Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

1,3,5,2,4,6-Triazatriphosphorine, 2,2,4,4,6,6-hexachloro-2,2,4,4,6,6-hexahydro-

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Phase change data

Go To: Top, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), NIST Free Links, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Method Reference
23.5388.6AC,DCLebedev, Kulagina, et al., 1999

Gas phase ion energetics data

Go To: Top, Phase change data, IR Spectrum, Mass spectrum (electron ionization), NIST Free Links, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
10.05 ± 0.03EIClare and Sowerby, 1981LLK
10.3 ± 0.1EICoxon, Palmer, et al., 1969RDSH
10.26 ± 0.05EIBrion, Oldfield, et al., 1966RDSH
10.43PENoodleman, Westwood, et al., 1978Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
Cl4N3P3+11.78Cl2EIClare and Sowerby, 1981LLK
Cl5N3P3+11.43ClEIClare and Sowerby, 1981LLK
P3N3Cl5+11.1 ± 0.1ClEICoxon, Palmer, et al., 1969RDSH

IR Spectrum

Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), NIST Free Links, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Coblentz Society, Inc.

Condensed Phase Spectrum

Notice: This spectrum may be better viewed with a Javascript and HTML 5 enabled browser.

IR spectrum
For Zoom
1.) Enter the desired X axis range (e.g., 100, 200)
2.) Check here for automatic Y scaling
3.) Press here to zoom

Notice: Except where noted, spectra from this collection were measured on dispersive instruments, often in carefully selected solvents, and hence may differ in detail from measurements on FTIR instruments or in other chemical environments. More information on the manner in which spectra in this collection were collected can be found here.

Notice: Concentration information is not available for this spectrum and, therefore, molar absorptivity values cannot be derived.

Additional Data

View scan of original (hardcopy) spectrum.

View image of digitized spectrum (can be printed in landscape orientation).

View spectrum image in SVG format.

Download spectrum in JCAMP-DX format.

Owner COBLENTZ SOCIETY
Collection (C) 2018 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin WYANDOTTE CHEMICALS CORP., WYANDOTTE, MICHIGAN, USA
Source reference COBLENTZ NO. 3065
Date Not specified, most likely prior to 1970
Name(s) 2,2,4,4,6,6-hexachloro-1,3,5,2.lambda.<5>,4.lambda.<5>,6.lambda.<5>-triazatriphosphinine
State SOLID (MINERAL OIL MULL)
Instrument Not specified, most likely a prism, grating, or hybrid spectrometer.
Path length
SPECTRAL CONTAMINATION DUE TO OIL AROUND 2900 CM-1
Resolution 4
Sampling procedure TRANSMISSION
Data processing DIGITIZED BY NIST FROM HARD COPY

This IR spectrum is from the Coblentz Society's evaluated infrared reference spectra collection.


Mass spectrum (electron ionization)

Go To: Top, Phase change data, Gas phase ion energetics data, IR Spectrum, NIST Free Links, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

Notice: This spectrum may be better viewed with a Javascript and HTML 5 enabled browser.

Mass spectrum
For Zoom
1.) Enter the desired X axis range (e.g., 100, 200)
2.) Check here for automatic Y scaling
3.) Press here to zoom

Additional Data

View image of digitized spectrum (can be printed in landscape orientation).

View spectrum image in SVG format.

Download spectrum in JCAMP-DX format.

Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
NIST MS number 29522

All mass spectra in this site (plus many more) are available from the NIST/EPA/NIH Mass Spectral Library. Please see the following for information about the library and its accompanying search program.


References

Go To: Top, Phase change data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), NIST Free Links, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lebedev, Kulagina, et al., 1999
Lebedev, B.V.; Kulagina, T.G.; Tur, D.R., Thermodynamics of hexachlorocyclotriphosphazene and octachlorocyclotetraphosphazene fromT--> 0 toT= 450 K, The Journal of Chemical Thermodynamics, 1999, 31, 6, 697-710, https://doi.org/10.1006/jcht.1998.0472 . [all data]

Clare and Sowerby, 1981
Clare, P.; Sowerby, D.B., Electron impact ionisation energies of some halo-cyclotriphosphazenes, J. Inorg. Nucl. Chem., 1981, 43, 477. [all data]

Coxon, Palmer, et al., 1969
Coxon, G.E.; Palmer, T.F.; Sowerby, D.B., Cyclic inorganic compounds. Part VII.The mass spectra of the trimeric chlorobromophosphonitriles, J. Chem. Soc., 1969, (A), 358. [all data]

Brion, Oldfield, et al., 1966
Brion, C.E.; Oldfield, D.J.; Paddock, N.L., Huckel type interactions in phosphonitrilic derivatives, Chem. Commun., 1966, 226. [all data]

Noodleman, Westwood, et al., 1978
Noodleman, L.; Westwood, N.P.C.; Mitchell, K.A.R., Ionization energies and electronic structure of N3P3Cl6 as determined by UV photoelectron and spectroscopy the X«alpha» scattered wave method, Chem. Phys. Lett., 1978, 58, 252. [all data]


Notes

Go To: Top, Phase change data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), NIST Free Links, References