., Chem. Ber., 1969, 102, 1937. [all data]

Buchan, Potemski, et al., 1991
Buchan, Nicholas I.; Potemski, Robert M.; Kuech, Thomas F., Vapor pressure and vapor composition of diethylgallium chloride and diethylaluminum chloride, J. Chem. Eng. Data, 1991, 36, 4, 372-374, https://doi.org/10.1021/je00004a008 . [all data]

Fic and Dvorak, 1965
Fic, V.; Dvorak, J., Organo-Aluminum Compounds. 1. Vapor Pressure of Triethyl Aluminum and Diethyl Aluminium Chloride, Chem. Prum., 1965, 15, 732-735. [all data]

Shaulov and Shmyreva, 1968
Shaulov, Yu.Kh.; Shmyreva, G.O., Russ. J. Phys. Chem., 1968, 42, 1008. [all data]

Smith, 1974
Smith, M.B., J. Organometal. Chem., 1974, 76, 171. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]


Notes

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