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Benzenamine, 2,4-dimethyl-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil491.2KN/AAldrich Chemical Company Inc., 1990BS
Tboil487.45KN/ABuehler, Wood, et al., 1932Uncertainty assigned by TRC = 0.5 K; TRC
Quantity Value Units Method Reference Comment
Tfus257.25KN/AWitschonke, 1954Metastable crystal phase; Uncertainty assigned by TRC = 1. K; TRC
Tfus259.35KN/AWitschonke, 1954Metastable crystal phase; Uncertainty assigned by TRC = 0.35 K; TRC
Tfus259.32KN/AWitschonke, 1954Crystal phase 1 phase; Uncertainty assigned by TRC = 0.8 K; TRC
Tfus261.05KN/AWitschonke, 1954Crystal phase 1 phase; Uncertainty assigned by TRC = 0.3 K; TRC
Tfus258.9KN/ABirch, Dean, et al., 1949Uncertainty assigned by TRC = 1. K; TRC

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
61.3 ± 0.6317.N/AVerevkin, 1997Based on data from 295. - 339. K.; AC
55.5398.AStephenson and Malanowski, 1987Based on data from 383. - 485. K.; AC
56.9341.N/AStull, 1947Based on data from 326. - 485. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
325.9 - 484.75.180722293.277-41.261Stull, 1947Coefficents calculated by NIST from author's data.

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Buehler, Wood, et al., 1932
Buehler, C.A.; Wood, J.H.; Hull, D.C.; Erwin, E.C., A Study of Molecular Organic Compounds. IV. The Molecular Organic Compounds of Phenol, their Parachors and Refractivities, J. Am. Chem. Soc., 1932, 54, 2398. [all data]

Witschonke, 1954
Witschonke, C.R., Freezing point and purity data for some organic compounds, Anal. Chem., 1954, 26, 562-4. [all data]

Birch, Dean, et al., 1949
Birch, S.F.; Dean, R.A.; Fidler, F.A.; Lowry, R.A., The preparation of the c(10) monocyclic aromatic hydrocarbons, J. Am. Chem. Soc., 1949, 71, 1362. [all data]

Verevkin, 1997
Verevkin, Sergey P., Thermochemistry of amines: experimental standard molar enthalpies of formation of some aliphatic and aromatic amines, The Journal of Chemical Thermodynamics, 1997, 29, 8, 891-899, https://doi.org/10.1006/jcht.1997.0212 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]


Notes

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